The structures and microtextures of the palygorskite-sepiolite group minerals

Developments in Clay Science

Volumn 3, Issue , 2011, Pages 3-32

  Guggenheim, Stephen ^a   Krekeler, Mark P S ^b  

^a UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

^b Miami University Hamilton   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84866391840     PISSN: 15724352     EISSN: None     Source Type: Book Series    
DOI: 10.1016/B978-0-444-53607-5.00001-3     Document Type: Chapter

References (78)

1. Artioli, G., Galli, E., 1994. The crystal structures of orthorhombic and monoclinic palygorskite. Mater. Sci. Forum 166-169, 647-652.
2. Artioli, G., Galli, E., Burattini, E., Cappuccio, G., Simeoni, S., 1994. Palygorskite from Bolca, Italy: a characterization by high-resolution synchrotron radiation powder diffraction and computer modeling. Neues Jahrb. Mineral. Monatsh. 5, 217-229.
3. Bailey, S.W., 1980. Structures of layer silicates. In: Brindley, G.W., Brown, G. (Eds.), Crystal Structures of Clay Minerals and Their X-ray Identification. Mineralogical Society, London, England, pp. 1-124.
4. Bates, T.F., 1959. Morphology and crystal chemistry of 1:1 layer lattice silicates. Am. Mineral. 44, 78-114.
5. Birsoy, R., 2002. Formation of sepiolite-palygorskite and related minerals from solution. Clays Clay Miner. 50, 736-745.
6. Bowles, A., Angino, E.A., Hosterman, J.W., Galle, O.K., 1971. Precipitation of deep-sea palygorskite and sepiolite. Earth Planet. Sci. Lett. 11, 324-332.
7. Bradley, W.F., 1940. The structural scheme of attapulgite. Am. Mineral. 25, 405-410.
8. Cámara, F., Garvie, L.A.J., Devouard, B., Groy, T.L., Buseck, P.R., 2002. The structure of Mnrich tuperssuatsiaite: a palygorskite-related mineral. Am. Mineral. 87, 1458-1463.
9. Chahi, A., Fritz, B., Duplay, J., Weber, F., Lucas, J., 1997. Textural transition and genetic relationship between precursor stevensite and sepiolite in lacustrine sediments (Jbel Rhssoul, Morocco). Clays Clay Miner. 45, 378-389.
10. Chen, T., Xu, H., Lu, A., Xu, X., Peng, S., Yue, S., 2004. Direct evidence of transformation from smectite to palygorskite: TEM investigation. Sci. China D Earth Sci. 47, 985-994.
11. Chiari, G., Giustetto, R., Ricchiardi, G., 2003. Crystal structure refinements of palygorskite and Maya Blue from molecular modeling and powder synchrotron diffraction. Eur. J. Mineral. 15, 21-33.
12. Chrisholm, J.E., 1992. Powder diffraction patterns and structural models for palygorskite. Can. Mineral. 30, 61-73.
13. Christ, C.L., Hathaway, J.C., Hostetler, P.B., Shepard, A.O., 1969. Palygorskite: new X-ray data. Am. Mineral. 54, 198-205.
14. Chryssikos, G.D., Gionis, V., Kacandes, G.H., Stathopoulou, E.T., Suárez, M., García-Romero, E., et al., 2009. Octahedral cation distribution in palygorskite. Am. Mineral. 94, 200-203.
15. Couture, R.A., 1977. Composition and origin of palygorskite-rich and montmorillonite-rich zeolite-containing sediments from the Pacific Ocean. Chem. Geol. 19, 113-130.
16. de Lapparent, J., 1935. Sur un constituent essential des terres a foulon. C. R. Acad. Sci. Paris 201, 481-482.
17. Dowty, E., 2005. ATOMS for Windows. Shape Software, Kingsport, TN, USA.
18. Drits, V.A., Aleksandrova, V.A., 1966. On the crystallographic nature of palygorskite. Zap. Vses. Miner. Obshch. 95, 551-560.
19. Drits, V.A., Sokolova, G.V., 1971. Structure of palygorskite. Sov. Phys., Crystallogr. 16, 183-185.
20. Fahey, J.J., Ross, M., Axelrod, J.M., 1960. Loughlinite, a new hydrous sodium magnesium silicate. Am. Mineral. 45, 270-281.
21. Ferraris, G., Khomyakov, A.P., Belluso, E., Soboleva, S.V., 1998. Kalifersite, a new alkaline silicate from Kola Peninsula (Russia) based on the palygorskite-sepiolite polysomatic series. Eur. J. Mineral. 10, 865-874.
22. Fois, E., Gamba, A., Tilocca, A., 2003. On the unusual stability of Maya Blue paint: molecular dynamics simulations. Microporous Mesoporous Mater. 57, 263-272.
23. Galán, E., Carretero, M.I., 1999. A new approach to compositional limits for sepiolite and palygorskite. Clays Clay Miner. 47, 399-409.
24. Garcia-Romero, E., Suárez, M., Santarén, J., Alvarez, A., 2007. Crystal chemical characterization of the palygorkite andsepiuolite from the Allou Kagne deposit, Senegal. Clays Clay Miner. 55, 606-617.
25. Giustetto, R., Chiari, G., 2004. Crystal structure refinement of palygorskite from neutron powder diffraction. Eur. J. Mineral. 16, 521-532.
26. Golden, D.C., Dixon, J.B., 1990. Low temperature alteration of palygorskite to smectite. Clays Clay Miner. 38, 401-408.
27. Golden, D.C., Dixon, J.B., Shadfar, H., Kippenberger, L.A., 1985. Palygorskite and sepiolite alteration to smectite under alkaline conditions. Clays Clay Miner. 33, 44-50.
28. Guggenheim, S., 1981. Cation ordering in lepidolite. Am. Mineral. 66, 1221-1232.
29. Guggenheim, S., 1984. The brittle micas. In: Bailey, S.W. (Ed.), Micas. Reviews in Mineralogy, vol. 13. Mineralogical Society of America, Washington, DC, pp. 61-104.
30. Guggenheim, S., 2010. Structures of the palygorskite-sepiolite group minerals: comments on the formation of the polysomes. In: Book of abstracts of the General Meeting. 2010 SEA-CSSJCMS Trilateral Meeting on Clays, p. 38.
31. Guggenheim, S., Eggleton, R.A., 1987. Modulated 2:1 layer silicates: review, systematics, and predictions. Am. Mineral. 72, 724-738.
32. Guggenheim, S., Eggleton, R.A., 1988. Crystal chemistry, classification, and identification of modulated layer silicates. In: Bailey, S.W. (Ed.), Hydrous Phyllosilicates (Exclusive of the Micas). Reviews in Mineralogy, vol. 20. Mineralogical Society of America, Washington, DC, pp. 675-725.
33. Guggenheim, S., Koster van Groos, A.F., 2001. Baseline studies of the clay minerals society source clays: thermal analysis. Clays Clay Miner. 49, 433-443.
34. Guggenheim, S., Adams, J.M., Bain, D.C., Bergaya, F., Brigatti, M.F., Drits, V.A., et al., 2006. Summary of recommendations of nomenclature committees relevant to clay mineralogy: report of the Association Internationale pour l'Etude des Argiles (AIPEA) Nomenclature-Committee for 2006. Clays Clay Miner. 54, 761-772 and Clay Minerals, 41, 863-878.
35. Güven, N., Carney, L.L., 1979. The transformation of sepiolite to stevensite and the effect of added chloride and hydroxide. Clays Clay Miner. 27, 253-260.
36. Hay, R.L., Wiggins, B., 1980. Pellets, ooids, sepiolite and silica in three calcretes of the southwestern United States. Sedimentology 27, 559-576.
37. Heller-Kalai, L., Rozenson, I., 1981. Mössbauer studies of palygorskite and some aspects of palygorskite mineralogy. Clays Clay Miner. 29, 226-232.
38. Imai, N., Otsuka, R., 1984. Sepiolite and palygorskite in Japan. In: Singer, A., Galán, E. (Eds.), Palygorskite-Sepiolite. Occurrences, Genesis, and Uses. Developments in Sedimentology, vol. 37. Elsevier, Amsterdam, pp. 211-232.
39. Jones, B.F., Galán, E., 1988. Sepiolite and palygorskite. In: Bailey, S.W. (Ed.), Hydrous Phyllosilicates (Exclusive of the Micas). Reviews in Mineralogy, vol. 19. Mineralogical Society of America, Washington, DC, pp. 631-674.
40. Karup-Møller, S., Peterson, O.V., 1984. Tuperssuatsiaite, a new mineral species from the Ilímaussaq intrusion in South Greenland. Neues Jahrb. Mineral. Monatsh. 501-512.
41. Khomyakov, A.P., 1995. Mineralogy of Hyperagpaitic Alkaline Rocks. Clarendon, Oxford.
42. Krekeler, M.P.S., Guggenheim, S., 2008. Defects in microstructure in palygorskite-sepiolite minerals: a transmission electron microscopy (TEM) study. Appl. Clay Sci. 39, 98-105.
43. Krekeler, M.P.S., Hammerly, E., Rakovan, J., Guggenheim, S., 2005. Microscopy studies of the palygorskite to smectite transformation. Clays Clay Miner. 53, 94-101.
44. La Iglesia, A., 1977. Precipitación por disolución homogénea de silicatos de aluminio y magnesio a temperatura ambiente. Sintesis de la paligorskita. Estud. Geol. 33, 535-544.
45. Martin, R.T., Bailey, S.W., Eberl, D.D., Fanning, D.S., Guggenheim, S., Kodama, H., et al., 1991. Revised classification of clay materials: report of the Clay Minerals Society Nomenclature Committee for 1986-1988. Clays Clay Miner. 39, 333-334.
46. Martin-Vivaldi, J.L., Cano-Ruiz, J., 1955. Contribution to the study of sepiolite: II. Some considerations regarding the mineralogical formula. Clays Clay Miner. 4, 173-176.
47. Merkl, R.S., 1989. A sedimentological, mineralogical, and geochemical study of the fuller's earth deposits of the Miocene Hawthorne group of south Georgia-north Florida. Ph.D. Dissertation, Indiana University, Bloomington, Indiana 182p.
48. Meunier, A., 2005. Clays. Springer, Berlin.
49. Milton, C., 1977. Mineralogy of the Green River Formation. Mineral. Rec. 8, 368-379.
50. Newman, A.C.D., Brown, G., 1987. The chemical constitution of clays. In: Newman, A.C.D. (Ed.), Chemistry of Clays and Clay Minerals. Monograph, vol. 6. Mineralogical Society, London, England, pp. 1-128.
51. Perrault, G., Harvey, Y., Pertsowsky, R., 1975. La yofortierite, un nouveau silicate hydrate de manganèse de St-Hilaire, P.Q. Can. Mineral. 13, 68-74.
52. 2O, opens up new chemistry and physics of low-temperature minerals. Proc. Natl. Acad. Sci. USA 94, 12263-12267.
53. Post, J.E., Bish, D.L., 1989. Rietveld refinement of crystal structures using powder X-ray diffraction data. In: Bish, D.L., Post, J.E. (Eds.), Modern Powder Diffraction. Reviews in Mineralogy, vol. 20. Mineralogical Society of America, Washington, DC, pp. 277-308.
54. Post, J.E., Heaney, P.J., 2008. Synchrotron powder X-ray diffraction study of the structure and dehydration behavior of palygorskite. Am. Mineral. 93, 667-675.
55. Post, J.E., Bish, D.L., Heaney, P.J., 2007. Synchrotron powder X-ray diffraction study of the structure and dehydration behavior of sepiolite. Am. Mineral. 92, 91-97.
56. Radolovich, E.W., 1961. Surface symmetry and cell dimensions of layer lattice silicates. Nat. Lond. 191, 67-68.
57. Randall, B.A.O., 1956. Stevensite from the Whin Sill in the region of the North Tyne. Mineral. Mag. 32, 218-229.
58. Robertson, R.H.S., 1962. The acceptability of mineral group names. Clay Miner. Bull. 5, 41-43.
59. Ruiz-Hitzky, E., 2001. Molecular access to intracrystalline tunnels of sepiolite. J. Mater. Chem. 11, 86-91.
60. Santaren, J., Sanz, J., Ruiz-Hitsky, E., 1990. Structural fluorine in sepiolite. Clays Clay Miner. 38, 63-68.
61. Serna, C., Fernandez-Alvarez, T., 1974. Adsorcion de hidrocarburos en sepiolite II: Propiedades ed superficie. Anal. Quim. 71, 371-376.
62. Serna, C., Van Scoyoc, G.E., Ahlrichs, J.L., 1977. Hydroxyl groups and water in palygorskite. Am. Mineral. 62, 784-792.
63. Siffert, B., Wey, R., 1962. Synthèsis d'une sépiolite à température ordinaire. C. R. Acad. Sci. Paris 245, 1460-1463.
64. Singer, A., 1979. Palygorskite in sediments: detrital, diagenetic, or neoformed. A critical review. Geol. Rundsch. 68, 996-1008.
65. Singer, A., Norrish, K., 1974. Pedogenetic palygorskite. Occurrences in Australia. Am. Mineral. 59, 508-517.
66. Smith, D.G.W., Norem, D., 1986. The electron microprobe analysis of palygorskite. Can. Mineral. 24, 499-511.
67. Springer, G., 1976. Falcondoite, nickel analogue of sepiolite. Can. Mineral. 14, 407-409.
68. Ssaftschenkow, T.V., 1862. Palygorskit. Verhandlungen der Russisch Kaiserlichen Gesellschaft für Mineralogie, Sankt Petersburg 102-104.
69. Suárez, M., García-Romero, E., Sánchez del Río, M., Martinetto, P., Dooryhée, E., 2007. The effect of the octahedral cations on the dimensions of the palygorskite cell. Clay Miner. 42, 287-297.
70. 2. Z. Kristallogr. 148, 65-81.
71. Velde, B., 1985. Clay minerals: a physico-chemical explanation of their occurrence. Developments in Sedimentology, vol. 40. Elsevier, New York, p. 427.
72. Weaver, C.E., 1984. Origin and geologic implications of the palygorskite of S.E. United States. In: Singer, A., Galán, E. (Eds.), Palygorskite-Sepiolite. Occurrences, Genesis, and Uses. Developments in Sedimentology, vol. 37. Elsevier, Amsterdam, pp. 39-58.
73. Weaver, C.E., Beck, K.C., 1977. Miocene of the S.E. United States: a model for chemical sedimentation in a perimarine environment. Sediment. Geol. 17, 1-234.
74. Wollast, R., Mackenzie, F.T., Bricker, O., 1968. Experimental precipitation and genesis of sepiolite at earth-surface conditions. Am. Mineral. 53, 1645-1662.
75. Yaalon, D.M., Wieder, M., 1976. Pedogenetic palygorskite in some arid brown (caliothid) soils of Israel. Clay Miner. 11, 73-79.
76. Yamnova, N.A., Egorov-Tismenko, Yu.K., Khomyakov, A.P., 1996. Crystal structure of a new natural (Na, Mn, Ti)-phyllosilicate. Crystallogr. Rep. 41, 239-244 as translated from the Russian in: Kristallografiya (1996) 41, 257-262.
77. Zoltai, T., 1981. Amphibole asbestos mineralogy. In: Veblen, D.R. (Ed.), Amphiboles and Other Hydrous Pyriboles. Reviews in Mineralogy, vol. 9A. Mineralogical Society of America, Washington, DC, pp. 237-278.
78. Zvyagin, B.B., 1957. Determination of the structure of celadonite by electron diffraction. Sov. Phys. Crystallogr. 2, 388-394.