Kinetic study of propane dehydrogenation and side reactions over Pt-Sn/Al 2O 3 catalyst

Chemical Engineering Research and Design

Volumn 90, Issue 8, 2012, Pages 1090-1097

  Sahebdelfar, Saeed ^a   Ravanchi, Maryam Takht ^a   Tahriri Zangeneh, Farnaz ^a   Mehrazma, Shokoufeh ^a   Rajabi, Soheila ^a  

^a NATIONAL PETROCHEMICAL COMPANY   (Iran)

Author keywords

Catalyst deactivation; Cracking; Hydrogenolysis; Kinetics; Propane dehydrogenation; Pt Sn catalysts

Indexed keywords

ACTIVE SITE; CATALYTIC SITES; CATALYTIC TESTS; CRACKING REACTIONS; DEACTIVATION RATE; DECAY LAW; DEHYDROGENATION REACTIONS; FIRST-ORDER; FIXED-BED; HYDROGEN CONCENTRATION; KINETIC EXPRESSION; KINETIC STUDY; NON-CATALYTIC; PRODUCT SELECTIVITIES; PROPANE DEHYDROGENATION; QUARTZ REACTORS; SIDE REACTIONS; THERMAL CRACKING;

CATALYST ACTIVITY; CATALYST DEACTIVATION; CRACK INITIATION; DEHYDROGENATION; ENZYME KINETICS; HYDROGEN; HYDROGENOLYSIS; HYDROLYSIS; KINETICS; PLATINUM; PROPANE; PROPYLENE; QUARTZ; RATE CONSTANTS; TIN;

CATALYTIC CRACKING;

EID: 84864519457     PISSN: 02638762     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cherd.2011.11.004     Document Type: Article

References (39)

1. Anderson J.R., Pratt K.C. Introduction to Characterization and Testing of Catalyst 1985, Academic Press, Australia. second ed.
2. Arora V.K. Propylene via CATOFIN propane dehydrogenation technology. Handbook of Petrochemicals Production Processes 2004, 10.43-10.49. McGraw-Hill, New York. R.A. Meyers (Ed.).
3. Bai L., Zhou Y., Zhang Y., Liu H., Sheng X. Effect of alumina binder on catalytic performance of Pt-Sn-Na/ZSM-5 catalyst for propane dehydrogenation. Ind. Eng. Chem. Res. 2009, 48:9885-9891.
4. 3. Catalyst Deactivation 1980, 53-62. Elsevier, Amsterdam. B. Delmon, G.F. Froment (Eds.).
5. Barias O.A., Holmen A., Blekkan E.A. Propane dehydrogenation over supported Pt and Pt-Sn catalysts: catalyst preparation, characterization, and activity measurements. J. Catal. 1996, 158:1-12.
6. Bhasin M.M., McCain J.H., Vora B.V., Imai T., Pujado R.R. Dehydrogenation and oxydehydrogenation of paraffins to olefins to olefins. Appl. Catal. A 2001, 221:397-419.
7. Bird R.B., Stewart W.E., Lightfoot E.N. Transport Phenomena 2002, Wiley, USA. second ed.
8. Bricker, J.C., Jan, D.-Y., Foresman, J.M., 1990. Dehydrogenation catalyst composition. US Patent 4914075, UOP.
9. 3 catalysts. Ind. Eng. Chem. Res. 2001, 40:5557-5563.
10. Chin S.Y., Radzi S.N.R., Maharon I.H., Shafawi M.A. Kinetic model and simulation analysis for propane dehydrogenation in an industrial moving bed reactor. World Acad. Sci. Eng. Technol. 2011, 76:183-189.
11. Heinritz-Adrin M., Thiagarajan N., Wenzel S., Gehrke H. STAR-Uhde's dehydrogenation technology (an alternative route to C3 and C4 olefins). ERTC (European Refining Technology Conference) Petrochemical 2003.
12. Heinritz-Adrian M., Wenzel S., Youssef F. Advanced propane dehydrogenation. Pet. Technol. Q. 2008, 13:83-91.
13. Kogan S.B., Herskowitz M. Selective propane dehydrogenation to propylene on novel bimetallic catalysts. Catal. Commun. 2001, 2:179-185.
14. Kumbilieva K., Gaidai N.A., Nekrasov N.V., Petrov L., Lapidus A.L. Types of active sites and deactivation features of promoted Pt catalysts for isobutane dehydrogenation. Chem. Eng. J. 2006, 120:25-32.
15. Larsson M., Hulten M., Blekkan E.A., Andersson B. The effect of reaction conditions and time on stream on the coke formed during propane dehydrogenation. J. Catal. 1996, 164:44-53.
16. Larese C., Campos-Martin J.M., Fierro J.L.G. Alumina- and zirconia-alumina-loaded tin-platinum. Surface features and performance for butane dehydrogenation. Langmuir 2000, 16:10294-10300.
17. Levenspiel O. Chemical Reaction Engineering 1999, Wiley, New York. third ed.
18. 3 catalyst. Appl. Catal. A 2008, 349:156-164.
19. Miracca I., Piovesan L. Light paraffins dehydrogenation in a fluidized bed reactor. Catal. Today 1999, 52:259-269.
20. Moghimpour Bijani P., Sahebdelfar S. Modeling of a radial-flow moving-bed reactor for dehydrogenation of isobutene. Kinet. Catal. 2008, 49:625-632.
21. Moulijn J.A., van Diepen A.E., Kapteijn F. Catalyst deactivation: is it predictable? What to do. Appl. Catal. A 2001, 212:3-16.
22. Padmavathi G., Chaudhuri K.K., Rajeshwer D., Sreenivasa Rao G., Krishnamurthy K.R., Trivedi P.C., Hathi K.K., Subramanyam N. Kinetics of n-dodecane dehydrogenation on promoted platinum catalyst. Chem. Eng. Sci. 2005, 60:4119-4129.
23. Pujado P., Vora B. Make C3-C4 olefins selectivity. Hydrocarb. Process. - Int. Ed. 1990, 69:65-70.
24. 3 catalyst. Appl. Catal. A 2011, 398:18-26.
25. Resasco D.E. Dehydrogenation - heterogeneous. Encyclopedia of Catalysis 2003, 49-79. Wiley, New York. I.K. Verbeek (Ed.).
26. 3 catalysts: the influence of operating conditions on product selectivity. Iran. J. Chem. Eng. 2010, 7:51-58.
27. Sahebdelfar S., Moghimpour Bijani P., Saeedizad M., Tahriri Zangeneh F., Ganji K. Modeling of adiabatic moving-bed reactor for dehydrogenation of isobutane to isobutene. Appl. Catal. A 2011, 395:107-113.
28. Sanfilippo D., Miracca I. Dehydrogenation of paraffins: synergies between catalyst design and reactor engineering. Catal. Today 2006, 111:133-139.
29. Scott Fogler H. Elements of Chemical Reaction Engineering 1999, Prentice-Hall, New York. third ed.
30. 3/Fe-Cr-Al monolithic catalysts. J. Catal. 2004, 224:404-416.
31. Waku T., Biscardi J.A., Iglesia E. Active, selective, and stable Pt/Na-[Fe]ZSM5 catalyst for the dehydrogenation of light alkanes. Chem. Commun. 2003, (14):1764-1765.
32. 2 removal. J. Catal. 2004, 222:481-492.
33. Weckhuysen B.M., Schoonheydt R.A. Alkane dehydrogenation over supported chromium oxide catalysts. Catal. Today 1999, 51:223-232.
34. 3 catalyst for propane dehydrogenation to propylene. Appl. Catal. A 2006, 315:58-67.
35. 3 catalyst. J. Mol. Catal. A: Chem. 2007, 266:80-87.
36. Zhang Y., Zhou Y., Qiu A., Wang Y., Xu Y., Wu P. Effect of Na addition on catalytic performance of Pt-Sn/ZSM-5 catalyst for propane dehydrogenation. Acta Phys.-Chim. Sin. 2006, 22:672-678.
37. Zhang Y., Zhou Y., Qiu A., Wang Y., Xu Y., Wu P. Effect of alumina binder on catalytic performance of Pt-Sn-Na/ZSM-5 catalyst for propane dehydrogenation. Ind. Eng. Chem. Res. 2006, 45:2213-2219.
38. Zhang Y., Zhou Y., Qiu A., Wang Y., Xu Y., Wu P. Propane dehydrogenation on Pt-Sn/ZSM-5 catalyst: effect of tin as a promoter. Catal. Commun. 2006, 7:862-868.
39. Zhang Y., Zhou Y., Liu H., Wang Y., Xu Y., Wu P. Effect of La addition on catalytic performance of Pt-Sn-Na/ZSM-5 catalyst for propane dehydrogenation. Appl. Catal. A 2007, 333:202-210.