Catalysis in a porous molecular capsule: Activation by regulated access to sixty metal centers spanning a truncated icosahedron

Journal of the American Chemical Society

Volumn 134, Issue 31, 2012, Pages 13082-13088

  Kopilevich, Sivil ^a   Gil, Adrià ^c   Garcia Ratés, Miquel ^b   Bonet Ávalos, Josep ^b   Bo, Carles ^c   Müller, Achim ^d   Weinstock, Ira A ^a  

^a BEN GURION UNIVERSITY OF THE NEGEV   (Israel)

^b UNIVERSITAT ROVIRA I VIRGILI   (Spain)

^c INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

^d BIELEFELD UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACETATE LIGANDS; ACTIVATION PARAMETER; ACTIVE SITE; CATALYTIC CYCLES; CATALYTIC TRANSFORMATION; CLEAVAGE RATES; DFT CALCULATION; FIRST-ORDER DEPENDENCE; KINETIC DATA; METAL CENTERS; METAL-OXIDE; METHYL TERT BUTYL ETHER; MICROENVIRONMENTS; MICROSCOPIC REVERSIBILITY; MODEL REACTIONS; MOLECULAR CAPSULE; ORGANIC SUBSTRATE; OXYGEN-18; REVERSE REACTIONS; SPHERICAL CAPSULE; WATER LIGANDS;

BUTENES; DENSITY FUNCTIONAL THEORY; DEUTERIUM; ENCAPSULATION; LIGANDS; MOLYBDENUM OXIDE; SUBSTRATES; VOLATILE FATTY ACIDS; WATER ANALYSIS;

MOLYBDENUM;

ACETIC ACID; BRONSTED ACID; CATION; DEUTERIUM; ISOBUTYLENE; METAL COMPLEX; METAL OXIDE; MOLYBDENUM COMPLEX; OXYGEN 18; TERT BUTYL METHYL ETHER; WATER;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ENCAPSULATION; MICROSCOPY; POROSITY; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 84864708258     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja304513t     Document Type: Article

References (20)

1. Amouri, H.; Desmarets, C.; Moussa, J. Chem. Rev. 2012, 112, 2015-2041
2. Chakrabarty, R.; Mukherjee, P. S.; Stang, P. J. Chem. Rev. 2011, 111, 6810-6918
3. Laughreya, Z.; Gibb, B. C. Chem. Soc. Rev. 2011, 40, 363-386
4. Wiester, M. J.; Ulmann, P. A.; Mirkin, C. A. Angew. Chem., Int. Ed. 2011, 50, 114-137
5. Yoshizawa, M.; Fujita, M. Bull. Chem. Soc. Jpn. 2010, 83, 609-618
6. Yoshizawa, M.; Klosterman, J. K.; Fujita, M. Angew. Chem., Int. Ed. 2009, 48, 3418-3438
7. Pluth, M. D.; Bergman, R. G.; Raymond, K. N. Acc. Chem. Res. 2009, 42, 1650-1659
8. Ajami, D.; Rebek, J. Top. Curr. Chem. 2012, 319, 57-78
9. Todea, A. M.; Merca, A.; Bögge, H.; van Slageren, H. J.; Dressel, M.; Engelhardt, L.; Luban, M.; Glaser, T.; Henry, M.; Müller, A. Angew. Chem., Int. Ed. 2007, 119, 6218-6222
10. Sadakane, M.; Yamagata, K.; Kodato, K.; Endo, K.; Toriumi, K.; Ozawa, Y.; Ozeki, T.; Nagai, T.; Matsui, Y.; Sakaguchi, N.; Pyrz, W. D.; Buttrey, D. J.; Blom, D. A.; Vogt, T.; Ueda, W. Angew. Chem., Int. Ed. 2009, 48, 3782-3786
11. Ziv, A.; Grego, A.; Kopilevich, S.; Zeiri, L.; Miro, P.; Bo, C.; Müller, A.; Weinstock, I. A. J. Am. Chem. Soc. 2009, 131, 6380-6382
12. Petina, O.; Rehder, D.; Haupt, E. T. K.; Grego, A.; Weinstock, I. A.; Merca, A.; Bögge, H.; Szakacs, J.; Müller, A. Angew. Chem., Int. Ed. 2011, 50, 410-414
13. Schäffer, C.; Bögge, H.; Merca, A.; Weinstock, I. A.; Dieter Rehder, D.; Haupt, E. T. K.; Müller, A. Angew. Chem., Int. Ed. 2009, 48, 8051-8046
14. Schäffer, C.; Todea, A. M.; Bögge, H.; Petina, O. A.; Rehder, D.; Haupt, E. T. K.; Müller, A. Chem. - Eur. J. 2011, 17, 9634-9639
15. Polydore, C.; Roundhill, D. M.; Liu, H.-Q. J. Mol. Cat. A. 2002, 186, 65-68
16. Breno, K. L.; Ahmed, T. J.; Pluth, M. D.; Balzarek, C; Tyler, D. R. Coord. Chem. Rev. 2006, 250, 1141-1151
17. Blackmond, D. G. Angew. Chem., Int. Ed. 2009, 48, 2648-2654
18. Bielanski, A.; Lubanska, A.; Micek-Ilnicka, A.; Pozniczek, J. Coord. Chem. Rev. 2005, 249, 2222-2231
19. Richens, D. T. Chem. Rev. 2005, 105, 1961-2002
20. William, H. Casey, private communication.