Easy access to acetal-spiroacetal-enol ethers by tandem dearomatization of a furan ring and acetalization

Synthesis (Germany)

Volumn 44, Issue 16, 2012, Pages 2567-2574

  Yin, Biao Lin ^a   Lai, Jin Qiang ^a   Huang, Li ^a   Zhang, Xiao Yu ^a   Ji, Fang Hua ^a  

^a SOUTH CHINA UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

carbocations; enols; ethers; furans; heterocycles

Indexed keywords

ACETALIZATION; CARBOCATIONS; DEAROMATIZATION; ENOLS; FORMYL GROUP; FURAN RING; FURANS; HETEROCYCLES; METHOXYMETHYL;

ORGANIC COMPOUNDS;

ETHERS;

1 [5 [3 [TERT BUTYL(DIMETHYL)SILOXY]PROPYL] 2 FURYL] 3 PHENYL PROP 2 YN 1 OL; 1 [5 [3 [TERT BUTYL(DIMETHYL)SILOXY]PROPYL] 2 FURYL]HEX 2 YN 1 OL; 2 (DIPHENYLMETHYLENE) 7 METHOXY 1,6 DIOXASPIRO[4.4]NON 3 ENE; 2 BENZYLIDENE 7 METHOXY 1,6 DIOXASPIRO[4.4]NON 3 ENE; 2 HEX 2 YN 1 YLIDENE 7 METHOXY 1,6 DIOXAPSIRO[4.4]NON 3 ENE; 3 [5 (1 METHOXY 3 PHENYLPROP 2 YN 1 YL) 2 FURYL]PROPAN 1 OL; 3 [5 (1 METHOXYHEX 2 YN 1 YL) 2 FURYL]PROPAN 1 OL; 3 [5 (1 METHOXYHEXA 2,4 DIYN 1 YL) 2 FURYL]PROPAN 1 OL; 3 [5 (METHOXYMETHYL) 2 FURYL]PROPIONALDEHYDE; 3 [5 [METHOXY(1 NAPHTHYL)METHYL] 2 FURYL]PROPRAN 1 OL; 3 [5 [METHOXY(4 METHOXYPHENYL)METHYL] 2 FURYL]PROPRAN 1 OL; 3 [5 [METHOXY(DIPHENYL)METHYL] 2 FURYL]PROPRAN 1 OL; 3 [5 [METHOXY(PHENYL)METHYL] 2 FURYL]PROPRAN 1 OL; 7 METHOXY 2 (1 NAPHTHYLMETHYLENE) 1,6 DIOXASPIRO[4.4]NON 3 ENE; 7 METHOXY 2 (3 PHENYLPROP 2 YN 1 YLIDENE) 1,6 DIOXASPIRO[4.4]NON 3 ENE; 7 METHOXY 2 (4 METHOXYBENZYLIDENE) 1,6 DIOXASPIRO[4.4]NON 3 ENE; [5 [3 [TERT BUTYL(DIMETHYL)SILOXY]PROPYL] 2 FURYL](1 NAPHTHYL)METHANOL; [5 [3 [TERT BUTYL(DIMETHYL)SILOXY]PROPYL] 2 FURYL](4 METHOXYPHENYL)METHANOL; [5 [3 [TERT BUTYL(DIMETHYL)SILOXY]PROPYL] 2 FURYL](DIPHENYL)METHANOL; [5 [3 [TERT BUTYL(DIMETHYL)SILOXY]PROPYL] 2 FURYL](PHENYL)METHANOL; [5 [3 [TERT BUTYL(DIMETHYL)SILOXY]PROPYL] 2 FURYL]METHANOL; ACETAL SPIROACETAL ENOL ETHER DERIVATIVE; ETHER DERIVATIVE; PROPIONALDEHYDE; TERT BUTYL[3 [5 (1 METHOXY 3 PHENYLPROP 2 YN 1 YL) 2 FURYL]PROPOXY]DIMETHYLSILANE; TERT BUTYL[3 [5 (1 METHOXYHEX 2 YN 1 YL) 2 FURYL]PROPOXY]DIMETHYLSILANE; TERT BUTYL[3 [5 (1 METHOXYHEXA 2,4 DIYN 1 YL) 2 FURYL]PROPOXY]DIMETHYLSILANE; TERT BUTYL[3 [5 [METHOXY(4 METHOXYPHENYL)METHYL] 2 FURYL]PROPOXY]DIMETHYLSILANE; TERT BUTYL[3 [5 [METHOXY(PHENYL)METHYL] 2 FURYL]PROPOXY]DIMETHYLSILANE; UNCLASSIFIED DRUG;

ACETALIZATION; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; DEAROMATIZATION; REACTION ANALYSIS; SYNTHESIS;

EID: 84864878391     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0032-1316548     Document Type: Article

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