Structure-property relationships in ILs: A study of the alkyl chain length dependence in vaporisation enthalpies of pyridinium based ionic liquids

Science China Chemistry

Volumn 55, Issue 8, 2012, Pages 1525-1531

  Zaitsau, Dzmitry H ^a   Yermalayeu, Andrei V ^a   Emel'yanenko, Vladimir N ^a   Verevkin, Sergey P ^a   Welz Biermann, Urs ^b   Schubert, Thomas ^c  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b Evonik Degussa Taiwan Ltd   (Taiwan)

^c Ionic Liquids Technologies GmbH   (Germany)

Author keywords

Enthalpy of vaporization; Ionic liquids; Quartz crystal microbalance; Structure property relations

Indexed keywords

ALKYL CHAIN LENGTHS; ENTHALPIES OF VAPORIZATION; ENTHALPY OF VAPORIZATION; LANGMUIRS; LINEAR DEPENDENCE; LIQUID PHASE; PYRIDINIUM; QUARTZ CRYSTAL MICROBALANCE TECHNIQUES; REFERENCE TEMPERATURE; STRUCTURE PROPERTY RELATION; STRUCTURE PROPERTY RELATIONSHIPS; VAPORIZATION ENTHALPIES;

ARCHITECTURAL ACOUSTICS; CHAIN LENGTH; ENTHALPY; IONIC LIQUIDS; QUARTZ CRYSTAL MICROBALANCES; SURFACE TENSION; VAPORS;

VAPORIZATION;

EID: 84866160666     PISSN: 16747291     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11426-012-4662-2     Document Type: Article

References (38)

1. Rantwijk FV, Sheldon RA. Biocatalysis in ionic liquids. Chem Rev, 2007, 107: 2757-2785 (Pubitemid 47033772)
2. Greaves TL, Drummond CJ. Protic ionic liquids: Properties and applications. Chem Rev, 2008, 108: 206-237 (Pubitemid 351176407)
3. Hapiot P, Lagrost C. Electrochemical reactivity in room-temperature ionic liquids. Chem Rev, 2008, 108: 2238-2264
4. Jessop PG, Subramaniam B. Gas-expanded liquids. Chem Rev, 2007, 107: 2666-2694 (Pubitemid 47033771)
5. Visser AE, Rogers RD. Room-temperature ionic liquids: New solvents for f-element separations and associated solution chemistry. J Solid State Chem, 2003, 171: 109-113
6. Kim GT, Appetecchi GB, Alessandrini F, Passerini S. Solvent-free, PYR1ATFSI ionic liquid-based ternary polymer electrolyte systems I. Electrochemical characterization. J Power Sources, 2007, 171: 861-869 (Pubitemid 47376784)
7. Orita A, Kamijima K, Yoshida M, Yang L. Application of sulfonium-, and thioxonium-based salts as electric double-layer capacitor electrolytes. J Power Sources, 2010, 195: 6970-6976
8. Lazzari M, Mastragostino M, Pandolfo AG, Ruiz V, Soavi F. Role of carbon porosity and ion size in the development of ionic liquid based supercapacitors. J Electrochem Soc, 2011, 158: A22-A25
9. Orita A, Kamijima K, Yoshida M. Allyl-functionalized ionic liquids as electrolytes for electric double-layer capacitors. J Power Sources, 2010, 195: 7471-7479
10. Fang SH, Yang L, Wei C, Peng CX, Tachibana K, Kamijima K. Low-viscosity and low-melting point asymmetric trialkylsulfonium based ionic liquids as potential electrolytes. Electrochem Commun, 2007, 9: 2696-2702 (Pubitemid 47626077)
11. Kazock J, Taggougui M, Anouti M, Willman P, Carre B, Lemordant D. Ionic liquids based on 1-aza-bicyclo[2,2,2]cotane (quinuclidine)salts: synthesis and physicochemical properties. J Appl Electrochem, 2009, 39: 2461-2467
12. Sakaebe H, Matsumoto H. N-Methyl-N-propylpiperdinium bis(trifluoromethanesulfonyl) imide (PP13-TFSI)-novel electrolyte base for Li battery. Electrochem Commun, 2003, 5: 594-598
13. Yang L, Zhang ZX, Gao XH, Zhang HQ, Mashita K. Asymmetric sulfonium-based molten salts with TFSI- or PF6 anion as novel electrolytes. J Power Sources, 2006, 162: 614-619 (Pubitemid 44573726)
14. 2 cell with low-viscosity ionic liquids based on bis(fluorosulfony)imide[FSI]. J Power Sources, 2006, 160: 1308-1303
15. 2]. J Chem Eng Data, 2011, 56: 4094-4101
16. Bittner B, Janus E, Milchert E. N-Hexylpyridinium bis(trifluoromethylsulfonyl) imide and Lewis acids-catalytic systems for Diels-Alder reaction. Cent Eur J Chem, 2011, 9: 192-198
17. Papaiconomou N, Estager J, Traore Y, Bauduin P, Bas C, Legeai S, Viboud S, Draye M. Synthesis, physicochemical properties, and toxicity data of new hydrophobic ionic liquids containing dimethylpyridinium and trimethylpyridinium cations. J Chem Eng Data, 2010, 55: 1971-1979
18. Rodriguez-Cabo B, Francisco M, Soto A, Arce A. Hexyl dimethylpyridinium ionic liquids for desulfurization of fuels. Effect of the position of alkyl side chains. Fluid Phase Equil, 2012, 314: 107-111
19. Gaile AA, Zalishchevkii GD, Gafur NN, Semenov LV, Varshavski OM, Fedyanin NP, Koldobskaya LL. Removal of aromatic hydrocarbons from reforming naphtha. combined extractionextractive-azeotropic distillation process. Chem Thechnol Fuels Oils, 2004, 40: 215-221 (Pubitemid 39570168)
20. Verevkin SP, Zaitsau DH, Emel'yanenko VN, Heintz A. A new method for the determination of vaporization enthalpies of ionic liquids at low temperatures. J Phys Chem B, 2011, 115: 12889-12895
21. Zaitsau DH, Verevkin SP, Emel'yanenko VN, Heintz A. Vaporization enthalpies of imidazolium based ionic liquids: Dependence on alkyl chain length. ChemPhysChem, 2011, 12: 3609-3613
22. Zaitsau DH, Fumino K, Emel'yanenko VN, Yermalaeu AV, Ludwig R, Verevkin SP. Structure-property relationships in ILs: A study of the anion dependence in vaporisation enthalpies of imidazolium based ionic liquids. ChemPhysChem, 2012, in press
23. Verevkin SP, Zaitsau DH, Emel'yanenko VN, Ralys RV, Schick C. Express thermo-gravimetric method for the vaporization enthalpies appraisal for very low volatile molecular and ionic compounds. Thermochim Acta, 2012, accepted
24. Sauerbrey G. Verwendung von Schwingquarzen zur Wägung dünner Schichten und zur Mikrowägung. Z Phys A, 1959, 155: 206-222
25. Paulechka YU, Kabo GJ, Blokhin AV, Vydrov OA, Magee JW, Frenkel M. Thermodynamic properties of 1-butyi-3-methylimidazolium hexafluorophosphate in the ideal gas state. J Chem Eng Data, 2003, 48: 457-462
26. Moelwyn-Hughes EA. Physical Chemistry. New York, London, Paris: Pergamon Press, 1954
27. Paulechka YU, Zaitsau DH, Kabo GJ. On the difference between isobaric and isochoric heat capacities of liquid cyclohexyl esters. J Mol Liq, 2004, 115: 105-111
28. Diedrichs A, Gmehling J. Measurement of heat capacities of ionic liquids by differential scanning calorimetry. Fluid Phase Equilib, 2006, 244: 68-77
29. Paulechka Y. Heat capacity of room-temperature ionic liquids: A critical review. J Phys Chem Ref Data, 2010, 39(3): 033108 1-23
30. Wang C, Luo H, Li H, Dai S. Direct UV-spectroscopic measurement of selected ionic-liquid vapors. PhysChem Chem Phys, 2010, 12: 7246-7250
31. 298 values of ionic liquids. Phys Chem Chem Phys, 2009, 11: 8544-8555
32. Kulikov D, Verevkin SP, Heintz A. Enthalpies of vaporization of a series of aliphatic alcohols: Experimental results and values predicted by the ERAS-model. Fluid Phase Equil, 2001, 192: 187-207 (Pubitemid 33110964)
33. Emel'yanenko VN, Verevkin SP, Koutek B, Doubsky J. Vapour pressures and enthalpies of vapourization of a series of the linear aliphatic nitriles. J Chem Thermodyn., 2005, 37: 73-81
34. Verevkin SP, Krasnykh EL, Vasiltsova TV, Koutek B, Doubsky J, Heintz A. Vapor pressures and enthalpies of vaporization of a series of the linear aliphatic aldehydes. Fluid Phase Equil, 2003, 206: 331-339 (Pubitemid 36555216)
35. Verevkin SP, Zaitsau DH, Emel'yanenko VN, Schick C, Liu H, Maginn E, Bulut S, Krossing I, Kalb R. Obscured vaporization enthalpies of ionic liquids: Milky way, bent up, or straight ahead? new experimental data on 1-alkyl-3-methylimidazolium bis-(trifluoro-methylsulfonyl)-imides with the even and odd number of C-atoms in the alkyl chain. J Am Chem Soc, 2012, submitted
36. Mansson M, Sellers P, Stridh G, Sunner S. Enthalpies of vaporization of some l-substituted n-alkanes. J Chem Thermodyn, 1977, 9: 91-97
37. Zaitsau DH, Kabo GJ, Strechan AA, Paulechka YU, Tschersich A, Verevkin SP, Heintz A. Experimental vapor pressures of 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imides and a correlation scheme for estimation of vaporization enthalpies of ionic liquids. J Phys Chem A, 2006, 110: 7303-7306 (Pubitemid 43953031)
38. Deyko A, Hessey SG, Licence P, Chernikova EA, Krasovskiy VG, Kustov LM, Jones RG. The enthalpies of vaporisation of ionic liquids: new measurements and predictions. Phys Chem Chem Phys, 2012, 14: 3181-3193