The characterization of latex particles prepared by pulsed electron beam induced emulsion polymerization

Radiation Physics and Chemistry

Volumn 81, Issue 10, 2012, Pages 1634-1638

  Xu, Yongfei ^a   Wang, Mozhen ^a   Ge, Xuewu ^a  

^a UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA   (China)

Author keywords

Emulsion polymerization; High energy pulsed electron beam; Methyl methacrylate; Porous structure; Styrene

Indexed keywords

ABSORBED DOSE; HIGH ENERGY ELECTRON BEAMS; IRRADIATION TIME; LATEX PARTICLES; LOW MOLECULAR WEIGHT; METHYL METHACRYLATES; MONOMER CONVERSIONS; POLYSTYRENE LATEX PARTICLES; POROUS STRUCTURES; PULSED ELECTRON BEAMS; SEM OBSERVATION;

DYNAMIC LIGHT SCATTERING; ELECTRON BEAMS; ELECTRON SOURCES; EMULSION POLYMERIZATION; ESTERS; GEL PERMEATION CHROMATOGRAPHY; INITIATORS (CHEMICAL); MOLECULAR WEIGHT; POLYSTYRENES; POROSITY; STYRENE;

LATEXES;

LATEX; METHACRYLIC ACID METHYL ESTER; MONOMER; POLY(METHYL METHACRYLATE); POLYSTYRENE; STYRENE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONTROLLED STUDY; ELECTRON BEAM; EMULSION POLYMERIZATION; GAMMA RADIATION; GEL PERMEATION CHROMATOGRAPHY; INTERMETHOD COMPARISON; LIGHT SCATTERING; MOLECULAR WEIGHT; PARTICLE SIZE; POLYMERIZATION; PULSE ELECTRON BEAM; RADIATION ABSORPTION; RADIATION EXPOSURE; SCANNING ELECTRON MICROSCOPY; TRANSMISSION ELECTRON MICROSCOPY;

EID: 84863836897     PISSN: 0969806X     EISSN: 18790895     Source Type: Journal    
DOI: 10.1016/j.radphyschem.2012.05.001     Document Type: Article

References (10)

1. Beuermann S., Buback M., Davis T.P., Gilbert R.G., Hutchinson R.A., Olaj O.F., Russell G.T., Schweer J., van Herk A.M. Critically evaluated rate coefficients for free-radical polymerization, 2. Propagation rate coefficients for methyl methacrylate. Macromol. Chem. Phys. 1997, 198:1545-1560.
2. Botman J.I.M., Derksen A.T.A.M., van Herk A.M., Jung M., Kuchta F.D., Manders L.G., Timmermans C.J., de Voigt M.J.A. A linear accelerator as a tool for investigations into free radical polymerization kinetics and mechanisms by means of pulsed electron beam polymerization. Nucl. Instrum. Methods Phys. Res., Sect. B 1998, 139:490-494.
3. Buback M., Gilbert R.G., Hutchinson R.A., Klumperman B., Kuchta F.-D., Manders B.G., O'Driscoll K.F., Russell G.T., Schweer J. Critically evaluated rate coefficients for free-radical polymerization, 1. Propagation rate coefficient for styrene. Macromol. Chem. Phys. 1995, 196:3267-3280.
4. Eindhoven University of Technology, 2001. Course on Emulsion Polymerisation. Eindhoven.
5. Genkin V.N., Sokolov V.V. Polymerization at periodic pulsed initiation. Dokl. Akad. Nauk SSSR 1977, 234:94-96.
6. Olaj O.F., Bitai I. The laser flash-initiated polymerization as a tool of evaluating (individual) kinetic constants of free radical polymerization, 3. Information from degrees of polymerization. Die Angew. Makromol. Chem. 1987, 155:177-190.
7. Olaj O.F., Bitai I., Hinkelmann F. The laser-flash-initiated polymerization as a tool of evaluating (individual) kinetic constants of free-radical polymerization, 2. The direct determination of the rate of constant of chain propagation. Die Makromol. Chem. 1987, 188:1689-1702.
8. Pusch J., van Herk A.M. Emulsion polymerization of novel transparent latices by pulsed electron beam initiation. Macromolecules 2005, 38:6939-6945.
9. Pusch J., van Herk A.M. Pulsed electron beam initiation in emulsion polymerization. Macromolecules 2005, 38:8694-8700.
10. van Herk A.M., de Brouwer H., Manders B.G., Luthjens L.H., Hom M.L., Hummel A. Pulsed electron beam polymerization of styrene in latex particles. Macromolecules 1996, 29:1027-1030.