Synthesis and characterization of cross-linked poly(arylene ether ketone) containing pendant quaternary ammonium groups for anion-exchange membranes

Journal of Membrane Science

Volumn 415-416, Issue , 2012, Pages 205-212

  Wang, Jing ^a,b   Wang, Junhua ^a,b   Zhang, Suobo ^a  

^a CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Anion exchange membrane; Cross linking; Fuel cells; Poly(arylene ether ketone) containing pendant quaternary ammonium groups

Indexed keywords

ALKALINE ANION-EXCHANGE MEMBRANES; ANION EXCHANGE; ANION EXCHANGE MEMBRANE; BIPHENOL; CROSS-LINKED MATERIALS; HYDROXIDE IONS; NUCLEOPHILIC AROMATIC SUBSTITUTION; POLYARYLENE ETHER KETONES; QUATERNARY AMMONIUM GROUP; QUATERNIZATION; ROOM TEMPERATURE; SIMPLIFIED PROCEDURE; SYNTHETIC APPROACH; TERTIARY AMINE GROUPS; WATER UPTAKE;

COPOLYMERS; CROSSLINKING; DIRECT METHANOL FUEL CELLS (DMFC); ETHERS; FUEL CELLS; HYDROGEN; IONS; MECHANICAL PROPERTIES; ORGANIC COMPOUNDS;

MEMBRANES;

4,4' DIFLUOROBENZOPHENONE,2,2',6,6' TETRAMETHYL 4,40 BIPHENOL; ALKALINE CERAMIDASE; BENZOPHENONE DERIVATIVE; COPOLYMER; HYDROXIDE; KETONE DERIVATIVE; METHANOL; MONOMER; NUCLEOPHILE; POLY(ARYLENE ETHER KETONE); QUATERNARY AMMONIUM DERIVATIVE; TERTIARY AMINE; UNCLASSIFIED DRUG;

ANION EXCHANGE; ARTICLE; CHEMICAL REACTION; CONDUCTANCE; CROSS LINKING; MEMBRANE PERMEABILITY; PRIORITY JOURNAL; SYNTHESIS;

EID: 84864749771     PISSN: 03767388     EISSN: 18733123     Source Type: Journal    
DOI: 10.1016/j.memsci.2012.04.054     Document Type: Article

References (24)

1. Steele B.C.H., Heinzel A. Materials for fuel-cell technologies. Nature 2001, 414:345-352.
2. Hickner M.A., Ghassemi H., Kim Y.S., Einsla B.R., McGrath J.E. Alternative polymer systems for Proton Exchange Membranes (PEMs). Chem. Rev. 2004, 104:4587-4612.
3. Borup R., Meyers J., Pivovar B., Kim Y.S., Mukundan R., Garland N., Myers D., Wilson M., Garzon F., Wood D., Zelenay P., More K., Stroh K., Zawodzinski T., Boncella J., McGrath J.E., Inaba M., Miyatake K., Hori M., Ota K., Ogumi Z., Miyata S., Nishikata A., Siroma Z., Uchimoto Y., Yasuda K., Kimijima K.-i., Iwashita N. Scientific aspects of polymer electrolyte fuel cell durability and degradation. Chem. Rev. 2007, 107:3904-3951.
4. Fran D.M. The global and urban environment: the need for clean power systems. J. Power Sources 1998, 71:7-11.
5. Silva R.F., De Francesco M., Pozio A. Tangential and normal conductivities of Nafion® membranes used in polymer electrolyte fuel cells. J. Power Sources 2004, 134:18-26.
6. Lee C.H., Park H.B., Lee Y.M., Lee R.D. Importance of proton conductivity measurement in polymer electrolyte membrane for fuel cell application. Ind. Eng. Chem. Res. 2005, 44:7617-7626.
7. Wee J.-H., Lee K.-Y. Overview of the development of CO-tolerant anode electrocatalysts for proton-exchange membrane fuel cells. J. Power Sources 2006, 157:128-135.
8. Cropper M.A.J., Geiger S., Jollie D.M. Fuel cells: a survey of current developments. J. Power Sources 2004, 131:57-61.
9. Tanaka M., Fukasawa K., Nishino E., Yamaguchi S., Yamada K., Tanaka H., Bae B., Miyatake K., Watanabe M. Anion conductive block poly(arylene ether)s: synthesis, properties, and application in alkaline fuel cells. J. Am. Chem. Soc. 2011, 133:10646-10654.
10. Zhang M., Kim H.K., Chalkova E., Mark F., Lvov S.N., Chung T.C.M. New Polyethylene Based Anion Exchange Membranes (PE-AEMs) with high ionic conductivity. Macromolecules 2011, 5937-5946.
11. Matsumoto K., Fujigaya T., Yanagi H., Nakashima N. Very high performance alkali anion-exchange membrane fuel cells. Adv. Funct. Mater. 2011, 21:1089-1094.
12. Kordesch K., Oliveira J.C.T. Fuel cells: the present state of the technology and future applications, with special consideration of the alkaline hydrogen/oxygen (air) systems. Int. J. Hydrogen Energy 1988, 13:411-427.
13. 2 alkaline membrane fuel cells with commercial Pt/C, Ag/C, and Au/C cathodes. J. Phys. Chem. B 2006, 110:21041-21049.
14. Hickner M.A. Ion-containing polymers: new energy & clean water. Mater. today 2010, 13:34-41.
15. Hibbs M.R., Hickner M.A., Alam T.M., McIntyre S.K., Fujimoto C.H., Cornelius C.J. Transport properties of hydroxide and proton conducting membranes. Chem. Mater. 2008, 20:2566-2573.
16. Luo Y., Guo J., Wang C., Chu D. Fuel cell durability enhancement by crosslinking alkaline anion exchange membrane electrolyte. Electrochem. Commun. 2012, 16:65-68.
17. Lin B., Qiu L., Lu J., Yan F. Cross-linked alkaline ionic liquid-based polymer electrolytes for alkaline fuel cell applications. Chem. Mater. 2010, 22:6718-6725.
18. Clark T.J., Robertson N.J., Kostalik Iv H.A., Lobkovsky E.B., Mutolo P.F., Abruna H.D., Coates G.W. A ring-opening metathesis polymerization route to alkaline anion exchange membranes: development of hydroxide-conducting thin films from an ammonium-functionalized monomer. J. Am. Chem. Soc. 2009, 131:12888-12889.
19. Robertson N.J., Kostalik H.A., Clark T.J., Mutolo P.F., Abruna H.D., Coates G.W. Tunable high performance cross-linked alkaline anion exchange membranes for fuel cell applications. J. Am. Chem. Soc. 2010, 132:3400-3404.
20. Gu S., Cai R., Yan Y. Self-crosslinking for dimensionally stable and solvent-resistant quaternary phosphonium based hydroxide exchange membranes. Chem. Commun. 2011, 47:2856-2858.
21. Ni J., Zhao C., Zhang G., Zhang Y., Wang J., Ma W., Liu Z., Na H. Novel self-crosslinked poly(aryl ether sulfone) for high alkaline stable and fuel resistant alkaline anion exchange membranes. Chem. Commun. 2011, 47:8943-8945.
22. Wang J., Zhao Z., Gong F., Li S., Zhang S. Synthesis of soluble poly(arylene ether sulfone) ionomers with pendant quaternary ammonium groups for anion exchange membranes. Macromolecules 2009, 42:8711-8717.
23. Du R., Zhao J. Properties of poly (N,N-dimethylaminoethyl methacrylate)/polysulfone positively charged composite nanofiltration membrane. J. Membr. Sci. 2004, 239:183-188.
24. Tongwen X., Zha F.F. Fundamental studies on a new series of anion exchange membranes: effect of simultaneous amination-crosslinking processes on membranes ion-exchange capacity and dimensional stability. J. Membr. Sci. 2002, 199:203-210.