Pre-intercalation of long chain fatty acid in the interlayer space of layered silicates and preparation of montmorillonite/natural rubber nanocomposites

Applied Clay Science

Volumn 67-68, Issue , 2012, Pages 50-56

  Rooj, Sandip ^a,c   Das, Amit ^a   Stöckelhuber, Klaus Werner ^a   Mukhopadhyay, Nabaneeta ^b   Bhattacharyya, Arup R ^b   Jehnichen, Dieter ^a   Heinrich, Gert ^a,c  

^a LEIBNIZ INSTITUTE OF POLYMER RESEARCH DRESDEN   (Germany)

^b INDIAN INSTITUTE OF TECHNOLOGY BOMBAY   (India)

^c DRESDEN UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

Exfoliation; Fatty acid; Intercalation; Nanocomposites; Natural rubber; Reinforcement

Indexed keywords

CARBON ATOMS; EXFOLIATION; INTERLAYER SPACES; LAYERED SILICATE; LONG CHAIN FATTY ACID; MORPHOLOGICAL DATA; NON-POLAR; ORGANO-MONTMORILLONITE; REINFORCING FILLERS; RUBBER NANOCOMPOSITES; TRANSMISSION ELECTRON MICROSCOPY TEM; WIDE-ANGLE X-RAY DIFFRACTION;

CLAY MINERALS; CONTACT ANGLE; FATTY ACIDS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; INTERCALATION; MECHANICAL PROPERTIES; NANOCOMPOSITES; REINFORCEMENT; SATURATED FATTY ACIDS; SILICATES; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

RUBBER;

COMPOSITE; FATTY ACID; FTIR SPECTROSCOPY; MONTMORILLONITE; RUBBER; SILICATE; TENSILE STRENGTH; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION;

EID: 84865479042     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2012.03.005     Document Type: Article

References (36)

1. Adams J.M. Synthetic organic chemistry using pillared, cation-exchanged and acid-treated montmorillonite catalysts - a review. Appl. Clay Sci. 1987, 2:309-342.
2. Aizenshtat Z., Miloslavsky I., Heller-Kallai L. The effect of montmorillonite on the thermal decomposition of fatty acids under "bulk flow" conditions. Org. Geochem. 1984, 7:85-90.
3. Beall G.W., Goss M. Self-assembly of organic molecules on montmorillonite. Appl. Clay Sci. 2004, 27:179-186.
4. Bergaya F., Jaber M., Lambert J.F.L. Organophylic clay minerals, chapter 2. Rubber-Clay Nanocomposites: Science, Technology and Applications 2011, 45-86. Wiley & Sons Inc. M. Galimberti (Ed.).
5. Brindley G.W. Complexes of primary amines with montmorillonite and vermiculite. Clay Miner. 1965, 6:91-96.
6. Brindley G.W., Ray S. Complexes of Ca-montmorillonite with primary monohydric alcohols (clay-organic studies VIII). Am. Mineral. 1964, 49:106-115.
7. Choi S.S., Kim I.-S. Filler-polymer interactions in filled polybutadiene compounds. Euro Polym. J. 2002, 38:1265-1269.
8. Das A., Jurk R., Stöckelhuber K.W., Heinrich G. Rubber curing chemistry governing the orientation of layered silicate. Express Polym Letters 2007, 1:717-729.
9. Das A., Jurk R., Stöckelhuber K.W., Majumder P.S., Engelhardt T., Fritzsche J., Klüpopel M., Heinrich G. Processing and properties of nanocomposites based on layered silicate and carboxylated nitrile rubber. J. Macromol. Sci. A Pure Appl. Chem. 2009, 46:7-15.
10. Das A., Stöckelhuber K.W., Jurk R., Jehnichen D., Heinrich G. A general approach to rubber-montmorillonite nanocomposites: Intercalation of stearic acid. Appl. Clay Sci. 2011, 51:117-125.
11. Fornes T.D., Paul D.R. Modeling properties of nylon 6/clay nanocomposites using composite theories. Polymer 2003, 44(17):4993-5013.
12. Gautier M., Muller F., Beny J.-M., Forestier L.L.E., Alberic P., Baillif P. Interactions of ammonium smectite with low-molecular-weight carboxylic acids. Clay Minerals 2009, 44:207-219.
13. Giannelis E.P. Polymer layered silicate nanocomposites. Adv. Mater. 1996, 8:29-35.
14. Gilman J.W. Flammability and thermal stability studies of polymer layered-silicate (clay) nanocomposites. Appl. Clay Sci. 1999, 15:31-49.
15. Huskic M., Zagar E., Zigon M., Brnardic I., Macan J., Ivankovic M. Modification of montmorillonite by cationic polyesters. Appl. Clay Sci. 2009, 43:420.
16. Jackson M.L. Interlayering of expansible layer silicates in soils by chemical weathering. Clays Clay Minerals 1963, 11:29-46.
17. Lagaly G., Barrer R.M., Goulding K. Clay-organic interactions. Philos. Trans. R. Soc. Lond. A 1984, 311:315-332.
18. Lagaly G. Reaktionen der tonmineral. Tonminerale und Tone 1993, 89-167. Steinkopff Verlag, Darmstadt. K. Jasmund, G. Lagaly (Eds.).
19. Li P., Yin L., Song G., Sun J., Wang L., Wang H. High-performance EPDM/organoclay nanocomposites by melt extrusion. Appl. Clay Sci. 2008, 40:38-44.
20. Lopez-Manchado M.A., Arroyo M., Herrero B., Biagiotti J. Vulcanization kinetics of natural rubber-organoclay nanocomposites. J. Appl. Polym. Sci. 2003, 89:1-15.
21. Mathew G., Huh M.Y., Rhee J.M., Lee M.H., Nah C. Improvement of properties of silica filled styrene-butadiene rubber composites through plasma surface modification of silica. Polym. Adv. Technol. 2004, 15:400-408.
22. Ma Y., Li Q.-F., Zhang L.-Q., Wu Y.-P. Role of stearic acid in preparing EPDM/clay nanocomposites by melt compounding. Polym. J. 2007, 39:48-54.
23. Moreno E., Cordobilla R., Calvet T., Cuevas-Diarte M.A., Gbabode G., Negrier P., Mondieig D., Oonk H.A.J. Polymorphism of even saturated carboxylic acids from n-decanoic to n-eicosanoic acid. New J. Chem. 2007, 31:947-957.
24. Norrish K., Quirk J. Crystalline swelling of montmorillonite. Nature 1954, 173:255-256.
25. Pojanavaraphan T., Schiraldi D.A., Magaraphan R. Mechanical, rheological, and swelling behavior of natural rubber/montmorillonite aerogels prepared by freeze-drying. Appl. Clay Sci. 2010, 50:271-279.
26. Rooj S., Das A., Thakur V., Mahaling R.N., Bhowmick A.K., Heinrich G. Preparation and properties of natural nanocomposites based on natural rubber and naturally occurring halloysite nanotubes. Mater. Design 2010, 31:2151-2156.
27. Rooj S., Das A., Heinrich G. Preintercalation of an organic accelerator into nanogalleries and preparation of ethylene propylene diene terpolymer rubber-clay nanocomposites. Polym. J. 2011, 243:285-292.
28. Rooj S., Das A., Stöckelhuber K.W., Reuter U., Heinrich G. Highly exfoliated natural rubber-clay composites by 'propping-open procedure': role of different fatty acid chain length on exfoliation. Macromol. Mater. Eng 2011, 10.1002/mame.201100185.
29. Sánchez-Martín M.J., Sánchez-Camazano M., Sayalero M.L., Dominguez-Gil A. Physicochemical study of the interaction of montmorillonite with hydralazine hydrochloride, a cardiovascular drug. Appl. Clay Sci. 1988, 3:53-61.
30. Stöckelhuber K.W., Das A., Jurk R., Heinrich G. Contribution of physico-chemical properties of interfaces on dispersibility, adhesion and flocculation of filler particles in rubber. Polymer 2010, 51:1954-1963.
31. Vaia R.A., Teukolsky R.K., Giannelis E.P. Interlayer structure and molecular environment of alkylammonium layered silicates. Chem. Mater. 1994, 6:1017-1022.
32. Viani B.E., Low P.F., Roth C.B. Direct measurement of the relation between interlayer force and interlayer distance in the swelling of montmorillonite. J. Colloid Interface Sci. 1983, 96:229-239.
33. Wang K.H., Xu M., Choi Y.S., Chung I.J. Effect of aspect ratio of clay on melt extensional process of maleated polyethylene/clay nanocomposites. Polym. Bull. 2001, 46:499-505.
34. Yariv S. Thermo IR-spectroscopy analysis of the interactions between organic pollutants and clay minerals. Thermochim. Acta 1996, 274:1-35.
35. Yariv S. Introduction to organo-clay complexes and interactions. Organo-clay complexes and interactions 2001, 39-111. Marcel Dekker, New York. S. Yariv, H. Cross (Eds.).
36. Yu Y., Gu Z., Song G., Li P., Li H., Liu W. Structure and properties of organo-montmorillonite/nitrile butadiene rubber nanocomposites prepared from latex dispersions. Appl. Clay Sci. 2011, 52:381-385.