A thermostated coupled apparatus for the simultaneous determination of adsorption isotherms and differential enthalpies of adsorption at high pressure and high temperature

Journal of Thermal Analysis and Calorimetry

Volumn 109, Issue 2, 2012, Pages 1077-1087

  Mouahid, Adil ^a   Bessieres, David ^a   Plantier, Frédéric ^a   Pijaudier Cabot, Gilles ^a  

^a UNIVERSITÉ DE PAU ET DES PAYS DE L'ADOUR   (France)

Author keywords

Activated carbons; Adsorption; Calorimeter; Carbon dioxide; High pressure; High temperature; Methane; Microporous materials

Indexed keywords

DIFFERENTIAL ENTHALPY; DIFFERENTIAL HEAT; EXPERIMENTAL STUDIES; FLOW CALORIMETER; HIGH PRESSURE; HIGH PRESSURE AND HIGH TEMPERATURE; HIGH TEMPERATURE; HIGH-PRESSURE AND TEMPERATURES; MICROPOROUS AND MESOPOROUS MATERIALS; PURE CARBON DIOXIDE; REPRODUCIBILITIES; SIMULTANEOUS DETERMINATIONS; STEPWISE METHODS;

ACTIVATED CARBON; ADSORPTION ISOTHERMS; CALORIMETERS; CARBON DIOXIDE; ENTHALPY; HEAT TRANSFER; MESOPOROUS MATERIALS; METHANE; MICROPOROUS MATERIALS;

ADSORPTION;

EID: 84864616173     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-011-1820-2     Document Type: Conference Paper

References (61)

1. Pini R, Ottiger S, Burlini L, Storti G, Mazzotti M. Sorption of carbon dioxide, methane and nitrogen in dry coals at high pressure and moderate temperature. Int J Greenh Gas Control. 2010;4:90-101.
2. Himeno S, Komatsu T, Fujita S. High-Pressure adsorption equilibria of methane and carbon dioxide on several activated carbons. J Chem Eng Data. 2005;50:369-76.
3. Krooss BM, van Bergen F, Gensterblum Y, Siemons N, Pagnier HJM, David P. High-pressure methane and carbon dioxide adsorption on dry and moisture-equilibrated Pennsylvanian coals. Int J Coal Geol. 2002;51:69-92.
4. Ottiger S, Pini R, Storti G, Mazzotti M. Measuring and modeling the competitive adsorption of CO2, CH4, and N2 on a dry coal. Langmuir. 2008;24(17):9531-40.
5. Ottiger S, Pini R, Storti G, Mazzotti M. Competitive adsorption equilibria of CO2 and CH4 on a dry coal. Adsorption. 2008; 14:539-56.
6. Cavenati S, Grande CA, Rodrigues AE. Adsorption equilibrium of methane, carbon dioxide, and nitrogen on Zeolite 13X at high pressures. J Chem Eng Data. 2004;49:1095-101.
7. Sun Y, Liu C, Su W, Zhou Y, Zhou L. Principles of methane adsorption and natural gas storage. Adsorption. 2009;15:133-7.
8. Barbosa MN, Araujo AS, Galvao LPFC, Silva EFB, Santos AGD, Luz GE Jr, Fernandes VJ Jr. Carbon dioxide adsorption over DIPA functionalized MCM-41 and SBA-15 molecular sieves. J Therm Anal Calorim. 2011. doi:10.1007/s10973-011- 1398-8.
9. Zhao H-Y, Cao Y, Lineberry Q, Pan W-P. Evaluation of CO2 adsorption capacity of solid sorbents. J Therm Anal Calorim. 2011. doi:10.1007/s10973-011- 1481-1.
10. Walton KS, Cavalcante CL Jr, Douglas Levan M. Adsorption equilibrium of alkanes on a high surface area activated carbon prepared from Brazilian coconut shells. Adsorption. 2005;11: 107-11.
11. Sweatman MB, Quirke N. Characterization of porous materials by gas adsorption at ambient temperatures and high pressure. J Phys Chem B. 2001;105:1403-11.
12. Liu J-C, Monson PA. Molecular modeling of adsorption in activated carbon: comparison of Monte Carlo simulations with experiment. Adsorption. 2005;11:5-13.
13. Li W-Z, Liu Z-Y, Che Y-L, Zhang D. Molecular simulation of adsorption and separation of mixtures of short linear alkanes in pillared layered materials at ambient temperature. J Colloid Interface Sci. 2007;312:179-85.
14. Birkett GR, Do DD. On the physical adsorption of gases on carbon materials from molecular simulation. Adsorption. 2007;13: 407-24.
15. Ghoufi A, Gaberova L, Rouquerol J, Vincent D, Llewellyn PL, Maurin G. Adsorption of CO2, CH4 and their binary mixture in Faujasite NaY: a combination of molecular simulations with gravimetry-manometry and microcalorimetry measurements. Microporous Mesoporous Mater. 2009;119:117-28.
16. Pinto da Costa JMC, Cracknell RF, Seaton NA, Sarkisov L. Towards predictive molecular simulations of normal and branched alkane adsorption in carbonaceous engine deposits. Carbon. 2011;49:445-56.
17. Wells BA, Chaffee AL. Modeling gas separation in metal-organic frameworks. Adsorption. 2011;17:255-64.
18. Tomar DS, Singla M, Gumma S. Potential parameters for helium adsorption in silicalite. Microporous Mesoporous Mater. 2011; 142:116-21.
19. Gibbs JW. Collected works. New York: Longmans Green and Co.; 1877.
20. Dabrowsko A. Adsorption from theory to practice. Adv Colloid Interface Sci. 2001;93:135-224.
21. Rouquerol F, Rouquerol J, Sing K. Adsorption by powders and porous solids principles, methodology and applications. San Diego: Academic Press; 1999.
22. Spiewak BE, Dumesic JA. Microcalorimetric measurements of differential heats of adsorption on reactive catalyst surfaces. Thermochim Acta. 1996;290:43-53.
23. Wadso I, Wadso L. A second generation twin double microcalorimeter measurements of sorption isotherms, heats of sorption and sorption kinetics. J Therm Anal. 1997;49:1045-52.
24. Berlier K, Bougard J, Olivier MG. Relevé automatique d'isotherme d'adsorption sur solides microporeux dans de large gamme de pression et de température. Meas Sci Technol. 1995;6:107-13.
25. Belmabkhout Y, Frère M, De Guy W. High-pressure adsorption isotherms of N2, CH4, O2, and Ar on different carbonaceous adsorbents. J Chem Eng Data. 2005;49:1379-91.
26. Cross B, Puech L, Wolf PE. A temperature-controlled device for volumetric measurements of helium adsorption in porous media. J Low Temp Phys. 2007;148:903-7.
27. Dreisbach F, Lösch HW. Magnetic suspension balance for simultaneous measurement of a sample, the density of the measuring fluid. J Therm Anal Calorim. 2000;62:515-21.
28. Dreisbach F, Losch HW, Harting P. Highest pressure adsorption equilibria data: measurement with magnetic suspension balance and analysis with a new adsorbent/adsorbate-volume. Adsorption. 2002;8:95-109.
29. Gravelle PC. Methods for the determination of heats of adsorption. J Therm Anal. 1978;14:53-77.
30. Myers A-L, Siperstein F. Characterization of adsorbents by energy profile of adsorbed molecules. Colloids Surf A Physicochem Eng Asp. 2001;187-188:73-81.
31. Dallos A, Martha VE, Biro Sz. Simultaneous determination of heats, equilibrium and kinetics of adsorption 1-ethoxy-2-propanol vapors. J Therm Anal Calorim. 2002;69:353-8.
32. Sheni D, Engelhard M, Siperstein F, Myers A-L, Bulow M. Comparison of sorption heats from isosteric and calorimetric experiments for nitrogen, oxygen and carbon dioxide on zeolites of types LTA and FAU. Adsorpt Sci Technol. 2000; 28(4): 106-10.
33. Rothstein D-P, Wu B-G, Victor Lee T, Madey R. Adsorption isotherms and isosteric heats of adsorption for ethane, propane, and n-butane on polystyrene. J Colloid Interface Sci. 1985;106: 399-409.
34. Kean W, Shizhang Q, Xijun H. Study of isosteric heat of adsorption and activation energy for surface diffusion of gases on activated carbon using equilibrium and kinetics information. Sep Purif Technol. 2004;34:165-76.
35. Van Dongen RH, Broekhoff JCP. The isosteric heat of adsorption on homogeneous, patchwise heterogeneous surface. Surf Sci. 1969;18:462-9.
36. Floess JK, Kim HH, Edens G, Oleksy SA, Kwak J. Surface area and heat of adsorption measurements of a microporous carbon. Carbon. 1992;30:1025-32.
37. Dezhi S, Jian C, Weimin L, Xiaoming Z. Heats of adsorption of some organic compounds on b-cyclodextrin determined by gas solid chromatography. J Chromatogr A. 1999;864:293-8.
38. Grajeka H, Paciura-Zadrozna J, Witkiewicz Z. Chromatographic determination of the differential isosteric adsorption enthalpies and differential entropies on ordered silica materials. J Chromatogr A. 2008;1194:118-27.
39. Grajek H. Comparison of the differential isosteric adsorption enthalpies and entropies calculated from chromatographic data. J Chromatogr A. 2003;986:89-99.
40. Diaz E, Ordonez S, Auroux A. Comparative study on the gasphase adsorption of hexane over zeolites by calorimetry and inverse gas chromatography. J Chromatogr A. 2005;1095:131-7.
41. Zimmerman W, Keller JU. A new calorimeter for simultaneous measurement of isotherms, heats of adsorption. Thermochim Acta. 2003;405:31-41.
42. Siperstein F, Gorte R, Myers A-L. A new calorimeter for simultaneous measurements of loading and heats of adsorption from gaseous mixtures. Langmuir. 1999;15:1570-6.
43. Garcia-Cuello V, Moreno-Pirajan JC, Giraldo-Gutiérrez L, Sapag K, Zgrablich G. A new calorimeter of adsorption for the determination of differential enthalpies. Microporous Mesoporous Mater. 2009;120:239-45.
44. Berlier K, Frere M. Adsorption of CO2 on activated carbon: simultaneous determination of integral heat and isotherm of adsorption. J Chem Eng Data. 1996;41:1144-8.
45. Rakic V, Dondur V, Gajinov S, Auroux A. Calorimetric study of room temperature adsorption of N2O and CO on Cu(II)-exchanged ZSM5 zeolites. Thermochim Acta. 2004;420:51-7.
46. Denoyel DR, Beurroies I, Vincent D. Microcalorimetric methods for studying vapour adsorption, wetting of powders. J Therm Anal Calorim. 2002;70:438-92.
47. Simonot-Grange M-H, Bertrand O, Pilverdier E, Bellat J-P, Paulin C. Differential calorimetric enthalpies of adsorption of pxylene and m-xylene on Y faujasites at 25°C. J Therm Anal. 1997;48:741-54.
48. Garcia-Cuello V, Moreno-Pirajan JC, Giraldo-Gutierrez L, Sapag K, Zgrablich G. Determination of differential enthalpy and isotherm by adsorption calorimetry. Res Lett Phys Chem. 2008. doi:10.1155/2008/127328.
49. Lehto V-P, Laine E. Simultaneous determination of the heat and the quantity of vapor sorption using a novel microcalorimetric method. Pharm Res 2000;17(6).
50. Llewellyn PL, Guillaume M. Gas adsorption microcalorimetry and modeling to characterize zeolites and related materials. C R Chimie. 2005;8:283-302.
51. Alexandre FPF, Marjo CM-H, Alfred B. Adsorption and differential heats of adsorption of normal and iso-butane on zeolite MFI. Microporous Mesoporous Mater. 2006;91:47-52.
52. Bidyut BS, Shigeru K, Ibrahim IEl-S, Khairul H, Kandadai S, Pradip D. Evaluation of adsorption parameters and heats of adsorption through desorption measurements. J Chem Eng Data. 2007;52:2419-24.
53. Dunne JA, Mariwala R, Rao M, Sircar S, Gorte RJ, Myers AL. Calorimetric heats of adsorption Isotherms 1. O2, N2, Ar, CO2, CH4, C2H6, and SF6 on silicalite. Langmuir. 1996;12:5888-95.
54. Hurly JJ, Schmidt JW, Boyes SJ, Moldover MR. Virial equation of state of helium, xenon, and helium-xenon mixtures from speed of sound and Burnett pvT measurement. Int J Thermophys. 1997; 18(3):579-634.
55. Bessières D, Lafitte Th, Daridon J-L, Randzio SL. High pressure thermal expansion of gases: measurements and calibration. Thermochim Acta. 2005;428:25-30.
56. Randzio SL, Grolier J-PE, Quint JR. An isothermal scanning calorimeter controlled by linear pressure variations from 0.1 to 400 MPa calibration and comparison with the piezothermal technique. Rev Sci Instrum. 1994;65:960-5.
57. Mahmud S, Zhejun P, James EF, Robert LR Jr, Khaled AMG. Adsorption of methane, nitrogen, carbon dioxide, and their binary mixtures on dry activated carbon at 318.2 K and pressures up to 13.6 MPa. Langmuir. 2003;19:5323-31.
58. Ronny P, Stefan O, Arvind R, Giuseppe S, Marco M. Reliable measurement of near-critical adsorption by gravimetric method. Adsorption. 2006;12:393-403.
59. Gensterblum Y, van Hemert P, Billemont P, Busch A, Charriere D, Lia D, Krooss BM, de Weireld G, Prinz D, Wolf K-HAA. European inter-laboratory comparison of high pressure CO2 sorption isotherms. I: Activated carbon. Carbon. 2009;47: 2958-69.
60. Van Hermet P, Bruining H, Rudolph ES, Wolf KH, Mass JG. Improved manometric setup for the accurate determination of supercritical carbon dioxide sorption. Rev Sci Instrum. 2009;80: 035103.
61. Horvath GG, Kawazoe K. Method for the calculation of effective pore-size distribution in molecular-sieve carbon. J Chem Eng Jpn. 1983;16:470-5