Etherification of glycerol by tert-butyl alcohol: Kinetic model

Industrial and Engineering Chemistry Research

Volumn 51, Issue 28, 2012, Pages 9500-9509

  Pico, M Pilar ^a   Romero, Arturo ^a   Rodríguez, Sergio ^a   Santos, Aurora ^a  

^a UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

AMBERLYST-15; AUTOCLAVE REACTORS; AUTOGENOUS PRESSURE; CATALYST LOADINGS; COMMERCIAL RESINS; DATA FITTINGS; DIETHERS; ETHERIFICATION REACTIONS; KINETIC EQUATIONS; KINETIC MODELS; MAGNETIC STIRRING; OPERATING CONDITION; PROCESS PERFORMANCE; PRODUCT DISTRIBUTIONS; SECONDARY REACTIONS; STOICHIOMETRIC EQUATION; STRONG ACIDS; TEMPERATURE RANGE; TERT-BUTYL ALCOHOLS;

BUTENES; CATALYST ACTIVITY; DEHYDRATION; ETHERS; GLYCEROL; INTEGRAL EQUATIONS; ION EXCHANGE; KINETIC THEORY; LOADING;

KINETICS;

EID: 84863895876     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie300481d     Document Type: Article

References (34)

1. Paniri, G.; Ghaziaskar, H. S.; Rezayat, M. Ternary solubility of mono- and di- tert -butyl ethers of glycerol in supercritical carbon dioxide J. Supercrit. Fluids 2010, 55, 43-48
2. Demirbas, A. Progress and recent trends in biofuels Prog. Energy Combust. Sci. 2007, 33, 1-18 (Pubitemid 44827524)
3. Lotero, E.; Liu, Y.; Lopez, D. E.; Suwannakarn, K.; Bruce, D. A.; Goodwin, J. G., Jr. Synthesis of Biodiesel via Acid Catalysis Ind. Eng. Chem. Res. 2005, 44, 5353-5363
4. Bozbas, K. Biodiesel as an alternative motor fuel: Production and policies in the European Union Renewable Sustainable Energy Rev. 2008, 12, 542-552 (Pubitemid 350214539)
5. Rahmat, N.; Abdullah, A. Z.; Mohamed, A. R. Recent progress on innovative and potential technologies for glycerol transformation into fuel additives: A critical review Renewable Sustainable Energy Rev. 2010, 14, 987-1000
6. Zhou, C. C.; Beltramini, J. N.; Fan, Y.; Lu, G. Q. Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals Chem. Soc. Rev. 2008, 37, 527-549
7. Melero, J. A.; Vicente, G.; Morales, G.; Paniagua, M.; Bustamante, J. Oxygenated compounds derived from glycerol for biodiesel formulation: Influence on EN 14214 quality parameters Fuel 2010, 88 (8) 2011-2018
8. Balaraju, M.; Rekha, V.; Prasad, S. P. S.; Prabhavathi Devi, B. L. A.; Prasad, R. B. N.; Lingaiah, N. Influence of solid acids as co-catalysts on glycerol hydrogenolysis to propylene glycol over Ru/C catalysts Appl. Catal. A 2009, 354, 82-87
9. Climent, M. J.; Corma, A.; Frutos, P. D.; Iborra, S.; Noy, M.; Velty, A.; Concepción, P. Chemicals from biomass: Synthesis of glycerol carbonate by transesterification and carbonylation with urea with hydrotalcite catalysts. The role of acid-base pairs J. Catal. 2010, 269, 140-149
10. Chang, J. S.; Chen, D. H. Optimization on the etherification of glycerol with tert -butyl alcohol J. Taiwan Inst. Chem. Eng. 2011, 42, 760-767
11. Jong Lee, H.; Seung, D.; Filimonov, I. N.; Kim, H. Etherification of glycerol by isobutylene. Effects of the density of acidic sites in ion-exchange resin on the distribution of products Korean J. Chem. Eng. 2011, 28, 756-762
12. Ancillotti, F.; Fattore, V. Oxygenate fuels: Market expansion and catalytic aspect of synthesis Fuel Process. Technol. 1998, 57, 163
13. Lee, H. J.; Seung, D.; Jung, K. S.; Kim, H.; Filimonov, I. N. Etherification of glycerol by isobutylene: Tuning the product composition Appl. Catal. A 2010, 390, 235-244
14. Klepácová, K.; Mravec, D.; Hájeková, E.; Bajus, M. Etherification of glycerol Pet. Coal 2003, 45 (1-2) 54-57
15. Klepácová, K.; Mravec, D.; Bajus, M. tert -Butalytion of glycerol catalysed by ion-exchange resins Appl. Catal. A 2005, 294, 141-147
16. Klepácová, K.; Mravec, D.; Kaszonyi, A.; Bajus, M. Etherification of glycerol and ethylene glycol by isobutylene Appl. Catal. A 2007, 328, 1-3
17. Melero, J. A.; Vicente, G.; Morales, G.; Paniagua, M.; Moreno, J. M.; Roldán, R.; Ezquerro, A.; Pérez, C. Acid-catalyzed etherification of bio-glycerol and isobutylene over sulfonic mesostructured silicas Appl. Catal. A 2008, 346, 44-51
18. Zhao, W.; Yang, B.; Yi, C.; Lei, Z.; Xu, J. Etherification of Glycerol with Isobutylene to Produce Oxygenate Additive Using Sulfonated Peanut Shell Catalyst Ind. Eng. Chem. Res. 2010, 49, 12399-12404
19. Silva, V. T. M.; Pereira, C.; Rodrigues, A. E. PermSMBR - A New Hybrid Technology: Application on Green Solvents and Biofuel Production AIChE J. 2011, 57, 1841-1851
20. Pereira, C.; Silva, V. T. M.; Rodrigues, A. E. Ethyl lactate as a solvent: Properties, applications and production processes - A review Green Chem. 2011, 13, 2658-2671
21. Behr, A.; Obendorf, L. Development of a process for the acid-catalyzed etherification of glycerine and isobutene forming glycerine tertiary butyl ethers Eng. Life Sci. 2003, 2 (7) 185-189
22. Karinen, R. S.; Krause, A. O. I. New biocomponents from glycerol Appl. Catal. A 2006, 306, 128-133
23. Di Serio, M.; Casale, L.; Tesser, R.; Santacesaria, E. New Process for the Production of Glycerol tert -Butyl Ethers Energy Fuels 2010, 24, 4668-4672
24. Frusteri, F.; Arena, F.; Bonura, G.; Cannilla, C.; Spadaro, L.; Di Blasi, O. Catalytic Etherification of Glycerol by tert -Butyl Alcohol to Produce Oxygenated Additives for Diesel Fuels Appl. Catal. A 2009, 367, 77-83
25. Ozbay, N.; Oktar, N.; Dogu, G.; Dogu, T. Conversion of Biodiesel By-Product Glycerol to Fuel Ethers over Different Solid Acid Catalysts Int. J. Chem. Reactor Eng. 2010, 8, A18
26. Kiatkittipong, W.; Intaracharoen, P.; Laosiripojana, N.; Chaisuk, C.; Praserthdam, P.; Assabumrungrat, S. Glycerol ethers synthesis from glycerol etherification with tert -butyl alcohol in reactive distillation Comput. Chem. Eng. 2011, 35, 2034-2043
27. Janaun, J.; Ellis, N. Glycerol Etherification by tert -Butanol Catalyzed by Sulfonated Carbon Catalyst J. Appl. Sci. 2010, 10 (21) 2633-2637
28. Klepácová, K.; Mravec, D.; Bajus, M. Etherification of glycerol with tert -butyl alcohol catalysed by ion-exchange resins Chem. Pap. 2006, 60 (3) 224-230 (Pubitemid 44220278)
29. Jamróz, M. E.; Jarosz, M.; Witowska-Jarosz, J.; Bednarek, E.; Tecza, W.; Jamróz, M. H.; Dobrowolski, J. C.; Kijénski Mono- di- and tri- tert -butyl ethers of glycerol. A molecular Study Spectrochim. Acta A 2007, 67 (3-4) 980-988
30. Abella, L. C.; Gaspillo, P. A. D.; Maeda, M.; Goto, S. Kinetic Study on the Dehydration of tert -Butyl Alcohol Catalyzed by Ion Exchange Resins Int. J. Chem. Kinet. 1999, 31 (12) 854-859 (Pubitemid 30514764)
31. Silva, V. T. M.; Rodrigues, A. E. Kinetic studies in a batch reactor using ion exchange resin catalysts for oxygenated production: The role of mass transfer mechanisms Chem. Eng. Sci. 2006, 61, 316-331
32. Graça, N.; Pais, L. S.; Silva, V. T. M.; Rodrigues, A. E. Oxygenated biofuels from butanol for diesel blends: Synthesis of the acetal 1,1-dibutoxyethane catalyzed by Amberlyst-15 ion exchange resin Ind. Eng. Chem. Res. 2010, 49, 6763-6771
33. Van Gerpen, J. Biodiesel processing and production Fuel Process. Technol. 2005, 86, 1097-1107
34. Honkela, M. L.; Ouni, T.; Krause, A. O. I. Thermodynamics and Kinetics of the Dehydration of tert -Butyl Alcohol Ind. Eng. Chem. Res. 2004, 43, 4060-4065 (Pubitemid 38943715)