Protecting-group-free catalytic asymmetric total synthesis of (-)-rosmarinecine

Tetrahedron

Volumn 68, Issue 36, 2012, Pages 7295-7301

  Nemoto, Hiroyuki ^a   Tanimoto, Kouichi ^b   Kanao, Yukiko ^b   Omura, Sohei ^b   Kita, Yasuyuki ^b,c   Akai, Shuji ^a  

^a UNIVERSITY OF SHIZUOKA   (Japan)

^b OSAKA UNIVERSITY   (Japan)

^c RITSUMEIKAN UNIVERSITY   (Japan)

Author keywords

3+2 Dipolar cyclization; Dynamic kinetic resolution; Lipase; Protecting group free; Rosmarinecine; Total synthesis

Indexed keywords

3 (TERT BUTYLDIMETHYLSILYL)OXY 1 PYRROLINE N OXIDE; 3 (TERT BUTYLDIMETHYLSILYLOXY)PYRROLIDINE; 3 ACETOXY 1 PYRROLINE N OXIDE; 3 HYDROXY 1 PYRROLINE N OXIDE; 3 HYDROXY 2,4 DIOXOHEXAHYDROFURO [2,3,4 GH]PYRROLIZINE; 3 HYDROXYPYRROLIDINE; 3 METHOXY 1 -PYRROLINE N OXIDE; 4 (TERT BUTYLDIMETHYLSILYL)OXY 1 PYRROLINE N OXIDE; 4 HYDROXY 1 PYRROLINE N OXIDE; 4 METHOXY 1 PYRROLINE N OXIDE; ALKALOID DERIVATIVE; ETHYL 2 OXOHEXAHYDRO 1,4 DIOXA 4A AZACYCLOPENTA[CD]PENTALENE 3 CARBOXYLATE; METHYL 2 OXOHEXAHYDRO 1,4 DIOXA 4A AZACYCLOPENTA[CD]PENTALENE 3 CARBOXYLATE; ROSMARINECINE; TRIACYLGLYCEROL LIPASE; UNCLASSIFIED DRUG;

ARTICLE; CANDIDA ANTARCTICA; CATALYSIS; CHEMICAL REACTION; CYCLOADDITION; NONHUMAN; OXIDATION; PRIORITY JOURNAL; RACEMIZATION; REACTION OPTIMIZATION; SYNTHESIS; TAUTOMERIZATION;

EID: 84864284106     PISSN: 00404020     EISSN: 14645416     Source Type: Journal    
DOI: 10.1016/j.tet.2012.06.095     Document Type: Article

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