Heteropolyacid catalyzed conversion of fructose, sucrose, and inulin to 5-ethoxymethylfurfural, a liquid biofuel candidate

Applied Energy

Volumn 99, Issue , 2012, Pages 80-84

  Yang, Yu ^a,b   Abu Omar, Mahdi M ^b   Hu, Changwei ^a  

^a China   (China)

^b PURDUE UNIVERSITY   (United States)

Author keywords

5 Ethoxymethylfurfural; Ethyl glucoside; Ethyl levulinate; Fructose

Indexed keywords

BIOFUELS; CATALYSTS; ETHANOL; GLUCOSE; LIQUIDS; ORGANIC SOLVENTS; POLYSACCHARIDES; SUGAR (SUCROSE);

5-ETHOXYMETHYLFURFURAL; CATALYZED CONVERSION; COSOLVENTS; ETHYL GLUCOSIDE; ETHYL LEVULINATE; HETEROPOLY ACIDS; HETEROPOLYACID CATALYST; LIQUID BIOFUELS; REACTION TEMPERATURE; TETRA-HYDROFURAN;

FRUCTOSE;

BIOFUEL; CARBOHYDRATE; CATALYST; ETHANOL; HEATING; TEMPERATURE EFFECT;

EID: 84864813564     PISSN: 03062619     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apenergy.2012.04.049     Document Type: Article

References (29)

1. Rostrup-Nielsen J. Chemistry: making fuels from biomass. Science 2005, 308:1421.
2. Demirbas A. Competitive liquid biofuels from biomass. Appl Energy 2011, 88:17-28.
3. Hammond G.P., Kallu S., McManus M.C. Development of biofuels for the UK automotive market. Appl Energy 2008, 85:506-515.
4. Tian Y.S., Zhao L.X., Meng H.B., Sun L.Y., Yan J.Y. Estimation of un-used land potential for biofuels development in (the) People's Republic of China. Appl Energy 2009, 86:S77-S85.
5. Singh A., Olsen S.I. A critical review of biochemical conversion, sustainability and life cycle assessment of algal biofuels. Appl Energy 2011, 88:3548-3555.
6. Pate R., Klise G., Wu B. Resource demand implications for US algae biofuels production scale-up. Appl Energy 2011, 88:3377-3388.
7. Yan J., Lin T. Biofuels in Asia. Appl Energy 2011, 86:S1-S10.
8. Wonglimpiyarat J. Technological change of the energy innovation system: from oil-based to bio-based energy. Appl Energy 2010, 87:749-755.
9. Markou G., Georgakakis D. Cultivation of filamentous cyanobacteria (blue-green algae) in agro-industrial wastes and wastewaters: a review. Appl Energy 2011, 88:3389-3401.
10. Nizami A., Orozco A., Groom E., et al. How much gas can we get from grass?. Appl Energy 2011, 92:783-790.
11. Lanzafame P., Temi D., Perathoner S., Centi G., Macario A., Aloise A., et al. Etherification of 5-hydroxymethyl-2-furfural (HMF) with ethanol to biodiesel components using mesoporous solid acidic catalysts. Catal Today 2011, 175:435-441.
12. Mascal M., Nikitin E.B. Direct, high yield conversion of cellulose into biofuel. Angew Chem Int Edit 2008, 120:8042-8044.
13. Gruter G.J.M., Dautzenberg F. Method for the synthesis of 5-alkoxymethyl furfural ethers and their use. Eur Pat Appl 2007, [1834950A1].
14. Tarabanko V.E., Smirnova M.A., Chernyak M.Y. Investigation of acid-catalytic conversion of carbohydrates in the presence of aliphatic alcohols at mild temperatures. Chem Sus Develop 2005, 13:551-558.
15. Brown D.W., Floyd A.J., Kinsman R.G., Roshan-Ali Y. Dehydration reactions of fructose in non-aqueous media. J Chem Technol Biotechnol 1982, 32:920-924.
16. Balat M., Balat H. Recent trends in global production and utilization of bio-ethanol fuel. Appl Energy 2009, 86:2273-2282.
17. Börjesson P. Good or bad bioethanol from a greenhouse gas perspective-what determines this?. Appl Energy 2009, 86:589-594.
18. Kozhevnikov I.V. Catalysis by heteropolyacids and multicomponent polyoxometalates in liquid-phase reactions. Chem Rev 1998, 98:171-198.
19. Fan C.Y., Guan H.Y., Zhang H., Wang J.H., Wang S.T., Wang X.H. Conversion of fructose and glucose into 5-hydroxymethylfurfural catalyzed by a solid heteropolyacid salt. Biomass Bioenergy 2011, 35:2659-2665.
20. Zhao Q., Wang L., Zhao S., Wang X.H., Wang S.T. High selective production of 5-hydroymethylfurfural from fructose by a solid heteropolyacid catalyst. Fuel 2011, 90:2289-2293.
21. Cheng M.X., Shi T., Wang S.T., Guan H.T., Fan C.T., Wang X.H. Fabrication of micellar heteropolyacid catalysts for clean production of monosaccharides from polysaccharides. Catal Commun 2011, 12:1483-1487.
22. Deng W.P., Liu M., Zhang Q.H., Tan X.S., Wang Y. Acid-catalysed direct transformation of cellulose into methyl glucosides in methanol at moderate temperatures. Chem Commun 2010, 46:2668-2670.
23. Choi J.H., Kim J.K., Park D.R., Park S., Yi J., Song I.K. Etherification of n-butanol to di-n-butyl ether over H3PMo12-xWxO40 (x= 0, 3, 6, 9, 12) Keggin and H6P2Mo18-xWxO62 (x= 0, 3, 9, 15, 18) Wells-Dawson heteropolyacid catalysts. Catal Communica 2011, 14:48-51.
24. Peng L.C., Lin L., Li H., Yang Q.L. Conversion of carbohydrates biomass into levulinate esters using heterogeneous catalysts. Appl Energy 2011, 88:4560-4569.
25. Saravanamurugan S., Nguyen V.B.O., Riisager A. Conversion of mono-and disaccharides to ethyl levulinate and ethyl pyranoside with sulfonic acid-functionalized ionic liquids. ChemSusChem 2011, 4:723-726.
26. Zhu H., Cao Q., Li C.H., Mu X.D. Acidic resin-catalysed conversion of fructose into furan derivatives in low boiling point solvents. Carbohyd Res 2011, 346:2016-2018.
27. Lichtenthaler F.W. Unsaturated O-and N-heterocycles from carbohydrate feedstocks. Accounts Chem Res 2002, 35:728-737.
28. Wei D.Z., Zou P., Tu M.B., Zheng H. Enzymatic synthesis of ethyl glucoside lactate in non-aqueous system. J Mol Catal B-Enzym 2002, 18:273-278.
29. Sirisansaneeyakul S., Worawuthiyanan N., Vanichsriratana W., Srinophakun P., Chisti Y. Production of fructose from inulin using mixed inulinases from Aspergillus niger and Candida guilliermondii. World J Microb Biot 2007, 23:543-552.