Site-specific transition metal occupation in multicomponent pyrophosphate for improved electrochemical and thermal properties in lithium battery cathodes: A combined experimental and theoretical study

Journal of the American Chemical Society

Volumn 134, Issue 28, 2012, Pages 11740-11748

  Shakoor, Rana A ^a   Kim, Heejin ^a   Cho, Woosuk ^b   Lim, Soo Yeon ^a   Song, Hannah ^c   Lee, Jung Woo ^a   Kang, Jeung Ku ^a   Kim, Yong Tae ^c   Jung, Yousung ^a   Choi, Jang Wook ^a  

^a Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

^b Korea Electronic Technology Institute (KETI)   (South Korea)

^c Pusan National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

BATTERY MATERIALS; BATTERY PROPERTIES; CATHODE MATERIALS; CELL POTENTIAL; ELECTRICAL VEHICLES; EXCELLENT PERFORMANCE; FIRST-PRINCIPLES CALCULATION; LI INSERTION/EXTRACTION; LI INTERCALATION; LITHIUM BATTERY CATHODES; LITHIUM INSERTION; LITHIUM-ION BATTERY; MOBILE ELECTRONICS; MULTI-COMPONENT SYSTEMS; MULTICOMPONENTS; OVERPOTENTIAL; POLYANIONS; SITE-SPECIFIC; THEORETICAL STUDY; UTILITY GRIDS; VOLUME CHANGE;

CATHODES; CHARGING (BATTERIES); ELECTRIC VEHICLES; LITHIUM BATTERIES; LITHIUM COMPOUNDS; MANGANESE; MANGANESE COMPOUNDS; REDOX REACTIONS; TRANSITION METALS;

LITHIUM;

COBALT; FERRIC ION; FERROUS ION; LITHIUM ION; MANGANESE; POLYANION; PYROPHOSPHATE; TRANSITION ELEMENT;

ARTICLE; CALCULATION; CONTROLLED STUDY; CRYSTAL STRUCTURE; ELECTRIC BATTERY; ELECTRIC POTENTIAL; ELECTROCHEMISTRY; EXPERIMENTAL STUDY; INTERCALATION COMPLEX; OXIDATION REDUCTION REACTION; SOLID; SURFACE CHARGE; THEORETICAL STUDY; THERMAL CONDUCTIVITY; THERMOSTABILITY;

EID: 84863966511     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3042228     Document Type: Article

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