Optimum temperature range for the proton dynamics in H-doped BaZrO 3:Yb dense ceramics-a neutron scattering study

Journal of Materials Research

Volumn 27, Issue 15, 2012, Pages 1939-1949

  Slodczyk, Aneta ^a   Colomban, Philippe ^a   Lamago, Daniel ^b,c   André, Gilles ^b   Zaafrani, Oumaya ^a   Lacroix, Olivier ^d   Sirat, Abdelkader ^d   Grasset, Frédéric ^d   Sala, Béatrice ^d  

^a SORBONNE UNIVERSITÉ   (France)

^b CEA SACLAY   (France)

^c KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^d UNIV MONTPELLIER   (France)

Author keywords

energetic material; ionic conductor; neutron scattering

Indexed keywords

ELECTROLYSERS; ENERGY ACTIVATION; IONIC CONDUCTOR; OPTIMUM TEMPERATURE; PROTON CONDUCTING; PROTON DOPING; PROTON DYNAMICS; PROTON MOTION; PROTONATED; PROTONIC; QUASIELASTIC NEUTRON SCATTERING; STRUCTURAL MODIFICATIONS; TEMPERATURE RANGE; THEORETICAL DENSITY; THERMAL EXPANSION MEASUREMENTS; THERMOGRAVIMETRIC; TRIPLE AXIS SPECTROMETERS; ULTRADENSE; WATER STEAM;

ACTIVATION ENERGY; BARIUM COMPOUNDS; CERAMIC MATERIALS; DYNAMICS; EXPLOSIVES; FUEL CELLS; NEUTRON DIFFRACTION; NEUTRON SCATTERING; PEROVSKITE; YTTERBIUM;

PROTONS;

EID: 84864559792     PISSN: 08842914     EISSN: 20445326     Source Type: Journal    
DOI: 10.1557/jmr.2012.180     Document Type: Article

References (52)

1. M. Ni, M.K.H. Leung, and D.Y.C. Leung: Energy and exergy analysis of hydrogen production by solid oxide steam electrolyzer plant. Int. J. Hydrogen Energy 32, 4648 (2007).
2. G.A. Olah: Beyond oil and gas: The methanol economy. Angew. Chem. Int. Ed. 44, 2636 (2005).
3. H. Iwahara, T. Esaka, H. Uchida, and N. Maeda: Proton conduction in sintered oxides and its application to steam electrolysis for hydrogen production. Solid State Ionics 3-4, 359 (1981).
4. Ph. Colomban ed: Proton Conductors Solids, Membranes and Gel-Materials and Devices (Cambridge University Press, Cambridge, 1992).
5. A.S. Nowick and Y. Du: High-temperature protonic conductors with perovskite-related structures. Solid State Ionics 77, 137 (1995).
6. 3. Solid State Ionics 125, 355 (1999).
7. 3. Solid State Ionics 35, 189 (1989).
8. 2.95. Solid State Ionics 127, 351 (2000).
9. 3 using quantum molecular dynamics. Solid State Ionics 136-137, 183 (2000).
10. Y.M. Baikov, W. Gunther, V.P. Gorelov, Ph. Colomban, and R. Baddour-Hadjean: Hydrogen in perovskites, mechanism of solubility, chemical state, effect on electron subsystem, phase transformation. Ionics 4, 347 (1998).
11. J.T.S. Irvine, D.J.D. Corcoran, A. Lashtabeg, and J.C. Walton: Incorporation of molecular species into the vacancies of perovskite oxides. Solid State Ionics 154-155, 447 (2002).
12. K.D. Kreuer: Proton-conducting oxides. Annu. Rev. Mater. Res. 33, 333 (2003).
13. T. Norby: Protonic conduction in solids: Bulk and interfaces, in Solid State Ionics in the 21st Century, edited by S.Kim, S.Yamaguchi, and J. Elliot (MRS Bull. 34(12), 923 2009).
14. 3-d. Solid State Ionics 180, 990 (2009).
15. 3-d; Part I: Fabrication and Microstructure. Ceramic materials/Book 3, ISBN 978-953-307-505-1 (Intech, Croatia, 2011).
16. B. Sala, O. Lacroix, S. Willemin, K. Rhamouni, H. Takenouti, A. Van der Lee, P. Goeuriot, B. Bendjeriou, and Ph. Colomban: Procédé d'optimisation de la conduction ionique d'une membrane conductrice ionique. AREVA, CNRS, ARMINES, SCT. PCT. Patent No WO 2008/152317 A2, December 12, 2008.
17. Ph. Colomban, A. Slodczyk, D. Lamago, G. Andre, O. Zaafrani, O. Lacroix, S. Willemin, and B. Sala: Proton dynamics and structural modifications in the protonic conductor perovskites. J. Phys. Soc. Jpn. 79, 1 (2010).
18. A. Slodczyk, Ph. Colomban, O. Zaafrani, O. Lacroix, J. Loricourt, F. Grasset, and B. Sala: What is the true nature of conducting proton in perovskite ceramic membrane: Hydroxyl ion or interstitial proton? in Solid-State Chemistry of Inorganic Materials VIII, edited by P.S. Halasyamani, S.J. Clarke, D.G. Mandrus, and K-S. Choi (Mater. Res. Soc. Proc. 1309, Warrendale, PA, 2011); p. 39, mrsf10-1309-ee03-21.
19. Ph. Colomban: Latest developments in proton conductors. Annu. Chimie Sci. Matériaux Paris 24, 1 (1999).
20. Ph. Colomban and J. Tomkinson: Novel forms of hydrogen in solids: The 'ionic' proton and the 'quasi-free' proton. Solid State Ionics 97, 123 (1997).
21. O. Zaafrani: Protonation, distorsions structurales et espèces protoniques dans des perovskites lacunaires. Ph.D. Thesis, Université Pierre et Marie Curie, Paris, 2010.
22. 3. Solid State Ionics 178, 515 (2007).
23. 3-y. J. Alloys Compd. 450, 103 (2008).
24. 2-yO9-d studied by neutron and x-ray powder diffraction. J. Alloys Compd. 328, 226 (2001).
25. 8.73. Solid State Ionics 179, 231 (2008).
26. 3 at 4.2 K: A possible structural site for the proton. Solid State Ionics 127, 43 (2000).
27. 3: Mechanism for large protonic conduction. Phys. Rev. B 54, 15795 (1996).
28. A. Slodczyk, C. Tran, and Ph. Colomban: Face to face with enemy-analysis of aqua carbonate hydroxide second surface phases in proton conducting perovskite ceramic electrolytic membrane, in Advanced Materials for Fuel Cells, edited by J. Hertz, M.L. DiVona, P. Knauth, and H.L. Tuller (Mater. Res. Soc. Proc. 1384, Warrendale, PA, 2012).
29. 2O. Solid State Ionics 180, 1151 (2009).
30. 2O. Solid State Ionics 61, 47 (1993).
31. R. Hempelmann: Hydrogen diffusion mechanism in proton conducting oxides. Physica B 226, 72 (1996).
32. J.Eckert, G.J. Kearley: Spectrochim. Acta, Part A 48, 269-478 (1992).
33. R.E. Lechner: Neutron investigations of superprotonic conductors. Ferroelectrics 167, 83 (1995).
34. 3+ β-alumina. J. Phys. 41, 273 (1980).
35. Ph. Colomban and A. Novak: Proton transfer and superionic conductivity in solids and gel. J. Mol. Struct. 177, 277 (1988).
36. 2.985. Solid State Ionics 77, 152 (1995).
37. 2.985. Solid State Ionics 86-88, 621 (1996).
38. 3-x/2 by quasielastic neutron scattering. Solid State Ionics 97, 497 (1997).
39. 2.95 (A 5 Y and Sc). Solid State Ionics 180, 22 (2009).
40. N. Malikova, C.K. Loong, J.M. Zanotti, and F. Fernandez-Alonso: Proton containing yttrium doped barium cerate: A simultaneous structural and dynamic study by neutron scattering. J. Phys. Chem. C 111, 6574 (2007).
41. A. Slodczyk, Ph. Colomban, D. Lamago, M.H. Limage, F. Romain, S. Willemin, and B. Sala: Phase transitions in the H1-conducting perovskite ceramics by the quasi-elastic neutron and high-pressure Raman scattering. Ionics 14, 215 (2008).
42. A. Slodczyk, B. Dabrowski, N. Malikova, and Ph. Colomban: Origins of rapid aging of Ba-based proton conducting perovskites, in Next-Generation Fuel Cells-New Materials and Concepts, edited by T. He, K. Swider-Lyons, B. Park, and P.A. Kohl (Mater. Res. Soc. Proc. 1311, Warrendale, PA, 2011). mrsf10-1311-gg06-25.
43. 3 modified perovskite protonic conductors. J. Raman Spectrosc. 40, 513 (2009).
44. http://www.llb.cea.fr.
45. 3-AgI glass. J. Non-Cryst. Solids 131-133, 973 (1991).
46. 3. Solid State Ionics 180, 1040 (2009).
47. H.M. Rietveld: Profile refinement method for nuclear and magnetic structures. J. Appl. Cryst. 2, 65 (1969).
48. J. Rodriguez-Carvajal: FullProf software. http://www.ill.eu/.
49. 3 solid solutions. Mater. Chem. Phys. 13, 153 (1985).
50. M. Parlier, G. Sassolas, J.P. Boilot, and Ph. Colomban: Dilatometric study of b-alumina single crystals. Solid State Ionics 2, 185 (1981).
51. A.E. Pasto and R.A. Condrate: The laser Raman spectra of several perovskite zirconates, in edited by J.P. Mathieu (Adv. Spectrosc. Vol. 1, Heyden & Sons Ltd., London, 1973).
52. S. Baliteau, F.Mauvy, S. Fourcade, and J.C. Grenier: Investigation on double perovskite Ba4Ca2Ta2O11. Solid State Sci. 11, 1572 (2009).