Purification of americium from assorted analytical waste in hydrochloric acid medium

Journal of Radioanalytical and Nuclear Chemistry

Volumn 292, Issue 3, 2012, Pages 1017-1023

  Sengupta, A ^a   Mohapatra, P K ^a   Thulasidas, S K ^a   Godbole, S V ^a   Adya, V C ^a   Manchanda, V K ^b  

^a BHABHA ATOMIC RESEARCH CENTRE   (India)

^b Sungkyunkwan University   (South Korea)

Author keywords

Americium; Analytical waste; CMPO; DHOA; DMDBTDMA; TODGA; TRPO

Indexed keywords

ACTINIDE; AMERICIUM; AMIDE; CALCIUM; HYDROCHLORIC ACID; IRON; LEAD; N,N' DIMETHYL N,N' DIBUTYLTETRADECYLMALONAMIDE; NICKEL; NITRATE; OCTYLPHENYL N,N DIISOBUTYL CARBAMOYLMETHY PHOSPHINE OXIDE; ORGANIC SOLVENT; PHOSPHINE OXIDE DERIVATIVE; SODIUM; UNCLASSIFIED DRUG; DHOA; N,N,N',N' TETRAOCTYLDIGLYCOLAMIDE; NITRIC ACID; OCTYLPHENYL N,N DIISOBUTYLCARBAMOYLMETHYLPHOSPHINEOXIDE; REAGENT; TBP; TRPO;

ACIDITY; AQUEOUS SOLUTION; ARTICLE; COLUMN CHROMATOGRAPHY; ELUTION; INTERMETHOD COMPARISON; PHASE PARTITIONING; PHASE SEPARATION; PURIFICATION; RADIOACTIVE WASTE DISPOSAL; SOLVENT EXTRACTION; SPECTROSCOPY; COMPARATIVE STUDY; ORGANIC CHEMISTRY; WASTE;

EID: 84863461086     PISSN: 02365731     EISSN: 15882780     Source Type: Journal    
DOI: 10.1007/s10967-011-1554-4     Document Type: Article

References (23)

1. Katzz JJ, Seaborg GT, Mross LR (1986) The chemistry of the actinide elements, vol 2, 2nd edn. Chapman and Hall, New York, pp 1188-1190.
2. Knoll GF (2000) Radiation detection and measurements, 3rd edn. John Wiley and Sons Inc, New York.
3. http://www.Epa.Gov/radiation/source-management/final-sealedsource-alts. Pdf
4. Sengupta A, Adya VC, Mohapatra PK, Godbole SV, Manchanda VK (2010) Separation and purification of americium from analytical waste solutions. J Radioanal Nucl Chem 283:777-783.
5. Mathur JN, Murali MS, Natarajan PR, Badheka LP, Banerji A, Micheal KM, Kapoor SC, Dhuwad RK (1992) Tail end purification of americium from plutonium loading effluents using a mixture of octyl (phenyl)-N,N-diisobutyl carbamoyl phosphine oxide and tri-N-butyl phosphate. J Radioanal Nucl Chem 165(4):219-227.
6. Schulte LD, FitzPatrick JF, Salazar RR, Schake BS, Martinez BT (1995) Clean-up of hydrochloric acid waste streams from actinide processing using extraction chromatography. Sep Sci Technol 30(7-9):1833-1847.
7. Micheal KM, Kapoor SC, Mathur JN, Iyer RH (1996) Purification of americium from bulk quantities of plutonium loading effluent using triauryl amine. J Radioanal Nucl Chem 213:431-439.
8. Muscatello AC, Navratil JD (1988) Americium removal from nitric acid waste streams. J. Radioanal. Nucl. Chem.lett. 128:449-462.
9. Michel H, Barci-Funel G, Dalmasso J, Ardisson G (1999) One step ion exchange process for radiochemical separation of americium plutonium and neptunium in sediments. J Radioanal Nucl Chem 240:467-470. (Pubitemid 29232280)
10. Michel H, Levent D, Barci V, Barci-Funel G, Hurel C (2008) Soil and sediment sample analysis for determination of natural and anthropogenic radionuclides. Talanta 74:1527-1533.
11. Tavcar P, Jakopic R, Benedik L (2005) Sequential determination of 241Am, 237Np, Pu radioisotopes and 90Sr in soil and sediment samples. Acta Chim solv 52:60-66. (Pubitemid 40544220)
12. Moreno J, Vajda N, Danesi PR, Larosa JJ, Zeiller E, Sinojmery M (1997) Combined procedure for the determination of 90Sr, 241Am and Pu radionuclides in soil samples. J Radioanal Nucl Chem 226:279-284.
13. Wang JJ, Chen IJ, Chiu JH (2004) Sequential isotopic determination of plutonium, thorium, americium, strontium and uranium in environmental and bio assay samples. Appl Radiat Isotop 61:299-305.
14. Lee YK, Bakhtiar SN, Akbarzadeh M, Lee JS (2000) Sequential isotopic determination of strontium thorium, plutonium, pranium and americium in bioassay samples. J Radioanal Nucl Chem 243:525-533. (Pubitemid 30459002)
15. Adya VC, Sengupta A, Dhawale BA, Rajeswari B, Thulasida SK, Godbole SV (2011) Recovery of americium from analytical solid waste containing large amounts of uranium, plutonium and silver. J Radioanal Nucl Chem 11:44. doi:10.1007/s10967-011-1360-z.
16. Vajda N, Chang-Kyu Kim (2010) Determination of 241Am isotope: a review of analytical methodology. J Radioanal Nucl Chem 284:341-366.
17. Sengupta A, Adya V, Acharya R, Mohapatra P, Manchanda V (2011) J Radioanal Nucl Chem 267:281-285. doi:10.1007/s10967-010-0675-5.
18. Ansari SN, Pathak PN, Husain M, Prasad AK, Parmar VS, Manchanda VK (2005) N,N,N0,N0 tetraoctyl diglycolamide (TODGA): a promising extractant for actinide partitioning from high level waste (HLW). Solv Extr Ion Exch 23:463-479.
19. Gupta KK, Manchanda VK, Subramanian MS, Singh RK (2000) Solvent extraction studies on U (VI), Pu(IV) and fission products using N,N dihexyl octanamide. Solv Extr Ion Exch 18:273-286.
20. Schulz WW, Horwitz EP (1988) TRUEX process and management of liquid TRU waste. Sep Sci Technol 23:1191-1210.
21. Mahajan GR, Prabhu DR, Manchanda VK, Badheka LP (1998) Substituted malonamides as extractants for partitioning of actinides from nuclear waste solutions. Waste Manage 18:125-133. (Pubitemid 28492209)
22. Nair GM, Prabhu DR, Mahajan GR, Shukla JP (1993) Tetra-butyl and tetra-isobutyl malonamides as extractants for U(VI) and Pu(IV). Solv Extr Ion Exch 11:831-847.
23. Mathur JN, Murali MS, Natarajan PR, Badheka LP, Banerji A, Ramanujam A, Dhami PS, Gopalakrishnan V, Dhumwad RK, Rao MK (1993) Partitioning of actinides from high-level waste streams of PUREX process using mixtures of CMPO and TBP in dodecane Waste Manage 13:317-325