Spin crossover equation of state and sound velocities of (Mg 0.65Fe0.35)O ferropericlase to 140 GPa

Journal of Geophysical Research: Solid Earth

Volumn 117, Issue 8, 2012, Pages

  Chen, Bin ^a,b   Jackson, Jennifer M ^a   Sturhahn, Wolfgang ^a   Zhang, Dongzhou ^a   Zhao, Jiyong ^c   Wicks, June K ^a   Murphy, Caitlin A ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b UNIVERSITY OF MICHIGAN   (United States)

^c ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BULK MODULUS; CHONDRITE; CORE-MANTLE BOUNDARY; ELASTICITY; EQUATION OF STATE; IRON OXIDE; MAGNESIUM; PRESSURE EFFECT; PYROLITE; PYROXENITE; SOUND VELOCITY; VIBRATION;

EID: 84865710450     PISSN: 21699313     EISSN: 21699356     Source Type: Journal    
DOI: 10.1029/2012JB009162     Document Type: Article

References (63)

1. Angel, R. J. (2001), Equation of State, in High-Pressure, High-Temperature Crystal Chemistry, Rev. Mineral. Geochem., vol. 41, edited by R. M. Hazen and R. T. Downs, pp. 35-60, Mineral. Soc. of Am., Washington, D. C.
2. Antonangeli, D., J. Siebert, C. M. Aracne, D. L. Farber, A. Bosak, M. Hoesch, M. Krisch, F. J. Ryerson, G. Fiquet, and J. Badro (2011), Spin crossover in ferropericlase at high pressure: A seismologically transparent transition?, Science, 331(6013), 64-67.
3. Auzende, A. L., J. Badro, F. J. Ryerson, P. K. Weber, S. J. Fallon, A. Addad, J. Siebert, and G. Fiquet (2008), Element partitioning between magnesium silicate perovskite and ferropericlase: New insights into bulk lower-mantle geochemistry, Earth Planet. Sci. Lett, 269(1-2), 164-174.
4. Badro, J., G. Fiquet, F. Guyot, J. Rueff, V. V. Struzhkin, G. Vanko, and G. Monaco (2003), Iron partitioning in Earth's mantle: Toward a deep lower mantle discontinuity, Science, 300(5620), 789-791, doi:10.1126/science.1081311. (Pubitemid 36532112)
5. Bower, D. J., M. Gurnis, J. M. Jackson, and W. Sturhahn (2009), Enhanced convection and fast plumes in the lower mantle induced by the spin transition in ferropericlase, Geophys. Res. Lett, 36, L10306, doi:10.1029/2009GL037706.
6. Bower, D. J., J. K. Wicks, M. Gurnis, and J. M. Jackson (2011), A geody-namic and mineral physics model of a solid-state ultralow-velocity zone, Earth Planet. Sci. Lett, 303(3-4), 193-202.
7. Crowhurst, J. C, A. F. Goncharov, and J. M. Zaug (2004), Impulsive stimulated light scattering from opaque materials at high pressure, J. Phys. Condens. Matter, 16(14), 1137-1142.
8. Crowhurst, J. C, J. M. Brown, A. F. Goncharov, and S. D. Jacobsen (2008), Elasticity of (Mg,Fe)O through the spin transition of iron in the lower mantle, Science, 319(5862), 451-453. (Pubitemid 351160575)
9. Dziewonski, A. M., and D. L. Anderson (1981), Preliminary reference Earth model, Phys. Earth Planet. Inter., 25, 297-356.
10. Dziewonski, A. M, V. Lekic, and B. A. Romanowicz (2010), Mantle anchor structure: An argument for bottom up tectonics, Earth Planet. Sci. Lett, 299, 69-79.
11. Fei, Y., H.-K. Mao, and B. O. Mysen (1991), Experimental-determination of element partitioning and calculation of phase-relations in the MgO-FeO-SiO2 system at high-pressure and high-temperature, J. Geophys. Res., 96(B2), 2157-2169.
12. Fei, Y., H.-K. Mao, J. Shu, and J. Hu(1992), P-V-Tequationof stateof magnesiowüstite (Mg0.6Fe0.4)O, Phys. Chem. Miner., 18(7), 416-422.
13. Fei, Y., Y. Wang, and L. W. Finger (1996), Maximum solubility of FeO in (Mg,Fe)SiO3-perovskite as a function of temperature at 26 GPa: Implication for FeO content in the lower mantle, J. Geophys. Res., 101(B5), 11,525-11,530.
14. Fei, Y., L. Zhang, A. Corgne, H. Watson, A. Ricolleau, Y. Meng, and V. Prakapenka (2007), Spin transition and equations of state of (Mg Fe)O solid solutions, Geophys. Res. Lett., 34, L17307, doi:10.1029/2007GL030712. (Pubitemid 350065254)
15. Fiquet, G., A. L. Auzende, J. Siebert, A. Corgne, H. Bureau, H. Ozawa, and G. Garbarino (2010), Melting of peridotite to 140 gigapascals, Science, 329(5998), 1516-1518.
16. Garnero, E. J., and D. V. Helmberger (1995), A very slow basal layer underlying large-scale low-velocity anomalies in the lower mantle beneath the pacific: Evidence from core phases, Phys. Earth Planet. Inter., 91(1-3), 161-176. (Pubitemid 26455939)
17. Garnero, E. J., and A. K. McNamara (2008), Structure and dynamics of Earth's lower mantle, Science, 320(5876), 626-628. (Pubitemid 351928337)
18. Goncharov, A. F., V. V. Struzhkin, and S. D. Jacobsen (2006), Reduced radiative conductivity of low-spin (Mg, Fe) O in the lower mantle, Science, 312(5777), 1205-1207.
19. Helmberger, D. V., and S. Ni (2005), Seismic modeling constraints on the south African super plume, in Earth's Deep Mantle: Structure, Composition, and Evolution, Geophys. Monogr. Ser., vol. 160, edited by R. D. van der Hilst et al., pp. 63-81, AGU, Washington, D. C.
20. Irifune, T. (1994), Absence of an aluminous phase in the upper part of the Earth's lower mantle, Nature, 370(6485), 131-133.
21. Jackson, J. M., J. Zhang, and J. D. Bass (2004), Sound velocities and elasticity of aluminous MgSiO3 perovskite: Implications for aluminum heterogeneity in Earth's lower mantle, Geophys. Res. Lett., 31, L10614, doi:10.1029/2004GL019918. (Pubitemid 39102738)
22. Jackson, J. M., S. V. Sinogeikin, S. D. Jacobsen, H. J. Reichmann, S. J. Mackwell, and J. D. Bass (2006), Single-crystal elasticity and sound velocities of (Mg0.94Fe0.06)O ferropericlase to 20 GPa, J. Geophys. Res., 111, B09203, doi:10.1029/2005JB004052. (Pubitemid 46978483)
23. Jackson, J. M., E. A. Hamecher, and W. Sturhahn (2009), Nuclear resonant X-ray spectroscopy of (Mg,Fe)SiO3 orthoenstatites, Eur. J. Mineral., 21(3), 551-560.
24. Jacobsen, S. D., H. J. Reichmann, H. A. Spetzler, S. J. Mackwell, J. R. Smyth, R. J. Angel, and C. A. McCammon (2002), Structure and elasticity of single-crystal (Mg, Fe)O and a new method of generating shear waves for gigahertz ultrasonic interferometry, J. Geophys. Res., 107(B2), 2037, doi:10.1029/2001JB000490.
25. Jacobsen, S. D., C. M. Holl, K. A. Adams, R. A. Fischer, E. S. Martin, C. R. Bina, J. Lin, V. B. Prakapenka, A. Kubo, and P. Dera (2008), Compression of single-crystal magnesium oxide to 118 GPa and a ruby pressure gauge for helium pressure media, Am. Mineral., 93(11-12), 1823-1828, doi:10.2138/am.2008.2988.
26. Kobayashi, Y., T. Kondo, E. Ohtani, N. Hirao, N. Miyajima, T. Yagi, T. Nagase, and T. Kikegawa (2005), Fe-Mg partitioning between (Mg, Fe)SiO3 post-perovskite, perovskite, and magnesiowüstite in the Earth's lower mantle, Geophys. Res. Lett., 32, L19301, doi:10.1029/2005GL023257. (Pubitemid 41694232)
27. Komabayashi, T., K. Hirose, Y. Nagaya, E. Sugimura, and Y. Ohishi (2010), High-temperature compression of ferropericlase and the effect of temperature on iron spin transition, Earth Planet. Sci. Lett., 297(3-4), 691-699, doi:10.1016/j.epsl.2010.07.025.
28. Lin, J.-F., J. Shu, H.-K. Mao, R. J. Hemley, and G. Shen (2003), Amorphous boron gasket in diamond anvil cell research, Rev. Sci. Instr., 74, 4732.
29. Lin, J.-F., V. V. Struzhkin, S. D. Jacobsen, M. Y. Hu, P. Chow, J. Kung, H. Liu, H.-K. Mao, and R. J. Hemley (2005), Spin transition of iron in magnesiowustite in the Earth's lower mantle, Nature, 436, 377-380, doi:10.1038/nature03825. (Pubitemid 41059045)
30. Lin, J.-F., S. D. Jacobsen, W. Sturhahn, J. M. Jackson, J.-C. Zhao, and C.-S. Yoo (2006), Sound velocities of ferropericlase in the Earth's lower mantle, Geophys. Res. Lett., 33, L22304, doi:10.1029/2006GL028099. (Pubitemid 47386138)
31. Mao, Z., J.-F. Lin, J. Liu, and V. B. Prakapenka (2011), Thermal equation of state of lower-mantle ferropericlase across the spin crossover, Geophys. Res. Lett., 38, L23308, doi:10.1029/2011GL049915.
32. Marquardt, H., S. Speziale, H. J. Reichmann, D. J. Frost, F. R. Schilling, and E. J. Garnero (2009), Elastic shear anisotropy of ferropericlase in Earth's lower mantle, Science, 324(5924), 224-226.
33. Mattern, E., J. Matas, Y. Ricard, and J. Bass (2005), Lower mantle composition and temperature from mineral physics and thermodynamic modelling, Geophys. J. Int., 160, 973-990, doi:10.1111/j.1365-246X.2004.02549.x. (Pubitemid 40435977)
34. McNamara, A. K., and S. Zhong (2004), Thermochemical structures within a spherical mantle: Superplumes or piles, J. Geophys. Res., 109, B07402, doi:10.1029/2003JB002847. (Pubitemid 39306354)
35. McNamara, A. K., E. J. Garnero, and S. Rost (2010), Tracking deep mantle reservoirs with ultra-low velocity zones, Earth Planet. Sci. Lett., 299(1), 1-9.
36. Murakami, M., and J. D. Bass (2011), Evidence of denser MgSiO3 glass above 133 gigapascal (GPa) and implications for remnants of ultradense silicate melt from a deep magma ocean, Proc. Natl. Acad. Sci. U. S. A., 108(42), 17,286-17,289.
37. Murakami, M., K. Hirose, N. Sata, and Y. Ohishi (2005), Post-perovskite phase transition and mineral chemistry in the pyrolitic lowermost mantle, Geophys. Res. Lett., 32, L03304, doi:10.1029/2004GL021956. (Pubitemid 40578630)
38. Murakami, M., S. V. Sinogeikin, J. D. Bass, N. Sata, Y. Ohishi, and K. Hirose (2007a), Sound velocity of MgSiO3 post-perovskite phase: A constraint on the D" discontinuity, Earth Planet. Sci. Lett, 259(1-2), 18-23. (Pubitemid 46939595)
39. Murakami, M., S. V. Sinogeikin, H. Hellwig, J. D. Bass, and J. Li (2007b), Sound velocity of MgSiO3 perovskite to Mbar pressure, Earth Planet. Sci. Lett, 256(1-2), 47-54, doi:10.1016/j.epsl.2007.01.011. (Pubitemid 46359665)
40. Murakami, M., Y. Ohishi, N. Hirao, and K. Hirose (2009), Elasticity of MgO to 130 GPa: Implications for lower mantle mineralogy, Earth Planet. Sci. Lett, 277(1-2), 123-129.
41. Rivers, M., V. B. Prakapenka, A. Kubo, C. Pullins, C. M. Holl, and S. D. Jacobsen (2008), The COMPRES/GSECARS gas-loading system for diamond anvil cells at the Advanced Photon Source, High Pressure Res., 28(3), 273-292, doi:10.1080/08957950802333593.
42. Sakai, T., E. Ohtani, H. Terasaki, M. Miyahara, M. Nishijima, N. Hirao, Y. Ohishi, and N. Sata (2009), Fe-Mg partitioning between post-perovskite and ferropericlase in the lowermost mantle, Phys. Chem. Miner., 37(487-496), 1-10.
43. Schubert, G., G. Masters, P. Olson, and P. Tackley (2004), Superplumes or plume clusters?, Phys. Earth Planet. Inter., 146(1-2), 147-162. (Pubitemid 38889336)
44. Sinmyo, R., K. Hirose, D. Nishio-Hamane, Y. Seto, K. Fujino, N. Sata, and Y. Ohishi (2008), Partitioning of iron between perovskite/postperovskite and ferropericlase in the lower mantle, J. Geophys. Res., 113, B11204, doi:10.1029/2008JB005730.
45. Speziale, S., A. Milner, V. E. Lee, S. M. Clark, M. P. Pasternak, and R. Jeanloz (2005), Iron spin transition in Earth's mantle, Proc. Natl. Acad. Sci. U. S.A., 102(50), 17,918-17,922, doi:10.1073/pnas.0508919102. (Pubitemid 41798477)
46. Sturhahn, W. (2000), CONUSS and PHOENIX: Evaluation of nuclear resonant scattering data, Hyperfine Interact, 125(1), 149-172. (Pubitemid 32267454)
47. Sturhahn, W. (2004), Nuclear resonant spectroscopy, J. Phys. Condens. Matter, 16(5), 497-530.
48. Sturhahn, W., and J. M. Jackson (2007), Geophysical applications of nuclear resonant spectroscopy, Spec. Pap. Geol. Soc. Am., 421, 157-174, doi:10.1130/2007.2421(09).
49. Sturhahn, W., and V. G. Kohn (1999), Theoretical aspects of incoherent nuclear resonant scattering, Hyperfine Interact, 123(1-8), 367-399.
50. Sturhahn, W., J. M. Jackson, and J.-F. Lin (2005), The spin state of iron in minerals of the Earth's lower mantle, Geophys. Res. Lett, 32, L12307, doi:10.1029/2005GL022802. (Pubitemid 41398438)
51. Sun, D., D. Helmberger, S. Ni, and D. Bower (2009), Direct measures of lateral velocity variation in the deep Earth, J. Geophys. Res., 114, B05303, doi:10.1029/2008JB005873.
52. Sun, D., D. Helmberger, and M. Gurnis (2010), A narrow, mid-mantle plume below southern Africa, Geophys. Res. Lett, 37, L09302, doi:10.1029/2009GL042339.
53. Tan, E., and M. Gurnis (2005), Metastable superplumes and mantle compressibility, Geophys. Res. Lett., 32, L20307, doi:10.1029/2005GL024190. (Pubitemid 41782698)
54. Tan, E., and M. Gurnis (2007), Compressible thermochemical convection and application to lower mantle structures, J. Geophys. Res., 112, B06304, doi:10.1029/2006JB004505. (Pubitemid 47364489)
55. Thorne, M. S., and E. J. Garnero (2004), Inferences on ultralow-velocity zone structure from a global analysis of SPdKS waves, J. Geophys. Res., 109, B08301, doi:10.1029/2004JB003010. (Pubitemid 39428435)
56. Toellner, T. S. (2000), Monochromatization of synchrotron radiation for nuclear resonant scattering experiments, Hyperfine Interact, 125(1-4), 3-28. (Pubitemid 32273143)
57. van Westrenen, W., et al. (2005), Thermoelastic properties of (Mg0 64Fe0 36)O ferropericlase based on in situ X-ray diffraction to 26.7 GPa and 2173K, Phys. Earth Planet. Inter., 151(1-2), 163-176.
58. Wang, Y., and L. Wen (2007), Geometry and P and S velocity structure of the "African Anomaly," J. Geophys. Res., 112, B05313, doi:10.1029/2006JB004483.
59. Wentzcovitch, R. M., J. F. Justo, Z. Wu, C. R. S. da Silva, D. A. Yuen, and D. Kohlstedt (2009), Anomalous compressibility of ferropericlase throughout the iron spin cross-over, Proc. Natl. Acad. Sci. U. S. A., 106(21), 8447-8452.
60. Wentzcovitch, R. M., Z. Wu, and P. Carrier (2010), First principles quasi-harmonic thermoelasticity of mantle minerals, Rev. Mineral. Geochem., 71(1), 99-128.
61. Wicks, J. K., J. M. Jackson, and W. Sturhahn (2010), Very low sound velocities in iron-rich (Mg, Fe)O: Implications for the core-mantle boundary region, Geophys. Res. Lett, 37, L15304, doi:10.1029/2010GL043689.
62. Wu, Z., J. F. Justo, C. R. S. da Silva, S. de Gironcoli, and R. M. Wentzcovitch (2009), Anomalous thermodynamic properties in ferropericlase throughout its spin crossover, Phys. Rev. B, 80(1), 014409, doi:10.1103/ PhysRevB.80.014409.
63. Zhuravlev, K. K., J. M. Jackson, A. S. Wolf, J. K. Wicks, J. Yan, and S. M. Clark (2009), Isothermal compression behavior of (Mg,Fe)O using neon as a pressure medium, Phys. Chem. Miner., 37(7), 465-474, doi:10.1007/s00269-009- 0347-6.