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C. Chatgilialoglu, A. Studer, John Wiley & Sons Ltd Chichester, UK
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D. Gigmes, and S. Marque C. Chatgilialoglu, A. Studer, Nitroxide-Mediated Polymerization and its Applications in Encyclopedia of Radicals in Chemistry Biology and Materials 2012 John Wiley & Sons Ltd Chichester, UK 1813 1850
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D. Bertin, D. Gigmes, S.R.A. Marque, R. Maurin, and P. Tordo J. Polym. Sci., Part A: Polym. Chem. 42 2004 3504 3515
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D. Gigmes, J. Vinas, N. Chagneux, C. Lefay, T.N.T. Phan, T. Trimaille, P.-E. Dufils, Y. Guillaneuf, G. Carrot, F. Boué, and D. Bertin ACS Symp. 1024 2009 245 262
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Dufils, P.-E.7
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P. Brémond, A. Koïta, S.R.A. Marque, V. Pesce, V. Roubaud, and D. Siri Org. Lett. 14 2012 358 361
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Brémond, P.1
Koïta, A.2
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Pesce, V.4
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Siri, D.6
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9
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D. Bertin, D. Gigmes, S.R.A. Marque, S. Milardo, J. Peri, and P. Tordo Collect. Czech. Chem. Commun. 69 2004 2223 2238
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2 requires warming of the solution above 50 °C (see for example A.B. Attygalle, U. Nishshanka, and C.S. Weisbecker J. Am. Soc. Mass. Spectrom. 2011 1515 1525 As warming is precluded with labile alkoxyamine such as 2, it may occur that the formation of pivaloyl-type chloride was very slow at room temperature, favoring the occurrence of side-reactions and hence the decomposition of the starting material.
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Attygalle, A.B.1
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a cannot be estimated with high reliability due to intimate ion pair effect which depends dramatically on the solvent, see: Audran, G.; Brémond, P.; Marque, S. R. A.; Obame, G., submitted for publication. However, the homolysis will not be faster than for 2, see D. Bertin, D. Gigmes, S.R.A. Marque, D. Siri, P. Tordo, and G. Trappo Chem. Phys. Chem. 9 2008 272 281
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E. Beaudoin, D. Bertin, D. Gigmes, S.R.A. Marque, D. Siri, and P. Tordo Eur. J. Org. Chem. 2006 1755 1768
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C. Dire, J. Nicolas, S. Brusseau, B. Charleux, S. Magnet, and L. Couvreur ACS Symp. 1024 2009 303 318
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