Fragmenting gadolinium: Mononuclear polyoxometalate-based magnetic coolers for ultra-low temperatures

Advanced Materials

Volumn 24, Issue 31, 2012, Pages 4301-4305

  Martínez Pérez, María José ^a   Montero, Oscar ^a   Evangelisti, Marco ^a   Luis, Fernando ^a   Sesé, Javier ^a   Cardona Serra, Salvador ^b   Coronado, Eugenio ^b  

^a UNIVERSITY OF ZARAGOZA   (Spain)

^b UNIVERSITY OF VALENCIA   (Spain)

Author keywords

gadolinium; magnetic refrigeration; magnetocaloric effect; molecular nanomagnets; polyoxometalates; ultra low temperatures

Indexed keywords

ADIABATIC DEMAGNETIZATION; CRITICAL TEMPERATURES; MAGNETIC INTERACTIONS; MAGNETIC IONS; MAGNETIC ORDERS; MAGNETIC REFRIGERANT MATERIALS; MOLECULAR NANOMAGNETS; POLYOXOMETALATE CLUSTERS; POLYOXOMETALATES; ULTRA LOW TEMPERATURES;

COOLING SYSTEMS; MAGNETIC REFRIGERATION; MAGNETOCALORIC EFFECTS; OXIDES; SYNTHETIC METALS; TEMPERATURE;

GADOLINIUM;

GADOLINIUM; POLYOXOMETALATE I; TUNGSTEN DERIVATIVE;

ARTICLE; CHEMISTRY; COLD; ENTROPY; MAGNETISM;

COLD TEMPERATURE; ENTROPY; GADOLINIUM; MAGNETICS; TUNGSTEN COMPOUNDS;

EID: 84864654045     PISSN: 09359648     EISSN: 15214095     Source Type: Journal    
DOI: 10.1002/adma.201200750     Document Type: Article

References (26)

1. For recent overviews, see: a), M. Evangelisti, E. K. Brechin, Dalton Trans. 2010, 39, 4672-4676, and references therein
2. b) R. Sessoli, Angew. Chem. 2012, 124, 43-45
3. Angew. Chem. Int.-Ed. 2012, 51, 43-45, and references therein.
4. V. K. Pecharsky, K. A. Gschneidner Jr., J. Magn. Magn. Mater. 1999, 200, 44-56.
5. See, e.g., D. S. Betts, An introduction to millikelvin technology, Cambridge University Press, New York 1989.
6. a) W. F. Giauque, D. P. MacDougall, Phys. Rev. 1935, 43, 768-768
7. b) W. F. Giauque, D. P. MacDougall, J. Am. Chem. Soc. 1935, 57, 1175-1185.
8. R. F. Wielinga, J. Lubbers, W. J. Huiskamp, Physica 1967, 37, 375-392.
9. R. D. McMichael, J. J. Ritter, R. D. Shull, J. Appl. Phys. 1993, 73, 6946-6948.
10. M. Evangelisti, O. Roubeau, E. Palacios, A. Camõn, T. N. Hooper, E. K. Brechin, J. J. Alonso, Angew. Chem. 2011, 123, 6736-6739
11. Angew. Chem. Int.-Ed. 2011, 50, 6606-6609.
12. F. S. Guo, J. D. Leng, J. L. Liu, Z. S. Meng, M. L. Tong, Inorg. Chem. 2012, 51, 405-413.
13. a) G. Karotsis, M. Evangelisti, S. J. Dalgarno, E. K. Brechin, Angew. Chem. 2009, 121, 10112-10115
14. Angew. Chem. Int.-Ed. 2009, 48, 9928-9931
15. b) G. Karotsis, S. Kennedy, S. J. Teat, C. M. Beavers, D. A. Fowler, J. J. Morales, M. Evangelisti, S. J. Dalgarno, E. K. Brechin, J. Am. Chem. Soc. 2010, 132, 12983-12990.
16. Y.-Z. Zheng, M. Evangelisti, R. E. P. Winpenny, Chem. Sci. 2011, 2, 99-102.
17. a) Y.-Z. Zheng, M. Evangelisti, R. E. P. Winpenny, Angew. Chem. 2011, 123, 3776-3779
18. Angew. Chem. Int.-Ed. 2011, 50, 3692-3695
19. b) Y.-Z. Zheng, M. Evangelisti, F. Tuna, R. E. P. Winpenny, J. Am. Chem. Soc. 2012, 134, 1057-1065.
20. See, e.g., R. P. Hudson, Principles and application of magnetic cooling, North-Holland Publishing Company, Amsterdam, 1972.
21. M. A. AlDamen, J. M. Clemente-Juan, E. Coronado, C. Martí- Gastaldo, A. Gaita-Ariño, J. Am. Chem Soc. 2008, 130, 8874-8875.
22. M. A. AlDamen, S. Cardona-Serra, J. M. Clemente-Juan, E. Coronado, A. Gaita-Ariño, C. Martí-Gastaldo, F. Luis, O. Montero, Inorg. Chem. 2009, 48, 3467-3479.
23. M. Evangelisti, F. Luis, L. J. de Jongh, M. Affronte, J. Mater. Chem. 2006, 16, 2534-2549.
24. T. Ozeki, T. Yamase, Acta Crystallogr. 1994, C50, 327-330.
25. I. Creaser, M. C. Heckel, R. J. Neitz, M. T. Pope, Inorg. Chem. 1993, 32, 1573-1578.
26. M. J. Martínez-Pérez, J. Sesé, F. Luis, D. Drung, T. Schurig, Rev. Sci. Instrum. 2010, 81, 016108/1-3.