Pathways and reaction products for the oxidative degradation of CO2 loaded and concentrated aqueous MEA and MEA/MDEA mixtures during CO2 absorption from flue gases

Greenhouse Gas Control Technologies

Volumn , Issue , 2005, Pages 1159-1164

  Lawal, Olanike ^a   Bello, Adeola ^a   Idem, Raphael ^a  

^a UNIVERSITY OF REGINA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84865963302     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1016/B978-008044704-9/50122-1     Document Type: Chapter

References (22)

1. Charkravarty T., Phukan U.K., Weiland R.H. Reaction of acid gases with mixtures of amines. Chem. Eng. Prog. 1985, Vol. 81:32-36.
2. 2 removal by amine blends. Paper presented at the AICHE spring National meeting 1989.
3. 2 solubility in aqueous mixture of MDEA and MEA or DEA. Ind. Eng. Chem. Res. 1991, vol. 30(No. 3):543-555.
4. Dawodu O.F., Meisen A. Degradation of alkanolamine blends by carbon dioxide. J. Chem. Eng. 1996, Vol. 74:960-962.
5. 2 absorption into aqueous MDEA and MDEA/MEA solutions. Paper No. 43e, presented at A.I.Ch.E. National Meeting 1987.
6. Versteeg G.F., Kuipers J.A.M., van Beckum F.P.H., van Swaaij W.P.M. Mass transfer with complex reversible chemical reactions-II. Parallel reversible. Chem. Eng. Sci. 1990, vol. 45:183-197.
7. 2 into aqueous tertiary amine and/MEA solutions. Can. J. Chem. Eng. 1992, Vol. 70:482-500.
8. Hagewiesche D.P., Ashour S.S., Al-ghewas A.H., Sandall O.C. Absorption of carbon dioxide into aqueous blends of monoethanolamine and N-methyldiethanol amine. Chem. Eng. Sci. 1995, vol. 50(No. 7):1071-1079.
9. Liao C.H., Li M.H. Kinetics of absorption of carbon dioxide into aqueous solutions of monoethanolamine reactions. Chem. Sci. 2002, vol. 45:183-197.
10. Rooney P.C., Dupart M.S., Bacon T.R. Oxygen's role in alkanolamine degradation. Hydrocarbon Processing 1998, July:109-113.
11. Kindrick R.C., Atwood K., Arnold M.R. The relative resistance to oxidation of commercially available amines. Girdler Report No. T2.15-1-30 1950, 1950. in Report: Carbon dioxide absorbents, Contract No. Nobs-50023, by Girdler Corp, for The Navy Department, Bureau of Ships, Washington 25, DC (Code 649P), June 1, Gas Processes Division, Louisville, KY.
12. th Edition 1997, Gulf Publishing, Houston, Texas, USA.
13. Blanc C., Grall M., Demarais G. The part played by degradation products in the corrosion of gas sweetening plants using DEA and MDEA. Proc. Gas Conditioning Conference, University of Oklahoma 1982, vol. 32. No. 3.
14. Lloyd W.G., Taylor F.T. Corrosion by deterioration of glycol and glycol-amine. Ind. Eng. Chem. 1954, Vol. 46:2407-2416.
15. Supap T., Idem R., Veawab A., Aroonwilas A., Tontiwachwuthikul P., Chakma A., Kybett B. Kinetics of the oxidative degradation of aqueous MEA in a flue gas treating unit. Ind. Eng. Chem. Res. 2001, Vol. 40:3445-3450.
16. Hofmeyer B.G., Scholton H.G., Lloyd W.G. Contamination and corrosion in monoethanolamine gas treating solutions. Presented at the National Meeting of the American Chemical Society 1954.
17. 2 absorption from flue gas streams. Ind. Chem. Eng. 2004, submitted.
18. 2 absorption from flue gases. Ind. Chem. Eng. 2004, submitted.
19. 2 capture from flue gas of a coal - fired electric power generating station 2003, 1-80. U.S. Department of Energy, National Energy Laboratory, clean air technology division, Pittsburgh, PA, USA.
20. Polderman L.D., Dillon C.P., Steele A.B. Why MEA solution breaks down in gas treating service. Oil Gas J. 1950, 53:69-71.
21. Rochelle G.T. Oxidative degradation of monoethanolamine. Prepared for presentation at the first national conference on carbon sequestration 2001.
22. Chakma A., Meisen A. Identification of methyldiethanolamine degradation products by gas chromatography and gas chromatography-mass spectroscopy. Journal of chromatography 1998, 457.