Thermal and catalytic decomposition of aqueous ethylene glycol mixtures by film boiling

International Journal of Heat and Mass Transfer

Volumn 55, Issue 23-24, 2012, Pages 6425-6434

  Evangelista, John W ^a,b   Avedisian, C Thomas ^a   Tsang, Wing ^a,c  

^a Cornell University   (United States)

^b UNITED STATES MILITARY ACADEMY   (United States)

^c NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

Author keywords

Catalysis; Critical heat flux; Ethylene glycol; Film boiling; Heat transfer; Synthesis gas; Thermal decomposition

Indexed keywords

CARBON; CATALYSIS; CATALYSTS; COATINGS; DECOMPOSITION; ETHYLENE; EVAPORATION; HEAT FLUX; HEAT TRANSFER; MIXTURES; NICKEL; NICKEL COATINGS; PLATINUM; POLYOLS; PYROLYSIS; SYNTHESIS GAS; TUBES (COMPONENTS);

BUBBLE POINT TEMPERATURES; CARBON DEPOSITION; CATALYTIC DECOMPOSITION; CHEMICAL CONVERSIONS; FILM BOILING; HYDROCARBON VAPORS; PLATINUM CATALYSTS; SATURATION TEMPERATURE;

ETHYLENE GLYCOL;

EID: 84865420967     PISSN: 00179310     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijheatmasstransfer.2012.06.030     Document Type: Article

References (20)

1. S.R. Choi, J.W. Evangelista, C.T. Avedisian, W. Tsang, Experimental study of chemical conversion of methanol and ethylene glycol in a film boiling reactor, Int. J. Heat Mass Transfer 54 (2011) 500-511.
2. S.R. Choi, Experimental study of chemical conversion of organic liquids by film boiling, Ph.D Thesis, Cornell University, 2010.
3. J.W. Evangelista, An experimental demonstration of converting organic liquids and their aqueous solutions in a film boiling reactor, M.S. Thesis, Cornell University, 2010.
4. S.A. Zhukov, V.A. Rafeev, S. Yu, S.B. Afans'ev, S.B. Echmaev, B.L. Korsunksii, Singularities of realization of film boiling on wire heaters, High Temp. 41 (2003) 243-251.
5. B.J. Urban, C.T. Avedisian, W. Tsang, The film boiling reactor: a new environment for chemical processing, AIChE J. 52 (2006) 2582-2595. (Pubitemid 44013420)
6. P.N. Kechagiopoulos, S.S. Voutetakis, A.A. Lemonidou, I.A. Vasalos, Sustainable hydrogen production via reforming of ethylene glycol using a novel spouted bed reactor, Catal. Today 127 (2007) 246-255. (Pubitemid 47302279)
7. J.D. Bernardin, I. Mudawar, The leidenfrost point: experimental study and assessment of existing models, ASME J. Heat Transfer 121 (1999) 894-903.
8. S. Hafner, A. Rashidi, G. Baldea, U. Riedel, A detailed chemical kinetic model of high-temperature ethylene glycol gasification, Comb. Theor. Model. 15 (2011) 517-535.
9. V.A. Maroni, S.J. Epperson, An in situ infrared spectroscopic investigation of the pyrolysis of ethylene glycol encapsulated in silica sodalite, Vib. Spectrosc. 27 (2001) 43-51. (Pubitemid 32998179)
10. MEGlobal Group, Ethylene Glycol Product Guide, (2008). (see ).
11. C.T. Avedisian, J. Koplik, Leidenfrost boiling of methanol droplets on hot porous ceramic surfaces, Int. J. Heat Mass Transfer 30 (2) (1987) 279-293.
12. Special Metals Corp. 2008 Inconel Alloy 600. Publication Number SMC-027. ().
13. J.H. Lienhard IV, J.H. Lienhard V, A Heat Transfer Textbook, third ed., Phlogiston Press, Cambridge, MA, 2003. pp. 468-479.
14. R. McGillis, V.P. Carey, On the role of marangoni effects on the critical heat flux for pool boiling of binary mixtures, ASME J. Heat Transfer 118 (1996) 103-109. (Pubitemid 126539460)
15. T. Valliyappan, N.N. Bakhshi, A.K. Dalai, Pyrolysis of glycerol for the production of hydrogen or syngas, Bioresourse Technol. 99 (2008) 4476-4483. (Pubitemid 351380835)
16. E. Bruneton, B. Narch, B.A. Oberlin, Carbon-carbon composites prepared by a rapid densification process II: Structural and textural characterizations, Carbon 35 (1997) 1593.
17. H. Okuno, H.M. Trinquecoste, A. Derre, M. Monthioux, P. Delhaes, Catalytic effects on carbon/carbon composites fabricated by a film boiling chemical vapor infiltration process, J. Mater. Res. 17 (2002) 1904-1913. (Pubitemid 35009885)
18. D. Rouvillain, M. Trinquecoste, E. Bruneton, A. Derre, P. David, P. Delhaes, Film boiling chemical vapor infiltration: an experimental study on carbon/carbon composite materials, Carbon 39 (2001) 1355-1365. (Pubitemid 32535952)
19. Y. Zhang, M.N. Gamo, K. Nakagawa, T. Ando, Synthesis of aligned carbon nanotubes in organic liquids, J. Mater. Res. 17 (2002) 2457-2464. (Pubitemid 35236764)
20. Y.F. Zhang, M.N. Gamo, C.Y. Xiao, T. Ando, Liquid phase synthesis of carbon nanotubes, Physica B 323 (2002) 293-295. (Pubitemid 35019063)