Toward rational design of amine solutions for PCC applications: The kinetics of the reaction of CO2(aq) with cyclic and secondary amines in aqueous solution

Environmental Science and Technology

Volumn 46, Issue 13, 2012, Pages 7422-7429

  Conway, William ^a   Wang, Xiaoguang ^a,b   Fernandes, Debra ^a   Burns, Robert ^a   Lawrance, Geoffrey ^a   Puxty, Graeme ^c   Maeder, Marcel ^a  

^a UNIVERSITY OF NEWCASTLE   (Australia)

^b NATIONAL INSTITUTE OF CLEAN AND LOW CARBON ENERGY   (China)

^c CSIRO   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

AMINE SOLUTIONS; CARBAMIC ACID; DIETHANOLAMINE; FORMATION RATES; FORMATION REACTION; FORWARD REACTIONS; H NMR SPECTROSCOPY; MORPHOLINES; N-METHYLPIPERAZINE; PROTONATION CONSTANTS; PYRROLIDINES; RATIONAL DESIGN; REVERSIBLE REACTION; SECONDARY AMINES; STOPPED FLOW;

AMINES; EQUILIBRIUM CONSTANTS; KINETICS; ORGANIC ACIDS; PIPE; RATE CONSTANTS;

CARBON DIOXIDE;

AMINE; BICARBONATE; CARBAMIC ACID; CARBON DIOXIDE; DIETHANOLAMINE; MORPHOLINE; PIPERIDINE; PYRROLIDINE DERIVATIVE; THIOMORPHOLINE;

AQUEOUS SOLUTION; CARBAMATE (ESTER); CARBON DIOXIDE; NUCLEAR MAGNETIC RESONANCE; REACTION KINETICS; SPECTROPHOTOMETRY;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL REACTION KINETICS; COMBUSTION; DECOMPOSITION; EQUILIBRIUM CONSTANT; POST COMBUSTION CAPTURE; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT;

AMINES; CARBAMATES; CARBON DIOXIDE; ETHANOLAMINES; KINETICS; SOLUTIONS; SPECTROPHOTOMETRY; WATER;

EID: 84863511497     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es300541t     Document Type: Article

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