Thermal and mechanical behaviour of self-curable waterborne hybrid polyurethanes functionalized with (3-aminopropyl)triethoxysilane (APTES)

Journal of Polymer Research

Volumn 19, Issue 9, 2012, Pages

  Sardon, H ^a   Irusta, L ^a   Santamaria P ^a   Fernandez Berridi M J ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

Author keywords

(3 aminopropyl)triethoxysilane; Mechanical properties; Thermal properties; Waterborne polyurethanes

Indexed keywords

MECHANICAL PROPERTIES; PHASE SEPARATION; PROPIONIC ACID; THERMODYNAMIC PROPERTIES;

ALIPHATIC DIISOCYANATE; ISOPHORONE DIISOCYANATE; MECHANICAL BEHAVIOUR; POLY(PROPYLENE GLYCOL); SEMI-CRYSTALLINE POLYESTERS; THERMAL AND MECHANICAL PROPERTIES; TRIETHOXYSILANE; WATERBORNE POLYURETHANE;

POLYURETHANES;

EID: 84865184858     PISSN: 10229760     EISSN: 15728935     Source Type: Journal    
DOI: 10.1007/s10965-012-9956-8     Document Type: Article

References (25)

1. Chattopadhyay DK, Webster DC (2009) Thermal stability and flame retardancy of polyurethanes. Prog Polym Sci 34:1068-1133
2. Nanda AK, Wicks DA (2006) The influence of the ionic concentration, concentration of the polymer, degree of neutralization and chain extension on aqueous polyurethane dispersions prepared by the acetone process. Polymer 47:1805-1811
3. Hepburn C (1993) Polyurethane elastomers, 2nd edn. Elsevier, London
4. Madhavan K, Gnanasekaran D, Reddy B (2011) Poly(dimethylsiloxane- urethane) membranes: effect of linear siloxane chain and caged silsesquioxane on gas transport properties. J Polym Res 18:1851-1861
5. Kim BK (1996) Aqueous polyurethane dispersions. Colloid Polym Sci 275:599-611
6. Dieterich D (1981) Aqueous emulsions, dispersions and solutions of polyurethanes; synthesis and properties. Prog Org Coat 9:281-340
7. Li CY, Chiu WY, Don TM (2005) Preparation of polyurethane dispersions by miniemulsion polymerization. J Polym Sci Part A Polym Chem 43:4870-4881
8. Sardon H, Irusta L, Fernandez-Berridi MJ (2009) Synthesis of isophorone diisocyanate (IPDI) based waterborne polyurethanes: Comparison between zirconium and tin catalysts in the polymerization process. Prog Org Coat 66:291-295
9. Subramani S, Lee JM, Lee JY, Kim JH (2007) Synthesis and properties of room temperature curable trimethoxysilaneterminated polyurethane and their dispersions. Polym Adv Technol 18:601-609
10. Subramani S, Cheong IW, Kim JH (2004) Synthesis and characterizations of silylated polyurethane from methyl ethyl ketoximeblocked polyurethane dispersion. Eur Polym J 40:2745-2755
11. Wang S, Chen P, Hwang J, Yeh J, Huang C, Chen K (2012) Performance properties of self-curing aqueous-based PU system with tri-glycidyl phosphate curing agent. J Polym Res 19:1-10
12. Kim BK, Yang JS, Yoo SM, Lee JS (2003) Waterborne polyurethanes containing ionic groups in soft segment. Colloid Polym Sci 281:461-468
13. Bao L, Lan Y, Zhang S (2006) Synthesis and properties of waterborne polyurethane dispersions with ions in the soft segments. J Polym Res 13:507-514
14. Song C, Yuan Q, Wang D (2004) Effect of the content of urea groups on the particle size in water-borne polyurethane or polyurethane/ polyacrylate dispersions. Colloid Polym Sci 282:642-645
15. Sardon H, Irusta L, Fernández-Berridi MJ, Lansalot M, Bourgeat- Lami E (2010) Synthesis of room temperature self-curable waterborne hybrid polyurethanes functionalized with (3-aminopropyl)- triethoxysilane (APTES). Polymer 51:5051-5057
16. Xiaojuan L, Xiaorui L, Lei W, Yiding S (2010) Synthesis and characterizations of waterborne polyurethane modified with 3- aminopropyltriethoxysilane. Polym Bull 65:45-57
17. Yeh JM, Yao CT, Hsieh CF, Yang HC, Wu CP (2008) Preparation and properties of amino-terminated anionic waterborne-polyurethane- silica hybrid materials through a sol-gel process in the absence of an external catalyst. Eur Polym J 44:2777-2783
18. Sardon H, Irusta L, Fernández-Berridi MJ, Luna J, Lansalot M, Bourgeat-Lami E (2011) Waterborne polyurethane dispersions obtained by the acetone process: a study of colloidal features. J Appl Polym Sci 120:2054-2062
19. Barni A, Levi M (2003) Aqueous polyurethane dispersions: a comparative study of polymerization processes. J Appl Polym Sci 88:716-723
20. Wang L, Shen Y, Lai X, Li Z, Liu M (2011) Synthesis and properties of crosslinked waterborne polyurethane. J Polym Res 18:469-476
21. Xiaojuan L, Yiding S, Lei W (2011) Preparation and properties of self-crosslinkable polyurethane/silane hybrid emulsion. J Polym Res 18:2425-2433
22. Camberlin Y, Pascault JP (1983) Quantitative DSC evaluation of phase segregation rate in linear segmented polyurethanes and polyurethaneureas. J Polym Sci Part A Polym Chem 21:415-423
23. Kwon J, Rahman M, Kim H (2006) Preparation and properties of crosslinkable waterborne polyurethanes containing aminoplast. Fibers Polym 7:95-104
24. Kanapitsas A, Pissis P, Gomez-Ribelles JL, Monleon-Pradas M, Privalko EG, Privalko VP (1999) Molecular mobility and hydration properties of segmented polyurethanes with varying structure of soft and hard chain segments. J Appl Polym Sci 71:1209-1221
25. Rekondo A, Irusta L, Fernandez-Berridi MJ (2010) Characterization of silanized poly(ether-urethane) hybrid systems using thermogravimetric analysis (TG). J Therm Anal Calorim 101:331-337