Diastereomerism in tetranuclear copper(II) complexes of a phenol based end-off compartmental ligand

Inorganic Chemistry Communications

Volumn 23, Issue , 2012, Pages 113-116

  Das, Debasis ^a   Guha, Averi ^a   Das, Sudhanshu ^a   Chakraborty, Prateeti ^a   Mondal, Tapan Kumar ^b   Goswami, Somen ^a   Zangrando, Ennio ^c  

^a UNIVERSITY OF CALCUTTA   (India)

^b JADAVPUR UNIVERSITY   (India)

^c UNIVERSITY OF TRIESTE   (Italy)

Author keywords

Catecholase activity; Crystal structure; DFT study; Diastereomeric Cu(II) complex; ESI MS study; Tetranuclear Cu(II)

Indexed keywords

EID: 84864469601     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2012.06.020     Document Type: Article

References (25)

1. J.M. Knaust, and S.W. Keller A mixed-ligand coordination polymer from the in situ, Cu(I)-mediated isomerization of bis(4-pyridyl)ethylene Inorg. Chem. 41 2002 5650 5652
2. A.N. Khlobystov, J. Blake, N.R. Champness, D.A. Lemenovskii, G.N. Majouga, V. Zyk, and M. Schröder Supramolecular design of one-dimensional coordination polymers based on silver(I) complexes of aromatic nitrogen-donor ligands Coord. Chem. Rev. 222 2001 155 192
3. J.A. Bertrand, and J.A. Kelley Five-coordinate complexes. II. Trigonal bipyramidal copper(II) in a metal atom cluster J. Am. Chem. Soc. 88 1966 4746 4747
4. 4-oxo-hexa-μ-chloro-tetrakis {(triphenylphosphine oxide) copper(II) Inorg. Chem. 6 1967 495 498
5. 6 mit tetraedrisch koodiniertem sauerstoff Z. Anorg. Allg. Chem. 357 1968 54 62
6. 4-oxo-bridged copper(II) complexes J. Chem. Soc., Dalton Trans. 1995 2649 2656
7. P. Roy, K. Dhara, M. Manassero, and P. Banerjee Di-, tetra-, and polynuclear copper(II) complexes: active catalysts for oxidation of toluene and benzene Eur. J. Inorg. Chem. 28 2008 4404 4412
8. O. Kahn Molecular Magnetism 1993 VCH Weinheim, Germany
9. J.L. Cole, L. Avigliao, L. Morpugno, and E.I. Solomon Spectroscopic and chemical studies of the ascorbate oxidase trinuclear copper active site: comparison to laccase J. Am. Chem. Soc. 113 1991 9080 9089
10. 4-coordination of the peroxo ligand Angew. Chem. Int. Ed. Engl. 33 1994 1969 1971
11. A. Mukherjee, M.K. Saha, I. Rudra, S. Ramasesha, M. Nethaji, and A.R. Chakravarty Synthesis, crystal structure and magnetic properties of quasi-linear tetranuclear copper(II) Schiff base complexes formed by covalent linkage of asymmetrically dibridged dicopper(II) units Inorg. Chim. Acta 357 2004 1077 1082 and references therein
12. K.C. Gupta, and A.K. Sutar Catalytic activities of Schiff base transition metal complexes Coord. Chem. Rev. 252 2008 1420 1450
13. A.M. Kirillov, M.N. Kopylovich, M.V. Kirillova, M.M. Haukka, F.C. Guedesda.Silva, and A.J.L. Pombeiro Multinuclear copper triethanolamine complexes as selective catalysts for the peroxidative oxidation of alkanes under mild conditions Angew. Chem. Int. Ed. 44 2005 4345 4349
14. R.L. Lieberman, and A.C. Rosenzweig Crystal structure of a membrane-bound metalloenzyme that catalyses the biological oxidation of methane Nature 434 2005 177 182
15. 3-oxo-bridged trinuclear Cu(II) complex: correlation to the native intermediate of the multicopper oxidases Inorg. Chem. 44 2005 8076 8086
16. 4] head groups: syntheses, structures, langmuir films, and effect of subphase changes Eur. J. Inorg. Chem. 31 2009 4686 4694
17. 4] soft materials Chem. Eur. J. 13 2007 9948 9956
18. 3-hydroxido-bridged copper azide and copper thiocyanate stepped cubanes: core conversion, structural diversity, and magnetic properties Inorg. Chem. 49 2010 6575 6585
19. 4-oxo-bridged copper(II) complexes: magnetic properties and catalytic applications in liquid phase partial oxidation reactions Dalton Trans. 2009 9543 9554
20. 4, (bdmmpH = 2,6-bis[(dimethylamino) methy1]-4-methylphenol; hfacac = hexa-fluoroacetylacetonato) Inorg. Chem. 34 1995 454 465
21. P. Roy, and M. Manassero Tetranuclear copper(II)-Schiff-base complexes as active catalysts for oxidation of cyclohexane and tolune Dalton Trans. 39 2010 1539 1545
22. 4-oxo)tetrakis(μ-benzoato)bis(μ-2,6- bis (morpholinomethyl)-4-methylphenolato) tetra copper(II) Inorg. Chem. 33 1994 456 464
23. A.D. Becke Density-functional thermochemistry. III. The role of exact exchange J. Chem. Phys. 98 1993 5648 5652
24. P.J. Stevens, J.F. Devlin, C.F. Chabalowski, and M.J. Frisch Ab initio calculation of vibrational absorption and circular dichroism spectra using density functional force fields J. Phys. Chem. 98 1994 11623 11627
25. Gaussian 03, Revision D.01 2004 Gaussian Inc. Wallingford CT