Reactivity patterns of O 2, CO 2, carboxylic acids, and triflic acid with molybdenum silyl hydrido complexes bearing polydentate phosphinoalkyl-silyl ligands: Pronounced effects of silyl ligands on reactions

Organometallics

Volumn 31, Issue 14, 2012, Pages 4941-4949

  Minato, Makoto ^a   Zhou, Da Yang ^a,c   Sumiura, Ken Ichiro ^a   Oshima, Yuki ^a   Mine, Shigeki ^a   Ito, Takashi ^a   Kakeya, Masaki ^a   Hoshino, Kei ^a   Asaeda, Takahiro ^a   Nakada, Takushi ^a   Osakada, Kohtaro ^b  

^a YOKOHAMA NATIONAL UNIVERSITY   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^c OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BENZOIC ACID; CARBON DIOXIDE HYDROGENATION; CARBOXYLATE LIGANDS; CARBOXYLATO; CENTRAL ATOM; CYCLOHEXYL; DIOXYGEN LIGANDS; DIOXYGENS; ELECTRON-DONATING SUBSTITUENTS; ELECTRONIC EFFECTS; ELECTRONWITHDRAWING; HYDRIDO COMPLEXES; HYDROXO COMPLEXES; MOLYBDENUM COMPLEX; MONODENTATES; PHENYL GROUP; REACTIVITY PATTERN; SI ATOMS; SILYL LIGANDS; SINGLE CRYSTAL X-RAY DIFFRACTION; TRANS INFLUENCE; TRIFLATO; TRIFLIC ACIDS; X-RAY STUDIES;

ACETIC ACID; ATOMS; CARBON DIOXIDE; CARBOXYLATION; CATALYST ACTIVITY; FORMIC ACID; LIGANDS; MOLYBDENUM; SILICON; X RAY DIFFRACTION;

MOLYBDENUM COMPOUNDS;

EID: 84864221135     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om200646c     Document Type: Article

References (42)

1. Tilley, T. D. In The Chemistry of Organic Silicon Compounds; Patai, S. and Rappaport, Z., Eds.; Wiley: New York, 1989; Part 2, Chapter 24.
2. Tilley, T. D. In The Silicon-Heteroatom Bond; Patai, S. and Rappaport, Z., Eds.; Wiley: New York, 1991; Chapter 10.
3. Corey, J. Y.; Braddock-Wilking, J. Chem. Rev. 1999, 99, 175
4. Zhou, D.-Y.; Minato, M.; Ito, T.; Yamasaki, M. Chem. Lett. 1997, 1017
5. Zhou, D.-Y.; Zhang, L.-B.; Minato, M.; Ito, T.; Osakada, K. Chem. Lett. 1998, 187
6. Kubas, G. J. In Metal Dihydrogen and σ-Bond Complexes; Kluwer: New York, 2001; pp 339-340.
7. Minato, M.; Zhou, D.-Y.; Zhang, L.-B.; Hirabayashi, R.; Kakeya, M.; Matsumoto, T.; Harakawa, A.; Kikutsuji, G.; Ito, T. Organometallics 2005, 24, 3434
8. Auburn, M. J.; Holmes-Smith, R. D.; Stobart, S. R. J. Am. Chem. Soc. 1984, 106, 1314
9. Auburn, M. J.; Grundy, S. L.; Stobart, S. R.; Zaworotko, M. J. J. Am. Chem. Soc. 1985, 107, 266
10. Auburn, M. J.; Stobart, S. R. Inorg. Chem. 1985, 24, 318
11. Holmes-Smith, R. D.; Stobart, S. R.; Vefghi, R.; Zaworotko, M. J.; Jochem, K.; Cameron, T. S. J. Chem. Soc., Dalton Trans. 1987, 969
12. Okazaki, M.; Ohshitanai, S.; Tobita, H.; Ogino, H. Chem. Lett. 2001, 952
13. Okazaki, M.; Tobita, H.; Ogino, H. J. Chem. Soc., Dalton Trans. 2002, 2061
14. Sangtrirutnugul, P.; Stradiotto, M.; Tilley, T. D. Organometallics 2006, 25, 1607
15. Takaya, J.; Iwasawa, N. J. Am. Chem. Soc. 2008, 130, 15254
16. MacInnis, M.; McDonald, R.; Ferguson, M. J.; Tobisch, S.; Turculet, L. J. Am. Chem. Soc. 2011, 133, 13622
17. Lee, Y.; Peters, J. J. Am. Chem. Soc. 2011, 133, 4438
18. Chatt, J.; Eaborn, C.; Ibekwe, S. J. Chem. Soc., Chem. Commun. 1966, 700
19. McWeeny, R.; Mason, R.; Towl, A. D. C. Discuss. Faraday Soc. 1969, 47, 20
20. Haszeldine, R. N.; Parish, R. V.; Setchfield, J. H. J. Organomet. Chem. 1973, 57, 279
21. Minato, M.; Nishiuchi, J.; Kakeya, M.; Matsumoto, T.; Yamaguchi, Y.; Ito, T. Dalton Trans. 2003, 483
22. Minato, M.; Kikutsuji, G.; Kakeya, M.; Osakada, K.; Yamasaki, M. Dalton Trans. 2009, 7684
23. Minato, M.; Zhou, D.-Y.; Sumiura, K.; Hirabayashi, R.; Yamaguchi, Y.; Ito, T. Chem. Commun. 2001, 2654
24. Dickman, M. H.; Pope, M. T. Chem. Rev. 1994, 94, 569
25. Kitajima, N.; Fujisawa, K.; Fujimoto, C.; Moro-oka, Y.; Hashimoto, S.; Kitagawa, T.; Toriumi, T.; Tatsumi, K.; Nakamura, A. J. Am. Chem. Soc. 1992, 114, 1277
26. Mezzetti, A.; Zangrando, E.; Del Zotto, A.; Rigo, P. Chem. Commun. 1994, 1597
27. Legzdins, P.; Phillips, E. C.; Rettig, C. J.; Sánchez, L.; Trotter, J.; Yee, V. C. Organometallics 1988, 7, 1877
28. Cotton, F. A.; Wilkinson, G. In Advanced Inorganic Chemistry, 5 th ed.; Wiley: New York, 1988; p 469.
29. Nakamoto, K. In Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3 rd ed.; Wiley: New York, 1977; pp 230-233.
30. Ito, T.; Takahashi, A.; Tamura, S. Bull. Chem. Soc. Jpn. 1986, 59, 3489
31. Ito, T.; Matsubara, T.; Yamashita, Y. J. Chem. Soc., Dalton Trans. 1990, 2407
32. Ito, T.; Shimada, K.; Ono, T.; Minato, M.; Yamaguchi, Y. J. Oranomet. Chem. 2000, 611, 308
33. Sneeden, R. P. A. In Comprehensive Organometallic Chemistry; Wilkinson, G., Ed.; Pergamon Press: Oxford, U.K., 1982; Vol. 8, pp 225-283.
34. Ito, T.; Matsubara, T. J. Chem. Soc., Dalton Trans. 1988, 2241
35. Jessop, P. G.; Ikariya, T.; Noyori, R. Chem. Rev. 1995, 95, 259 and references cited therein
36. Mitchell, J. A.; Reid, E. E. J. Am. Chem. Soc. 1931, 53, 1879
37. Jessop, P. G.; Hsiao, Y.; Ikariya, T.; Noyori, R. J. Am. Chem. Soc. 1994, 116, 8851
38. Hutschka, H.; Dedieu, A.; Eichberger, M.; Fornika, R.; Leitner, W. J. Am. Chem. Soc. 1997, 119, 4432
39. Beck, W. Inorg. Synth. 1990, 28, 1 and references cited therein
40. Molander, G. A.; Corrette, C. P. Organometallics 1998, 17, 5504
41. Cotton, F. A.; Wilkinson, G. In Advanced Inorganic Chemistry, 5 th ed.; Wiley: New York, 1988; p 464.
42. Mine, S.; Minato, M. To be submitted for publication.