Direct synthesis of hydrogen peroxide in a trickle bed reactor: Comparison of Pd-based catalysts

Industrial and Engineering Chemistry Research

Volumn 51, Issue 26, 2012, Pages 8883-8890

  Biasi, Pierdomenico ^a,b   Canu, Paolo ^b   Menegazzo, Federica ^c   Pinna, Francesco ^c   Salmi, Tapio O ^a  

^a ÅBO AKADEMI UNIVERSITY   (Finland)

^b UNIVERSITY OF PADOVA   (Italy)

^c CA' FOSCARI UNIVERSITY OF VENICE   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CONTACT TIME; CONTINUOUS OPERATION; CONTINUOUS REACTORS; DIRECT SYNTHESIS; FIXED BED; GAS AND LIQUID FLOWS; GREEN SYNTHESIS; HYDROGEN PEROXIDE PRODUCTION; LIQUID AND GAS FLOW; MAXIMUM PRODUCTION RATE; OPERATING CONDITION; PALLADIUM CATALYST; PD-BASED CATALYST; PRODUCTION RATES; REACTOR TECHNOLOGY; SEMIBATCH REACTOR; SULFATED ZIRCONIA; TRICKLE BED REACTOR;

BATCH REACTORS; CATALYST SELECTIVITY; CERIUM COMPOUNDS; CHEMICAL PLANTS; FLOW RATE; GASES; HYDROGEN PEROXIDE; SILICA; ZIRCONIA;

LIQUIDS;

EID: 84863514626     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie202128v     Document Type: Conference Paper

References (29)

1. Biasi, P.; Menegazzo, F.; Pinna, F.; Eränen, K.; Canu, P.; Salmi, T. O. Hydrogen Peroxide Direct Synthesis: Selectivity Enhancement in a Trickle Bed Reactor Ind. Eng. Chem. Res. 2010, 49, 10627-10632
2. 2 direct synthesis over PdAu catalysts Chem. Eng. J. 2011, 176-177, 172-177
3. 2 using Au-Pd catalysts Catal. Today 2007, 122, 397-402
4. Melada, S.; Rioda, R.; Menegazzo, F.; Pinna, F.; Strukul, G. Direct synthesis of hydrogen peroxide on zirconia-supported catalysts under mild conditions J. Catal. 2006, 239, 422-430
5. Menegazzo, F.; Burti, P.; Signoretto, M.; Manzoli, M.; Vankova, S.; Boccuzzi, F.; Pinna, F.; Strukul, G. Effect of the Addition of Au in Zirconia and Ceria Supported Pd Catalysts for the Direct Synthesis of Hydrogen Peroxide J. Catal. 2008, 257, 369-381
6. 2 as diluents Green Chem. 2010, 12, 282-289
7. Campos-Martin, J. M.; Blanco-Brieva, G.; Fierro, J. L. G. Hydrogen peroxide synthesis: An outlook beyond the anthraquinone process Angew. Chem., Int. Ed. 2006, 45, 6962-1984
8. Centi, G.; Perathoner, S.; Abate, S. Modern Heterogeneous Oxidation Catalysis: Direct synthesis of hydrogen peroxide: recent advances; Wiley-VCH: Weinheim, Germany, 2009; pp 253-287.
9. Samanta, C. Direct synthesis of hydrogen peroxide from hydrogen and oxygen: An overview of recent developments in the process Appl. Catal., A 2008, 350, 133-149
10. Blanco-Brieva, G.; Capel-Sanchez, M. C.; Pilar, d. F. M.; Padilla-Polo, A.; Campos-Martin, J. M.; Fierro, J. L. G. New Two-Step Process for Propene Oxide Production (HPPO) Based on the Direct Synthesis of Hydrogen Peroxide Ind. Eng. Chem. Res. 2008, 47, 8011-8015
11. 2 and air as diluents J. Supercrit. Fluids 2010, 56, 33-40
12. Burch, R.; Ellis, P. R. An investigation of alternative catalytic approaches for the direct synthesis of hydrogen peroxide from hydrogen and oxygen Appl. Catal., B 2003, 42, 203-211
13. - ions J. Catal. 2011, 280, 239-246
14. - Ions Ind. Eng. Chem. Res. 2011, 50, 4351-4358
15. Edwards, J. K.; Solsona, B.; Ntainjua, N. E.; Carley, A. F.; Herzing, A. A.; Kiely, C. J.; Hutchings, G. J. Switching Off Hydrogen Peroxide Hydrogenation in the Direct Synthesis Process Science 2009, 323, 1037-1041
16. 4/Ethanol System Catal. Lett. 2009, 132, 342-348
17. 2 catalyst for the direct synthesis of hydrogen peroxide Phys. Chem. Chem. Phys. 2010, 12, 2488-2492
18. Pritchard, J.; Kesavan, L.; Piccinini, M.; He, Q.; Tiruvalam, R.; Dimitratos, N.; Lopez-Sanchez, J. A.; Carley, A. F.; Edwards, J. K.; Kiely, C. J.; Hutchings, G. J. Direct synthesis of hydrogen peroxide and benzyl alcohol oxidation using Au-Pd catalysts prepared by sol immobilization Langmuir 2010, 26, 16568-16577
19. 2 coming from direct synthesis. Patent Application, WO2005063619 A2, 2005.
20. Paparatto, G.; Rivetti, F.; Andrigo, P.; De Alberti, G. Process for the continuous production of hydrogen peroxide. U.S. Patent 6,649,140, 2003.
21. Parasher, S.; Rueter, M.; Zhou, B. Nanocatalyst Anchored onto Acid Functionalized Solid Support and Methods of Making and Using. U.S. Patent 7,045,481, 2006.
22. Zhou, B.; Lee, L. K. Catalyst and Process for Hydrogen Peroxide Production. U.S. Patent 6,168,775, 2001.
23. 2-expanded Solvents Prepr.-Am. Chem. Soc., Div. Pet. Chem. 2008, 53, 227-229
24. 2 over Pd/C catalyst in an aqueous medium at high pressure: Detailed kinetic study and modelling J. Supercrit. Fluids 2011, 57, 227-235
25. 2: the role of the catalysts in relation to the kinetic of reaction Top. Catal. 2006, 38, 181-193
26. 2 direct synthesis: Effect of the textural properties of the support on the activity and selectivity J. Catal. 2010, 273, 266-273
27. Ramachandran, P. A.; Chaudhari, R. V. Three-Phase Catalytic Reactors; Gordon and Breach: New York, 1983.
28. 2 Catalyst in Ethanol Appl. Catal., A 2006, 314, 94-100
29. 3H-functionalized mesoporous silica J. Mol. Catal. A: Chem. 2009, 319, 98-107