A case study of chlorine transport and fate following a large accidental release

Atmospheric Environment

Volumn 62, Issue , 2012, Pages 184-198

  Buckley, Robert L ^a   Hunter, Charles H ^a   Werth, David W ^a   Whiteside, Morgana T ^a   Chen, Kuo Fu ^a   Mazzola, Carl A ^b  

^a SAVANNAH RIVER NATIONAL LABORATORY   (United States)

^b Shaw Environmental Inc   (United States)

Author keywords

Absorption; Atmospheric modeling; Chlorine release; Deposition velocity; Dispersion

Indexed keywords

A-TRAIN; ACCIDENTAL RELEASE; ADJACENT SURFACES; ATMOSPHERIC CONDITIONS; ATMOSPHERIC CONSTITUENTS; ATMOSPHERIC MODELING; CHLORINE RELEASE; COMPREHENSIVE MODELING; DEPOSITION VELOCITIES; EXCHANGE MECHANISM; HENRY'S LAW; HUMAN HEALTH EFFECTS; LOCAL SURFACES; MAN-MADE STRUCTURES; MODELING RESULTS; SOUTH CAROLINA; TOXICOLOGICAL HAZARDS; VAPOR CLOUD; VEGETATION DAMAGE;

ABSORPTION; ATMOSPHERIC MOVEMENTS; DISPERSION (WAVES); MODELS; SURFACE WATERS; VAPORS; VEGETATION;

CHLORINE;

CHLORINE;

ABSORPTION; ACCIDENT; ANIMAL; ATMOSPHERIC DEPOSITION; ATMOSPHERIC POLLUTION; CHLORINE; DILUTION; DISPERSION; FISH; MIXING; MORTALITY; POLLUTANT TRANSPORT; PUBLIC HEALTH; SPATIOTEMPORAL ANALYSIS; TOXICOLOGY;

AQUATIC ENVIRONMENT; ARTICLE; ATMOSPHERIC DEPOSITION; ATMOSPHERIC DISPERSION; ATMOSPHERIC TRANSPORT; CHEMICAL REACTION; ENVIRONMENTAL IMPACT ASSESSMENT; ENVIRONMENTAL RELEASE; FLOW RATE; METEOROLOGICAL PHENOMENA; PRIORITY JOURNAL; SIMULATION; SUNLIGHT; TRAFFIC ACCIDENT; VAPOR;

SOUTH CAROLINA; UNITED STATES;

ANIMALIA;

EID: 84865975420     PISSN: 13522310     EISSN: 18732844     Source Type: Journal    
DOI: 10.1016/j.atmosenv.2012.08.025     Document Type: Article

References (72)

1. Aietat E.M., Roberts P.V. Application of mass-transfer theory to the kinetics of a fast gas-liquid reaction: chlorine hydrolysis. Environmental Science and Technology 1986, 20:44-50.
2. Allen D.E., Thomason C.S. Fish Kill Investigation Graniteville Chlorine Spill Fish Kill Investigation in the Horse Creek System in Aiken County, SC January 7, 2005 through January 24, 2005 2005, Division of Wildlife and Freshwater Fisheries, South Carolina Department of Natural Resources, EPA-005706.
3. Alper E. Gas absorption with second-order reaction-comparison of approximate enhancement factor equations. Chemical Engineering Science 1973, 28(11):2092-2093.
4. Avissar R., Eloranta E.W., Gürer K., Tripoli G.J. An evaluation of the large-eddy simulation option of the Regional Atmospheric Modeling System in simulating a convective boundary layer: a FIFE case study. Journal of Atmospheric Sciences 1998, 55:1109-1130.
5. Benjamin S.G., Grell G., Brown J.M., Smirnova T.G., Bleck R. Mesoscale weather prediction with the RUC hybrid isentropic-terrain-following coordinate model. Monthly Weather Review 2004, 132:473-494.
6. Blanton J.O., Garrett A.J., Bollinger J.S., Hayes D.W., Koffman L.D., Amft J. Transport and dispersion of a conservative tracer in coastal waters with large intertidal areas. Estuaries and Coasts 2009, 32(3):573-592.
7. Britter R., Weil J., Leung J., Hanna S. Worked Examples Using Improved Source Emission Models, Draft Task 5 Report Under the Project: Toxic Industrial Chemical (TIC) Source Emissions Model Improvements March 31, 2009, Hanna Consultants, Prepared for Defense Threat Reduction Agency, Contract Number HDTRA1-07-C-0082, Report Number P098-5.
8. Britter R., Weil J., Leung J., Hanna S. Toxic industrial chemical (TIC) source emissions modeling for pressurized liquefied gases. Atmospheric Environment 2010, 45:1-25.
9. Brunson R.J., Wellek R.M. Determination of enhancement factor for mass transfer with an instantaneously fast chemical reaction. Chemical Engineering Science 1970, 25(5):904.
10. Buckley R.L., Kurzeja R.J. An observational and numerical study of the nocturnal sea breeze. Part I: structure and circulation. Journal of Applied Meteorology 1997, 36:1577-1598.
11. Buckley R.L., Hunter C.H., Addis R.P., Parker M.J. Modeling dispersion from toxic gas released after a train collision in Graniteville, SC. Journal of the Air and Waste Management Association 2007, 57:268-278.
12. Chang J.C., Franzese P., Chayantrakom K., Hanna S.R. Evaluations of CALPUFF, HPAC, and VLSTRACK with two mesoscale field datasets. Journal of Applied Meteorology 2003, 42:453-466.
13. Cooke S.J., Schreer J.F. Additive effects of chlorinated biocides and water temperature on fish in thermal effluents with emphasis on the Great Lakes. Reviews in Fisheries Science 2010, 9:69-113.
14. Cotton W.R., Tripoli G.J., Rauber R.M., Mulvihill E.A. Numerical simulation of the effects of varying ice crystal nucleation rates and aggregation processes on orographic snowfall. Journal of Climate and Applied Meteorology 1986, 25:1658-1680.
15. Cox R.M., Sontowski J., Fry R.N., Dougherty C.M., Smith T.J. Wind and diffusion modeling for complex terrain. Journal of Applied Meteorology 1998, 37(10):996-1009.
16. Cox R.M., Sontowski J., Dougherty C.M., Boutet C.J. The use of diagnostic and prognostic windfields for atmospheric transport calculations: an evaluation of the DIPOLE EAST 169 field experiment. Meteorological Applications 2003, 10:151-164.
17. Defense Threat Reduction Agency (DTRA) Hazard Prediction and Assessment Capability, On-Line Help, Version 5.0 January 2008, For further information contact DTRA, Operational Applications Division Consequence Branch (TDOC) at (703) 767-3419.
18. Dillon E.B. The role of deposition in limiting the hazard extent of dense-gas plumes. Journal of Hazardous Materials 2009, 164:1293-1303.
19. Environmental Protection Agency (EPA) Human Health Risk Assessment Protocol for Hazardous Waste Combustion Facilities 2005, Office of Solid Waste and Emergency Response, United States Environmental Protection Agency, EPA530-R-05-006 (Chapter 3).
20. Environmental Protection Agency (EPA) AERSURFACE User's Guide 2008, U.S. EPA Office of Air Quality Planning and Standards, EPA-454/B-08-001.
21. Environmental Protection Agency (EPA) Acute Exposure Guideline Levels 2008, (accessed 10.07.12.). http://www.epa.gov/oppt/aegl/pubs/chemlist.htm.
22. Federal Emergency Management Agency (FEMA) Guidelines and Specifications for Flood Mapping Partners. Appendix A: Guidance for Aerial Mapping and Surveying 2003, (accessed 10.07.12.). http://www.fema.gov/plan/prevent/fhm/dl_cgs.shtm.
23. Gabriel P., Harrington J., Stephens G., Schneider T. Adjoint perturbation method applied to two-stream radiative transfer. Journal of Quantitative Spectroscopy and Radiative Transfer 1998, 59(112):1-24.
24. Garrett A.J., Murphy C.E. A PUFF-PLUME Atmospheric Deposition Model for Use at SRP in Emergency Response Situations 1981, DP-1595.
25. Garrett, A.J., Bollinger, J.S., Hayes, D.W., 2005. Analysis of Tritium Transport in Flooded South Carolina Savannah River Floodplain, ANS 2005 Winter Meeting, Washington, DC, November 13-17.
26. Goodwin B.S., Donaho J.C. Tropical storm and hurricane recovery and preparedness strategies. Institute for Laboratory Animal Research Journal 2010, 51:104-119.
27. Hanna, S.R., Chang, J.C., White, J.M., Bowers, J.F., 2007. Evaluation of the HPAC Dispersion Model with the Joint Urban 2003 (JU2003) Tracer Observations, Urban Environment. 7th Symposium on the Urban Environment (Paper 10.1), American Meteorological Society, 10-13 September 2007, San Diego, California (United States). AMS Headquarters, 45 Beacon Street, Boston, MA 02108-3693, United States.
28. Hanna S., Dharmavaram J., Zhang J., Sykes I., Witlox H., Khajehnajafi S., Koslan K. Comparison of six widely-used dense gas dispersion models for three recent chlorine railcar accidents. Process Safety Progress 2008, 27(3):248-259.
29. Hanna, S., Hendrick, E., Santos, L., Reen, B., Stauffer, D., Deng, A.J., McQueen, J., Tsidulko, M., Janjic, Z., Sykes, R.I., 2008b. Comparison of observed, MM5 and WRF-NMM model-simulated, and HPAC-assumed boundary-layer meteorological variables for three days during the IHOP field experiment. In: 15th Joint Conference on Applications of Air Pollution Meteorology with the A&WMA (Paper 1.2), American Meteorological Society 88th Annual Meeting, 20-24 January 2008, New Orleans, Louisiana (United States). AMS Headquarters, 45 Beacon Street, Boston, MA 02108-3693, United States.
30. Hanna S., Chang J. Gaps in toxic industrial chemical (TIC) model systems. Croatian Meteorological Journal 2008, 43(43):13-18.
31. Hill, A.C., Chamberlain Jr., E.M., 1974. The removal of water soluble gases from the atmosphere by vegetation. In: ERDA Symposium Series 38, Atmosphere-Surface Exchange of Particulate and Gaseous Pollutants. Coordinators: Engelmann, R.J., U.S. Atomic Energy Commission and Sehmel, G.A., Battelle, PNNL.
32. International Program of Chemical Safety (IPCS) IPCS INCHEM Database for Chlorine, Poisons Information Monographs (PIM) 947 1998, Available online at:, (accessed 10.07.12.). http://www.inchem.org/documents/pims/chemical/pim947.htm.
33. Islam M.R., Kalam M.R., Khan M.R. Reactive gas solubility in water: an empirical relation. Industrial and Engineering Chemistry Research 2000, 39:2627-2630.
34. Kohl A.L., Nielsen R.B. Gas Purification 1997, Gulf Professional Publishing.
35. Kuo H. Further studies of the parameterization of the influence of cumulus convection on large-scale flow. Journal of Atmospheric Sciences 1974, 31:1232-1240.
36. Leaist D.G. Absorption of chlorine into water. Journal of Solution Chemistry 1986, 15(10):827-838.
37. Li Y., Vodacek A., Raqueno N., Kremens R., Garrett A.J., Bosch I., Makarewicz J.C., Lewis T.W. Circulation and stream plume modeling in Conesus lake. Environmental Modeling and Assessment 2007, 10.1007/s10666-007-9090x.
38. MacKay D., Matsunaga R. Evaporation rates of liquid hydrocarbon spills on land and water. Journal of Chemical Engineering 1973, 51:434-439.
39. MacKay D., Yeun A. Mass transfer coefficient correlations for volatilization of organic solutes from water. Environmental Science and Technology 1983, 17:211-217.
40. Mellor G.L., Yamada T. A hierarchy of closure models for planetary boundary layers. Journal of Atmospheric Sciences 1974, 31:1791-1806.
41. Merchuk J.C. Further considerations on enhancement factor for oxygen absorption into fermentation broth. Biotechnology and Bioengineering 1977, 19(12):1885-1889.
42. Meyers M.P., DeMott P.J., Cotton W.R. New primary ice nucleation parameterizations in an explicit cloud model. Journal of Applied Meteorology 1992, 31:708-721.
43. National Transportation Safety Board (NTSB), 2005. Collision of Norfolk Southern Freight Train 192 with Standing Norfolk Southern Local Train P22 with Subsequent Hazardous Materials Released at Graniteville, South Carolina, January 6, 2005. Railroad Accident Report, ID: NTSB/RAR-05/04, PB2005-916304, Notation 7710A, Adopted November 29, 2005.
44. O'Steen B.L., Werth D.W. The application of an evolutionary algorithm to the optimization of a mesoscale meteorological model. Journal of Applied Meteorology and Climatology 2009, 48(2):317-329.
45. Perry R.H., Perry J.H., Chilton C.H., Kirkpatrick S.D. Chemical Engineers' Handbook 1963, McGraw-Hill.
46. Perry R.H., Pigford R.L. Kinetics of gas-liquid reactions - simultaneous absorption and chemical reaction. Industrial and Engineering Chemistry 1953, 45(6):1247-1253.
47. Pielke R.A., Cotton W.R., Walko R.L., Tremback C.J., Lyons W.A., Grasso L.D., Nicholls M.E., Moran M.D., Wesley D.A., Lee T.J., Copeland J.H. A comprehensive meteorological modeling system-RAMS. Meteorology and Atmospheric Physics 1992, 49:69-91.
48. Reynolds M.R. ALOHA (Areal Locations of Hazardous Atmospheres) 5.0 Theoretical Description. NOAA Technical Memorandum NOS ORCA-65 1992, Seattle, Washington (United States).
49. Roseboom D.P., Richey D.L. Acute Toxicity of Residual Chlorine and Ammonia to Some Native Illinois Fishes 1977, ISWS/RI-85/77, Illinois State Water Survey, Urbanna, IL.
50. Sada E., Kumazawa H. Variation of enhancement factor in gas absorption with order of chemical-reaction. Chemical Engineering Science 1974, 29(2):335-338.
51. Sander R. Compilation of Henry's Law Constants for Inorganic and Organic Species of Potential Importance in Environmental Chemistry 1999, Available online at:, (accessed 10.07.12.). http://www.ceset.unicamp.br/%7Emariaacm/ST405/Lei%252520de%252520Henry.pdf.
52. Sehmel G.A. Deposition and resuspension. Chapter 12 in Atmospheric Science and Power Production, DOE/TIC-27601 1984, 533-583. D. Randerson (Ed.).
53. Sikora E.J., Chappelka A.H. Air Pollution Damage to Plants 1996, ACES Publications, ANR-0913: Alabama Cooperative Extension System, 1996. Available online at:, (accessed 10.07.12.). http://www.aces.edu/pubs/docs/A/ANR-0913/ANR-0913.pdf.
54. Smagorinsky J. General circulation experiments with the primitive equations. part I, the basic experiment. Monthly Weather Review 1963, 91:99-164.
55. South Carolina Department of Health and Environmental Control (SCDHEC) Graniteville, SC Train Derailment and Chlorine Release: Lessons Learned, Michael Spradlin 2006, Available online at:, (accessed 10.07.12.). http://www.astswmo.org/Files/Meetings/2006/2006-Hazardous_Waste_Conference/Chlorine-Gas-Train-Derailment-and-Cleanup.pdf.
56. Southworth G.R. The role of volatilization in removing polycyclic aromatic hydrocarbons from aquatic environments. Bulletin of Environmental Contamination and Toxicology 1979, 21:507-514.
57. Springer C., Lunney P.D., Valsaraj K.T. Emission of Hazardous Chemicals from Surface and Near Surface Impoundments to Air 1984, USEPA Solid and Hazardous Waste Research Division, Proj. Num. 808161-02.
58. Stull R.B. An Introduction to Boundary Layer Meteorology 1988, Kluwer Academic Publishers, Dordrecht, The Netherlands.
59. Sykes R.I., Parker S.F., Henn D.S. Numerical simulation of ANATEX tracer data using a turbulence closure model for long-range dispersion. Journal of Applied Meteorology 1993, 32:929-947.
60. Sykes R.I., Henn D.S. Representation of velocity gradient effects in a Gaussian puff model. Journal of Applied Meteorology 1995, 34:2715-2723.
61. Sykes R.I., Parker S.F., Henn D.S., Cerasoli C.P., Santos L.P. PC-SCIPUFF Version 1.2PD Technical Documentation 1998, Titan Corporation, P. O. Box 2229, Princeton, New Jersey, United States.
62. Sykes R.I., Parker S.F., Henn D.S. SCIPUFF Version 2.1 Technical Documentation 2004, Titan Corporation, P. O. Box 2229, Princeton, New Jersey, United States.
63. Tata P., Witherspoon J., Lue-Hing C. VOC Emissions from Wastewater Treatment Plants: Characterization, Control, and Compliance 2003, CRC.
64. Thibodeaux Environmental Chemodynamics, Movement of Chemicals in Air, Water, and Soil 1996, John Wiley and Sons, New York.
65. United States Geological Survey (USGS Light Detection and Ranging (LIDAR) Viewer 2006, Available online at:, (accessed 10.07.12.). http://lidar.cr.usgs.gov/LIDAR_Viewer/.
66. United States Geological Survey, USGS, 2009a. Available online at: (accessed 10.07.12.). http://waterdata.usgs.gov/nwis/dv/%3fsite_no%3d02196690%26agency_cd%3dUSGS%26referred_module%3dsw.
67. United States Geological Survey, USGS, 2009b. Available online at: (accessed 10.07.12.). http://waterdata.usgs.gov/nwis/dv/%3fsite_no%3d02196689%26agency_cd%3dUSGS%26referred_module%3dsw.
68. Van Sickle D., Wenck M.A., Belflower A., Drocuick D., Ferdinands J. Panel classification of self-reported exposure histories: a useful exposure index after a mass-casualty event. Public Health Reports 2007, 122.
69. Van Sickle D., Wenck M.A., Belflower A., Drocuick D., Ferdinands J., Holguin F., Svendsen E., Bretous L., Jankelevich S., Gibson J.J., Garbe P., Moolenaar R.L. Acute health effects after exposure to chlorine gas after a train derailment. The American Journal of Emergency Medicine 2009, 27.
70. Vivian J.E., Whitney R.P. Absorption of chlorine in water. Chemical Engineering Progress 1947, 43(12):691-702.
71. Walko R.L., Band L.E., Baron J., Kittel T.G.F., Lammers R., Lee T.J., Ojima D., Pielke R.A., Taylor C., Tague C., Tremback C.J., Vidale P.L. Coupled atmosphere-biophysics-hydrology models for environmental modeling. Journal of Applied Meteorology 2000, 39:931-944.
72. Wenck M.A., Van Sickle D., Drocuik D., Bellflower A., Youngblood C., Whisnant M.D., Taylor R., Rudnick V., Gibson J.J. Rapid assessment of exposure to chlorine released from a train derailment and resulting impact to health. Public Health Reports 2007, 122.