Stepwise intramolecular photoisomerization of NHC-chelate dimesitylboron compounds with C-C bond formation and C-H bond insertion

Journal of the American Chemical Society

Volumn 134, Issue 26, 2012, Pages 11026-11034

  Rao, Ying Li ^a   Chen, Leanne D ^a   Mosey, Nicholas J ^a   Wang, Suning ^a  

^a QUEEN S UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BORON ATOM; BORYLENES; C-C BOND FORMATION; C-H BOND; C-H INSERTION; CARBON ATOMS; COMPUTATIONAL STUDIES; HIGH QUANTUM EFFICIENCY; HOMO-LUMO ENERGY GAP; LIGHT-COLORED; MECHANISTIC ASPECTS; N-HETEROCYCLIC CARBENES; SINGLE CRYSTAL X-RAY DIFFRACTION ANALYSIS; TETRAHEDRAL GEOMETRY; THERMALLY STABLE; UV IRRADIATION;

BORON; BORON COMPOUNDS; CHELATION; ORGANIC COMPOUNDS; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS;

ISOMERS;

BORON DERIVATIVE; CARBENE; CARBON; CHELATE; DIMESITYLBORON COMPOUND; HETEROCYCLIC CARBENE; UNCLASSIFIED DRUG;

ARTICLE; ATOM; CHEMICAL BOND; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ENERGY; GEOMETRY; HEATING; HYDROGEN BOND; ISOMER; ISOMERIZATION; NUCLEAR MAGNETIC RESONANCE; PHOTOISOMERIZATION; QUANTITATIVE ANALYSIS; ULTRAVIOLET IRRADIATION; X RAY DIFFRACTION;

EID: 84863505069     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja304211v     Document Type: Article

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