In situ monitoring of Pt nanoparticle formation in ethylene glycol solution by SAXS-influence of the NaOH to Pt ratio

Langmuir

Volumn 28, Issue 36, 2012, Pages 13072-13079

  Steinfeldt, Norbert ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDIC MEDIUMS; ALKALINE REACTION; ETHYLENE GLYCOL SOLUTIONS; GROWING PROCESS; GROWTH REACTIONS; IN-SITU; IN-SITU MONITORING; IN-SITU STUDY; IRREVERSIBLE AGGREGATION; METAL REDUCTION; MOLAR RATIO; NANOPARTICLE FORMATION; NARROW SIZE DISTRIBUTIONS; NUCLEATION REACTION; PARTICLE FORMATIONS; POLY(N-VINYL-2-PYRROLIDONE); PROTECTING AGENT; PT COMPLEXES; PT NANOPARTICLES; REDUCTION RATE; SIZE AND SIZE DISTRIBUTIONS; SMALL ANGLE X-RAY SCATTERING; TEMPORAL EVOLUTION;

ETHYLENE GLYCOL; METAL NANOPARTICLES; NUCLEATION; PARTICLE SIZE ANALYSIS; PLATINUM; SIZE DISTRIBUTION;

PLATINUM COMPOUNDS;

ETHYLENE GLYCOL; METAL NANOPARTICLE; PLATINUM; SODIUM HYDROXIDE;

ARTICLE; CHEMISTRY; SMALL ANGLE SCATTERING; SOLUTION AND SOLUBILITY; X RAY DIFFRACTION;

ETHYLENE GLYCOL; METAL NANOPARTICLES; PLATINUM; SCATTERING, SMALL ANGLE; SODIUM HYDROXIDE; SOLUTIONS; X-RAY DIFFRACTION;

EID: 84866054107     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la3026232     Document Type: Article

References (43)

1. Corain, B.; Schmid, G.; Toshima, N. Metal Nanoclusters in Catalysis and Material Sciences-The Issue of Size Control, 1 st ed.; Elsevier B.V.: Amsterdam, 2008.
2. Burda, C.; Chen, X.; Narayanan, R.; El-Sayed, M. A. The Chemistry and Properties of Nanocrystals of Different Shapes Chem. Rev. 2005, 105, 1025-1102 (Pubitemid 40600877)
3. Bonet, F.; Delmas, V.; Grugeon, S.; Urbina, R. H.; Silvert, P.-Y.; Tekaia-Elhsissen, K. Synthesis of Monodisperse Au, Pt, Pd, Ru and Ir Nanoparticles in Ethylene Glycol Nanostruct. Mater. 1999, 11, 1277-1284
4. Skrabalak, S. E.; Wiley, B. J.; Kim, M.; Formo, E. V.; Xia, Y. On the Polyol Synthesis of Silver Nanostructures: Glycolaldehyde as a Reducing Agent Nano Lett. 2008, 8, 2077-2081
5. Chen, Y.; Liew, K. Y.; Li, J. Size-Controlled Synthesis of Ru Nanoparticles by Ethylene Glycol Reduction Mater. Lett. 2008, 62, 1018-1021
6. Liu, Z.; Shamsuzzoha, M.; Ada, E. T.; Reichert, W. M.; Nikles, D. E. Synthesis and Activation of Pt Nanoparticles with Controlled Size for Fuel Cell Electrocatalysts J. Power Sources 2007, 164, 472-480 (Pubitemid 46109215)
7. Roucoux, A.; Schulz, J.; Patin, H. Reduced Transition Metal Colloids: A Novel Family of Reusable Catalysts Chem. Rev. 2002, 102, 3757-3778 (Pubitemid 35350663)
8. Toshima, N.; Shiraishi, Y.; Teranishi, T.; Miyake, M.; Tominaga, T.; Watanabe, H.; Brijoux, W; Bönnemann, H.; Schmid, G. Various Ligand-Stabilized Metal Nanoclusters as Homogeneous and Heterogeneous Catalysts in the Liquid Phase Appl. Organomet. Chem. 2001, 15, 178-196 (Pubitemid 32174300)
9. Campelo, J. M.; Luna, D.; Luque, R.; Marinas, J. M.; Romero, A. A. Sustainable Preparation of Supported Metal Nanoparticles and Their Applications in Catalysis ChemSusChem 2009, 2, 18-45
10. Koebel, M. M.; Jones, L. C.; Somorjai, G. A. Preparation of Size-Tunable, Highly Monodisperse PVP-Protected Pt-Nanoparticles by Seed-Mediated Growth J. Nanopart. Res. 2008, 10, 1063-1069
11. Wang, Y.; Ren, J.; Deng, K.; Gui, L.; Tang, Y. Preparation of Tractable Platinum, Rhodium, and Ruthenium Nanoclusters with Small Particle Size in Organic Media Chem. Mater. 2000, 12, 1622-1627
12. Park, J.; Joo, J.; Kwon, S. G; Jang, Y.; Hyeon, T. Synthesis of Monodisperse Spherical Nanocrystals Angew. Chem., Int. Ed. 2007, 46, 4630-4660 (Pubitemid 46997457)
13. Rioux, R. M.; Song, H.; Hoefelmeyer, J. D.; Yang, P.; Somorjai, G. A. High-Surface-Area Catalyst Design: Synthesis, Characterization, and Reaction Studies of Platinum Nanoparticles in Mesoporous SBA-15 Silica J. Phys. Chem. B 2005, 109, 2192-2202
14. Teranishi, T.; Kurita, R.; Miyake, M. J. Shape Control of Pt Nanoparticles J. Inorg. Organomet. Polym. 2000, 10, 145-156 (Pubitemid 32401774)
15. Xia, Y.; Xiong, Y.; Lim, B.; Skrabalak, S. E. Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics Angew. Chem., Int. Ed. 2008, 48, 60-103
16. Song, H.; Kim, F.; Connor, S.; Somorjai, G. A; Yang, P. Pt Nanocrystals: Shape Control and Langmuir Blodgett Monolayer Formation J. Phys. Chem. B 2005, 109, 188-193 (Pubitemid 40120963)
17. Garcia-Gutierrez, D. I.; Gutierrez-Wing, C. E.; Giovanetti, L.; Ramallo-Lopez, J. M.; Requejo, F. G.; Jose-Yacaman, M. Temperature Effect on the Synthesis of Au-Pt Bimetallic Nanoparticles J. Phys. Chem. B 2005, 109, 3813-3821 (Pubitemid 40402259)
18. Rioux, R. M.; Song, H.; Yang, P.; Somorjai, G. A. Platinum Nanoclusters' Size and Surface Structure Sensitivity of Catalytic Reactions. In Metal Nanoclusters in Catalysis and Material Sciences: The Issue of Size Control, 1 st ed.; Corain, B.; Schmid, G.,; Toshima, N., Eds.; Elsevier B.V.: Amsterdam, 2008; Chapter 7.
19. Nandanwar, S. U.; Chakraborty, M.; Mukhodadhyay, S.; Shenov, K. T. Stability of Ruthenium Nanoparticles Synthesized by Solvothermal Method Cryst. Res. Technol. 2011, 46, 393-399
20. Chen, J.; Herricks, T.; Geissler, M.; Xia, Y. J. Single Crystal Nanowires of Platinum can be Synthesized by Controlling the Reaction Rate of a Polyol Process J. Am. Chem. Soc. 2004, 126, 10854-10855 (Pubitemid 39180565)
21. Bock, C.; Paquet, C.; Couillard, M.; Botton, G. A.; MacDougall, B. R. Size-Selected Synthesis of PtRu Nano-Catalysts: Reaction and Size Control Mechanism J. Am. Chem. Soc. 2004, 126, 8028-8037 (Pubitemid 38812794)
22. Hatakeyama, Y.; Okamoto, M.; Torimoto, T.; Kuwabata, S.; Nishikawa, K. Small-Angle X-ray Scattering Study of Au Nanoparticles Dispersed in the Ionic Liquids 1-Alkyl-3-methylimidazolium Tetrafluoroborate J. Phys. Chem. C 2009, 113, 3917-3922
23. Svergun, D. I.; Stykova, E. V.; Dembo, A. T.; Bronstein, L. M.; Platonova, O. A.; Yakunin, A. N.; Valetsky, P. M; Khokhlov, A. R. Size Distribution of Metal Nanoparticles in Polyelectrolyte Gels J. Chem. Phys. 1998, 109, 11109-11116 (Pubitemid 128675161)
24. Steinfeldt, N.; Sebek, M.; Jähnisch, K. Liquid Phase Hydrogenation of Methyl-N-Boc-pyrrole-2-carboxylate over Tailored Ru Nanoparticles J. Catal. 2012, 289, 249-258
25. 4 Conversion to Syngas. ChemCatChem 2012, 4, 1368-1375.
26. Abecassis, B.; Testard, F.; Spalla, O.; Barboux, P. Probing in Situ the Nucleation and Growth of Gold Nanoparticles by Small-Angle X-ray Scattering Nano Lett. 2007, 7, 1723-1727 (Pubitemid 47140452)
27. Tanaka, H.; Koizumi, S.; Hashimoto, T.; Itoh, H.; Satoh, M.; Naka, K.; Chujo, Y. Combined in Situ and Time-Resolved SANS and SAXS Studies of Chemical Reactions at Specific Sites and Self-Assembling Processes of Reaction Products: Reduction of Palladium Ions in Self-Assembled Polyamidoamine Dendrimers as a Template Macromolecules 2007, 40, 4327-4337 (Pubitemid 47012590)
28. Smith, M. C.; Gilbert, J. A.; Mawdsley, J. R.; Seifert, S.; Myers, D. J. In Situ Small-Angle X-ray Scattering Observation of Pt Catalyst Particle Growth During Potential Cycling J. Am. Chem. Soc. 2008, 130, 8112-8113 (Pubitemid 351898506)
29. Hashimoto, T.; Saijo, K.; Harada, M.; Toshima, N. Small-Angle X-ray Scattering Analysis of Polymer-Protected Platinum, Rhodium, and Platinum/Rhodium Colloidal Dispersions J. Chem. Phys. 1998, 109, 5627-5638 (Pubitemid 128678737)
30. Glatter, O. A New Method for the Evaluation of Small-Angle Scattering Data J. Appl. Crystallogr. 1977, 10, 415-421
31. Glatter, O. Evaluation of Small-Angle Scattering Data from Lamellar and Cylindrical Particles by the Indirect Transformation Method J. Appl. Crystallogr. 1980, 13, 577-584
32. Glatter, O.; Kratky, O. Small-Angle X-ray Scattering; Academic Press: London, 1982.
33. Guinier, A.; Fournet, G. Small-Angle Scattering of X-rays; Wiley: New York, 1955.
34. Turkevich, J.; Stevenson, P. C.; Hillier, J. A Study of the Nucleation and Growth Processes in the Synthesis of Colloidal Gold Discuss. Faraday Soc. 1951, 11, 55-75
35. Duff, D. G.; Edwards, P. P.; Johnson, B. F. G. Formation of a Polymer-Protected Platinum Sol: A New Understanding of the Parameters Controlling Morphology J. Phys. Chem. 1995, 99, 15934-15944
36. 4 in Aqueous Solution: A First Principles Study J. Am. Chem. Soc. 2001, 123, 7371-7380 (Pubitemid 32879454)
37. shell Bimetallic Nanoparticles J. Phys. Chem. C 2008, 112, 19922-19929
38. 2: Effects of Citrate and NaOH and Reaction Mechanism J. Phys. Chem. B 2000, 104, 6767-6772
39. Yang, J.; Deivaraj, T. C.; Too, H.-P.; Lee, J. Y. Acetate Stabilization of Metal Nanoparticles and its Role in the Preparation of Metal Nanoparticles in Ethylene Glycol Langmuir 2004, 20, 4241-4245
40. Chang, S. C.; Ho, Y.; Weaver, M. J. Applications of Real-Time FTIR Spectroscopy to the Elucidation of Complex Electroorganic Pathways: Electrooxidation of Ethylene Glycol on Gold, Platinum, and Nickel in Alkaline Solution J. Am. Chem. Soc. 1991, 113, 9506-9513
41. Ciacchi, L. C.; Mertig, M.; Pompe, W.; Meriani, S.; De Vita, A. Nucleation and Growth of Platinum Clusters in Solution and on Biopolymers Platinum Met. Rev. 2003, 47, 98-107
42. Tao, A. R.; Habas, S.; Yang, P. Shape Control of Colloidal Metal Nanocrystals Small 2008, 4, 310-325 (Pubitemid 351424026)
43. Ott, L. S.; Finke, R. G. Transition-Metal Nanocluster Stabilization for Catalysis: A Critical Review of Ranking Methods and Putative Stabilizers Coord. Chem. Rev. 2007, 251, 1075-1100