Vibrational relaxation and vibration-rotation energy transfer between highly vibrationally excited KH(X 1σ +, v=14-21) and CO 2

Journal of Quantitative Spectroscopy and Radiative Transfer

Volumn 113, Issue 16, 2012, Pages 2081-2087

  Cui, Xiu hua ^a,b   Mu, Bao xia ^b   Shen, Yi fan ^b   Dai, Kang ^b  

^a XI'AN JIAOTONG UNIVERSITY   (China)

^b XINJIANG UNIVERSITY   (China)

Author keywords

CO 2; Doppler profile; Energy transfer; KH; Overtone pump; Rotational temperature

Indexed keywords

DOPPLER-PROFILE; ENERGY-TRANSFER RATE; KH; PUMP-PROBE CONFIGURATION; RATE COEFFICIENTS; RELAXATION RATES; ROTATIONAL ENERGY; ROTATIONAL TEMPERATURE; SINGLE-COLLISION; TRANSLATIONAL ENERGY; VIBRATIONAL LEVELS; VIBRATIONAL QUANTUM NUMBER; VIBRATIONAL RELAXATION; VIBRATIONAL STATE; VIBRATIONALLY EXCITED;

ENERGY TRANSFER; EXCITED STATES; MOLECULES; QUANTUM THEORY;

CARBON DIOXIDE;

CARBON DIOXIDE; DOPPLER EFFECT; ENERGY; SCATTERING; TEMPERATURE; VIBRATION;

EID: 84865743586     PISSN: 00224073     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jqsrt.2012.06.021     Document Type: Article

References (21)

1. Oref I, Tardy DC Energy transfer in highly excited large polyatomic molecules. Chem Rev 1990, 90:1407-1445.
2. Flynn GW, Parmenter CS, Wodtke AM Vibrational energy transfer. J Phys Chem 1996, 100:12817-12838.
3. Barker JR, Yoder LM, King KD Vibrational energy transfer modeling of nonequilibrium Polyatomic Reaction Systems. J Phys Chem A 2001, 105:796-809.
4. Sery ET, Muyskens MA, Lin Z, Flynn GW Competition between photochemistry and energy transfer in ultraviolet-excited diazabenzenes.3.photofragmentation and collisional quenching in mixtures of 2- methylpyrazine and carbon dioxide. J Phys Chem A 2000, 104:10538-10544.
5. -1).ΙΙ. Collisions with carbon dioxide. J Chem Phys 2002, 117:5221-5233.
6. 2: effect of donor vibrational mode. J Phys Chem A 2008, 112:1157-1167.
7. 2. J Phys Chem A 2002, 106:3642-3650.
8. 2. J Chem Phys 1998, 108:9658-9667.
9. 2. J Chem Phys 1999, 111:7373-7382.
10. 2. J Chem Phys 2008, 129:014303-1/11.
11. 3. J Chem Phys 1996, 105:4105-4116.
12. Silva M, Jongma R, Field RW, Wodtke AM The dynamics of stretched molecules: experimental studies of highly vibrationally excited molecules with stimulated emission pumping. Annu Rev Phys Chem 2001, 52:811-851.
13. 2 (v=19-28). Chem Phys 1993, 175:83-98.
14. 3 photodissociation. J Chem Phys 1994, 100:287-300.
15. 2→KH(v=0; J)+H: electronic orbital alignment effects. J Chem Phys 1999, 110:6743-6748.
16. Liu DK, Lin KC State-specific reaction and product energy disposal of electronically excited potassium with hydrogen molecule. J Chem Phys 1997, 107:4244-4252.
17. 2: reaction mechanism and product energy disposal. J Chem Phys 1996, 105:9121-9129.
18. Stwalley WC, Zemke WT, Yang SC Spectroscopy and structure of the alkali hydride diatomic molecules and their ions. J Phys Chem Ref Date 1991, 20:153-187.
19. 2. J Mol Spectrosc 1999, 193:204-212.
20. 2 at 780nm. J Quant Spectrosc Radiat Transf 2005, 96:289-299.
21. 1∑+, v'=5-22. J Chem Phys 1982, 77:3998-4005.