Nanocasted Cs salt of phosphomolybdic acid: A new system for selective oxidation of alcohols

Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

Volumn 42, Issue 6, 2012, Pages 805-810

  Fazaeli, Razieh ^a   Aliyan, Hamid ^a   Poorgholam, Mohammad Reza ^a  

^a ISLAMIC AZAD UNIVERSITY   (Iran)

Author keywords

green chemistry; heteropoly acids; HPAs; mesoporous silica SBA 15; nanocasting

Indexed keywords

EID: 84864063002     PISSN: 15533174     EISSN: 15533182     Source Type: Journal    
DOI: 10.1080/15533174.2011.617347     Document Type: Article

References (17)

1. Sing, K.S.W.; Everett, D.H.; Haul, R.A. W.; Moscou, L.; Pierotti, R.A.; Rouquérol, J.; Siemieniewska, T. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl. Chem. 1985, 57, 603-619.
2. Schüth, F. Endo-and Exotemplating to create high-surface-area inorganic materials. Angew. Chem. Int. Ed. Engl. 2003, 42, 3604-3622.
3. Lu, A.-H.; Schüth, F. Nanocasting pathways to create ordered mesoporous solids. C.R. Acad. Sci., Ser. IIc: Chim. 2005, 8, 609-620.
4. Kozhevnikov, I.V. In Catalysts for Fine Chemical Synthesis, Catalysis by Polyoxometalates 2, E. Derouane, ed. Wiley: New York, 2002.
5. Okuhara, T.; Mizuno, N.; Misono, M. Catalytic chemistry of heteropoly compounds. Adv. Catal. 1996, 41, 113-252.
6. Ono, Y.; Thomas, J.M.; Zamaraev, K.I., eds. Perspectives in Catalysis; Blackwell: London, 1992.
7. Dewan, A.; Sarma, T.; Bora, U.; Kakati, D.K. Rapid and selective oxidation of benzyl alcohpls to aldehydes and ketones with novel vanadium polyoxometalate under solvent-free conditions. Tetrahedron Lett. 2011, 52, 2563-2565.
8. Cosner, C.C.; Cabrera, P.J.; Byrd, K.M.; Thomas, A.M.A.; Helquist, P. Selective oxidation of benzylic and allylic alcohols using Mn(OAc)(3)/Catalytic 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone. Org. Lett. 2011, 13, 6-8.
9. Hajipour, A.R.; Khazdooz, L.; Ruoho, A.E. Oxidation of benzylic alcohols to their corresponding carbonyl compounds using ceric ammonium nitrate (CAN)/Brönsted acidic ionic liquid. J. Iran. Chem. Soc. 2011, 8, 382-387.
10. Zhou, C.; Chen, Y.; Guo, Z.; Wang, X.; Yang, Y. Promoted aerobic oxidation of benzyl alcohol on CNT supported platinum by iron oxide. Chem. Commun. 2011, 47, 7473-7475.
11. Fazaeli, R.; Tangestaninejad, S.; Aliyan, H.; Moghadam, M. One-pot synthesis of dihydropyrimidinones using facile and reusable polyoxometalate catalysts for the Biginelli reaction. Appl. Catal., A 2006, 309, 44-51.
12. Fazaeli, R.; Tangestaninejad, S.; Aliyan, H. Highly efficient conversion of aldehydes to geminal diacetates (solvent-free) and their deprotection using facile and reusable molybdenum and tungsten polyoxometalates. Appl. Catal., A 2007, 318, 218-226.
13. Fazaeli, R.; Aliyan, H. Clay (KSF and K10)-supported heteropoly acids: Friendly, efficient, reusable and heterogeneous catalysts for high yield synthesis of 1,5-benzodiazepine derivatives both in solution and under solventfree conditions. Appl. Catal., A 2007, 331, 78-83.
14. Fazaeli, R.; Aliyan, H.A Heterogeneous catalyst for efficient synthesis of 2-arylbenzothiazoles and 2-arylbenzimidazoles. Appl. Catal., A 2009, 353, 74-79.
15. Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G.H.; Chmelka, B.F.; Stucky, G.D. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 Angstrom pores. Science 1998, 279, 548-552.
16. Kozhevnikov, I.V. Catalysis by Polyoxometalates; Wiley, England, 2002.
17. Rao, P.M.; Goldberg-Oppenheimer, P.; Kababya, S.; Vega, S.; Landau. M.V. Proton enriched high-surface-area cesium salt of phosphotungstic heteropolyacid with enhanced catalytic activity fabricated by nanocasting strategy. J. Mol. Catal. A: Chem, 2007, 275, 214-227.