Bis(tridentate) ruthenium-terpyridine complexes featuring microsecond excited-state lifetimes

Journal of the American Chemical Society

Volumn 134, Issue 30, 2012, Pages 12354-12357

  Brown, Douglas G ^a   Sanguantrakun, Nawaporn ^a   Schulze, Benjamin ^b   Schubert, Ulrich S ^b   Berlinguette, Curtis P ^a  

^a UNIVERSITY OF CALGARY   (Canada)

^b FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CARBENE LIGANDS; EXCITED-STATE LIFETIME; FOUR-ORDER; HETEROLEPTIC; LIGAND FIELD; METAL-TO-LIGAND CHARGE TRANSFER STATE; ROOM TEMPERATURE; RUTHENIUM COMPLEXES; TERPYRIDINES; UNIMOLECULAR;

CHARGE TRANSFER; EXCITED STATES; RUTHENIUM; RUTHENIUM COMPOUNDS;

LIGANDS;

2',6' BIS(1 MESITYL 3 METHYL 1,2,3 TRIAZOL 4 YL 5 IDENE)PYRIDINE; 2,2':6',2'' TERPYRIDINE LIGAND; BIS(TRIDENTATE)RUTHENIUM TERPYRIDINE COMPLEX; CARBENE; PYRIDINE DERIVATIVE; RUTHENIUM COMPLEX; TRIDENTATE CARBENE LIGAND; UNCLASSIFIED DRUG;

ARTICLE; ATOMIC EMISSION SPECTROMETRY; CHROMATOPHORE; ELECTROCHEMISTRY; ENERGY TRANSFER; EXCITATION; METAL TO LIGAND CHARGE TRANSFER; MICROSECOND EXCITED STATE LIFETIME; ROOM TEMPERATURE; SEPARATION TECHNIQUE;

COORDINATION COMPLEXES; LIGANDS; METHANE; PYRIDINES; RUTHENIUM;

EID: 84864436659     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3039536     Document Type: Article

References (27)

1. Campagna, S.; Puntoriero, F.; Nastasi, F.; Bergamini, G.; Balzani, V. Top. Curr. Chem. 2007, 280, 117
2. Hofmeier, H.; Schubert, U. S. Chem. Soc. Rev. 2004, 33, 373
3. Ardo, S.; Meyer, G. J. Chem. Soc. Rev. 2009, 38, 115
4. Alstrum-Acevedo, J. H.; Brennaman, M. K.; Meyer, T. J. Inorg. Chem. 2005, 44, 6802
5. Bomben, P. G.; Robson, K. C. D.; Berlinguette, C. P. Coord. Chem. Rev. 2012, 256, 1438
6. Tyson, D. S.; Luman, C. R.; Zhou, X.; Castellano, F. N. Inorg. Chem. 2001, 40, 4063
7. Damrauer, N. H.; Cerullo, G.; Yeh, A.; Boussie, T. R.; Shank, C. V.; McCusker, J. K. Science 1997, 275, 54
8. Baranoff, E.; Collin, J.-P.; Flamigni, L.; Sauvage, J.-P. Chem. Soc. Rev. 2004, 33, 147
9. Schramm, F.; Meded, V.; Fliegl, H.; Fink, K.; Fuhr, O.; Qu, Z.; Klopper, W.; Finn, S.; Keyes, T. E.; Ruben, M. Inorg. Chem. 2009, 48, 5677
10. Breivogel, A.; Förster, C.; Heinze, K. Inorg. Chem. 2010, 49, 7052
11. Hammarström, L.; Johansson, O. Coord. Chem. Rev. 2010, 254, 2546
12. Abrahamsson, M.; Jäger, M.; Osterman, T.; Eriksson, L.; Persson, P.; Becker, H.-C.; Johansson, O.; Hammarström, L. J. Am. Chem. Soc. 2006, 128, 12616
13. Österman, T.; Abrahamsson, M.; Becker, H.-C.; Hammarström, L.; Persson, P. J. Phys. Chem. A 2012, 116, 1041
14. Abrahamsson, M.; Jäger, M.; Kumar Rohan, J.; Osterman, T.; Persson, P.; Becker, H.-C.; Johansson, O.; Hammarström, L. J. Am. Chem. Soc. 2008, 130, 15533
15. Robson, K. C. D.; Koivisto, B. D.; Yella, A.; Sporinova, B.; Nazeeruddin, M. K.; Baumgartner, T.; Grätzel, M.; Berlinguette, C. P. Inorg. Chem. 2011, 50, 5494
16. Koivisto, B. D.; Robson, K. C. D.; Berlinguette, C. P. Inorg. Chem. 2009, 48, 9644
17. Schulze, B.; Escudero, D.; Friebe, C.; Siebert, R.; Görls, H.; Sinn, S.; Thomas, M.; Mai, S.; Popp, J.; Dietzek, B.; González, L.; Schubert, U. S. Chem.-Eur. J. 2012, 18, 3785
18. Medlycott, E. A.; Hanan, G. S. Chem. Soc. Rev. 2005, 34, 133
19. Collin, J. P.; Beley, M.; Sauvage, J. P.; Barigelletti, F. Inorg. Chim. Acta 1991, 186, 91
20. Djukic, J. P.; Sortais, J. B.; Barloy, L.; Pfeffer, M. Eur. J. Inorg. Chem. 2009, 817
21. Chi, Y.; Chou, P.-T. Chem. Soc. Rev. 2007, 36, 1421
22. Constable, E. C.; Thompson, A.; Tocher, D. A.; Daniels, M. A. M. New J. Chem. 1992, 16, 855
23. Collin, J. P.; Kayhanian, R.; Sauvage, J. P.; Calogero, G.; Barigelletti, F.; DeCian, A.; Fischer, J. Chem. Commun. 1997, 775
24. Son, S. U.; Park, K. H.; Lee, Y.-S.; Kim, B. Y.; Choi, C. H.; Lah, M. S.; Jang, Y. H.; Jang, D.-J.; Chung, Y. K. Inorg. Chem. 2004, 43, 6896
25. Schulze, B.; Escudero, D.; Friebe, C.; Siebert, R.; Görls, H.; Köhn, U.; Altuntas, E.; Baumgaertel, A.; Hager, M. D.; Winter, A.; Dietzek, B.; Popp, J.; González, L.; Schubert, U. S. Chem.-Eur. J. 2011, 17, 5494
26. Ung, G.; Bertrand, G. Chem.-Eur. J. 2011, 17, 8269
27. There are examples of mononuclear ruthenium complexes with slightly longer lifetimes where emission is primarily ligand-based, e.g.: Wang, X. Y.; Del Guerzo, A.; Baitalik, S.; Simon, G.; Shaw, G. B.; Chen, L. X.; Schmehl, R. Photosynth. Res. 2006, 87, 83