General pathway of sulfur-chain breakage of polythionates by iodine confirmed by the kinetics and mechanism of the pentathionate-iodine reaction

Inorganic Chemistry

Volumn 51, Issue 14, 2012, Pages 7837-7843

  Xu, Li ^a   Csekö, György ^a   Kégl, Tamás ^a   Horváth, Attila K ^a  

^a UNIVERSITY OF PÉCS   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

IODINE; POLYTHIONATES; SULFUR; THIOSULFATE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; KINETICS; PH; TEMPERATURE; TIME;

HYDROGEN-ION CONCENTRATION; IODINE; KINETICS; MOLECULAR STRUCTURE; SULFUR; TEMPERATURE; THIOSULFATES; TIME FACTORS;

EID: 84863886247     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic300895c     Document Type: Article

References (43)

1. Orbán, M.; Kepper, P. D.; Epstein, I. R. J. Phys. Chem. 1982, 86, 431-433
2. Rábai, G.; Beck, M. T.; Kustin, K.; Epstein, I. R. J. Phys. Chem. 1989, 93, 2853-2858
3. Orbán, M.; Epstein, I. R. J. Phys. Chem. 1982, 86, 3907-3910
4. Maselko, J.; Epstein, I. R. J. Chem. Phys. 1984, 80, 3175-3178
5. Orbán, M.; Epstein, I. R. J. Am. Chem. Soc. 1987, 109, 101-106
6. Nagypál, I.; Bazsa, G.; Epstein, I. R. J. Am. Chem. Soc. 1986, 108, 3635-3640
7. Szirovicza, L.; Nagypál, I.; Bárdi, I. Int. J. Chem. Kinet. 1991, 23, 99-101
8. Zhivotniko, V. V.; Koptyug, I. V.; Sagdeev, R. Z. J. Phys. Chem. A 2007, 111, 4122-4124
9. Koptyug, I. V.; Zhivotniko, V. V.; Sagdeev, R. Z. J. Phys. Chem. B 2008, 112, 1170-1176
10. Lu, Y.; Gao, Q.; Xu, L.; Zhao, Y.; Epstein, I. R. Inorg. Chem. 2010, 49, 6026-6034
11. Xu, L.; Horváth, A. K.; Hu, Y.; Ji, C.; Zhao, Y.; Gao, Q. J. Phys. Chem. A 2011, 115, 1853-1860
12. Christiansen, J. A.; Drost-Hansen, W.; Nielsen, A. Acta Chem. Scand. 1952, 6, 333-340
13. Goehring, M.; Heibing, W.; Appel, I. Z. Anorg. Chem. 1947, 254, 185-200
14. Wagner, H.; Schreier, H. Phosphorus Sulfur Relat. Elem. 1978, 4, 281-284
15. Wagner, H.; Schreier, H. Phosphorus Sulfur Relat. Elem. 1978, 4, 285-286
16. Pan, C. W.; Wang, W.; Horváth, A. K.; Xie, J.; Lu, Y.; Wang, Z.; Ji, C.; Gao, Q. Inorg. Chem. 2011, 50, 9670-9677
17. Du, Z.; Gao, Q.; Feng, J.; Lu, Y.; Wang, J. J. Phys. Chem. B 2006, 110, 26098-26104
18. Jeffrey, M. I.; Brunt, S. D. Hydrometallurgy 2007, 89, 52-60
19. Varga, D.; Horváth, A. K.; Nagypál, I. J. Phys. Chem. B 2006, 110, 2467-2470
20. Yuan, L.; Gao, Q.; Zhao, Y.; Tang, X.; Epstein, I. R. J. Phys. Chem. A 2010, 114, 7014-7020
21. Kurin-Csörgei, K.; Orbán, M.; Rábai, G.; Epstein, I. J. Chem. Soc., Faraday Trans. 1996, 92, 2851-2855
22. Rábai, G.; Hanazaki, I. J. Phys. Chem. A 1999, 103, 7268-7273
23. Read, J. F.; Bewick, S. A.; Donaher, S. C.; Ealman, M. D.; Oakey, J.; Schaubel, C.; Tam, N. C.; Theriault, A.; Watson, K. J. Inorg. React. Mech. 2005, 5, 281-304
24. Kerek, A.; Horváth, A. K. J. Phys. Chem. A 2007, 111, 4235-4241
25. Awtrey, A. D.; Connick, R. E. J. Am. Chem. Soc. 1951, 73, 4546-4549
26. Csekö, G.; Horváth, A. K. J. Phys. Chem. A 2010, 114, 6521-6526
27. Kelly, D. P.; Wood, A. P. Methods Enzymol. 1994, 243, 475-501
28. IUPAC Stability Constant Database; Royal Society of Chemistry: London, 1992-1997.
29. Peintler, G. ZiTa, version 5.0; a comprehensive program package for fitting parameters of chemical reaction mechanism; Attila József University: Szeged, Hungary, 1989-1998.
30. Adamo, C.; Barone, V. J. Chem. Phys. 1999, 110, 6158-6170
31. Perdew, J. P.; Burke, K.; Ernzerhof, M. Phys. Rev. Lett. 1996, 77, 3865-3868
32. Rappoport, D.; Furche, F. J. Chem. Phys. 2010, 133, 134105-134115
33. Greenwood, N. N.; Earnshaw, A. Chemistry of the Elements, 2nd ed.; Butterworth-Heinemann: New York, 1997.
34. Tomasi, J.; Persico, M. Chem. Rev. 1994, 94, 2027-2094
35. Granovsky, A. A. Firefly, version 7.1.G, http://classic.chem.msu.su/gran/ firefly/index.html.
36. Reed, A. E.; Curtiss, L. A.; Weinhold, F. Chem. Rev. 1988, 88, 899-926
37. Turner, D. H.; Flynn, G. W.; Sutin, N.; Beitz, J. V. J. Am. Chem. Soc. 1972, 94, 1554-1559
38. Ruasse, M.; Aubard, J.; Galland, B.; Adenier, A. J. Phys. Chem. 1986, 90, 4382-4388
39. Eigen, M.; Kustin, K. J. Am. Chem. Soc. 1962, 84, 1355-1361
40. Lengyel, I.; Epstein, I. R.; Kustin, K. Inorg. Chem. 1993, 32, 5880-5882
41. Lengyel, I.; Li, J.; Kustin, K.; Epstein, I. R. J. Am. Chem. Soc. 1996, 118, 3708-3719
42. Yiin, B. S.; Margerum, D. W. Inorg. Chem. 1990, 29, 1559-1564
43. Fava, A.; Bresadola, S. J. Am. Chem. Soc. 1955, 77, 5792-5794