Pervaporation of ethanol/water mixtures using clinoptilolite and 4A filled sodium alginate membranes

Desalination

Volumn 300, Issue , 2012, Pages 24-31

  Nigiz, Filiz Ugur ^a   Dogan, Hacer ^b   Hilmioglu, Nilufer Durmaz ^a  

^a KOCAELI UNIVERSITY   (Turkey)

^b MATERIALS INSTITUTE   (Turkey)

Author keywords

Clinoptilolite; Pervaporation; Sodium alginate; Zeolite 4A

Indexed keywords

CLINOPTILOLITES; ETHANOL WATER MIXTURES; FEED COMPOSITIONS; FEED MIXTURE; FLUX AND SELECTIVITY; GLUTARALDEHYDES; MEMBRANE MATRIX; MODIFIED MEMBRANES; NATURAL ZEOLITES; PERFORMANCE VALUE; PV PERFORMANCE; SEPARATION PROPERTY; SODIUM ALGINATE MEMBRANE; SODIUM ALGINATES; SOLUTION-CASTING METHOD; SYNTHETIC ZEOLITES; WATER CONCENTRATIONS; ZEOLITE 4A; ZEOLITE LOADING; ZEOLITE PARTICLES;

ALDEHYDES; ETHANOL; EVAPORATION; LOADING; MIXTURES; PERVAPORATION; SCANNING ELECTRON MICROSCOPY; ZEOLITES;

MEMBRANES;

ALGINATE; CLINOPTILOLITE; DESALINATION; ETHANOL; MEMBRANE; PARTICLE SIZE; PERFORMANCE ASSESSMENT; SCANNING ELECTRON MICROSCOPY; VAPORIZATION; ZEOLITE;

EID: 84863454149     PISSN: 00119164     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.desal.2012.05.036     Document Type: Article

References (42)

1. Vane L.M. A review of pervaporation for product recovery from biomass fermentation processes. J. Chem. Technol. Biotechnol. 2008, 80:603-629.
2. Vane L.M. Separation technologies for the recovery and dehydration alcohols from fermentation broths. Biofuels, Bioprod. Biorefin. 2008, 2:553-588.
3. Hua Jiang H., Shri R., Tschirner U.W., Ramarao B.V. A review of separation technologies in current and future biorefineries. Sep. Purif. Technol. 2008, 62:1-21.
4. Sun Y., Cheng J. Hydrolysis of lignocellulosic materials for ethanol production:a review 2001, Department of Biological an Agricultural Engineering, North Carolina State University, Raleigh, USA.
5. Santosh K., Neetu S., Ram P. Anhydrous ethanol: a renewable source of energy. Renewable Sustain. Energy Rev. 2010, 14:1830-1844.
6. Asli I., Serpil S., Gulum S. Recovery of strawberry aroma compounds by pervaporation. J. Food Eng. 2006, 75:36-42.
7. Pereira J.R.M., Rufino A.C., Habert R., Nobrega L.M.C., Cabral C.P., Borges C.C. Aroma compounds recovery of tropical fruit juice by pervaporation:membrane material selection and process evaluation. J. Food Eng. 2005, 66:77-87.
8. Tatiana G.L., Ying S.H., Luisa F.S. Comparative study of commercially available polymeric and microporous silica membranes for the dehydration of IPA/water mixtures by pervaporation/vapour permeation. Desalination 2002, 149:3-8.
9. Yuexin Z., Shanshan X., Gongping L., Wanqin J. Preparation of ceramic-supported poly(vinyl alcohol)-chitosan composite membranes and their applications in pervaporation dehydration of organic/water mixtures. J. Membr. Sci. 2010, 349:341-348.
10. Jiding L., Cuixian C., Binbing H., Yong P., Jian Z., Weijun J. Laboratory and pilot-scale study on dehydration of benzene by pervaporation. J. Membr. Sci. 2002, 203:127-136.
11. Peter D.C., Teresa O., Andrew G.L., Li K. Membranes for the dehydration of solvents by pervaporation. J. Membr. Sci. 2008, 318:5-37.
12. Mulder M. Basic Principles of Membrane Technology 1996, Kluwer Academic Press, AA Dordrecht.
13. Kalyani S., Smith B., Sridhar S., Krishnaiah A. Pervaporation separation of ethanol-water mixtures through sodium alginate membranes. Desalination 2008, 229:68-81.
14. Uragami T., Saito M. Studies on syntheses and permeabilities of special polymer membranes 68. Analysis of permeation and separation characteristics and new technique for separation of aqueous alcoholic solutions through alginic acid membranes. Sep. Sci. Technol. 1989, 24:541-554.
15. Mochizuki A., Amiya S., Sato Y., Ogawara H., Yamashita S. Pervaporation separation of water/ethanol mixtures through polysaccharide membranes, IV. The relationships between the permselectivity of alginic acid membrane and its solid-state structure. J. Appl. Polym. Sci. 1990, 40:385-400.
16. Yeom C.K., Lee K.H. Characterization of sodium alginate membrane cross-linked with glutaraldehyde in pervaporation separation. J. Appl. Polym. Sci. 1998, 67:209-219.
17. Yeom C.K., Lee K.H. Characterization of permeation behaviors of ethanol-water mixtures through sodium alginate membrane with cross-linking gradient during pervaporation separation. J. Appl. Polym. Sci. 1998, 69:1607-1619.
18. Chovou S., Dobrak A., Figoli A., Galiano A., Simona S., Diroli E., Sikdar S.K., Brugen B.V. Pervaporation performance of unfilled and filled PDMS membranes and novel SBS membranes for the removal of toluene from diluted aqueous solutions. Chem. Eng. J. 2010, 139:37-46.
19. Shi Y., Wang X., Chen G. Pervaporation characteristics and solution diffusion behaviors through sodium alginate dense membrane. J. Appl. Polym. Sci. 1996, 61:1387-1394.
20. Yeom C.K., Jecaland J.C., Lee K.H. Characterization of relaxation phenomena and permeation behaviors in sodium alginate membrane during pervaporation separation of ethanol-water mixture. J. Appl. Polym. Sci. 1996, 62:1561-1576.
21. Shi Y., Wang X., Chen G., Olemme G., Zhang S., Drioli E. Preparation and characterization of high-performance dehydrating pervaporation alginate membranes. J. Appl. Polym. Sci. 1998, 68:959-968.
22. Naidu B.V.K., Bhat S.D., Sairam M., Wali A.C., Sawant D.P., Halligudi S.B., Mallikarjuna N.N., Aminabhavi T.M. Comparison of the pervaporation separation of a water-acetonitrile mixture with zeolite-filled sodium alginate and poly(vinyl alcohol)-polyaniline semi-interpenetrating polymer network membranes. J. Appl. Polym. Sci. 2005, 96:1968-1978.
23. Bhat S.D., Naidu B.V.K., Shanbhag G.V., Halligudi S.B., Sairamand M., Aminabhavi T.M. Mesoporous molecular sieve (MCM-41)-filled sodium alginate hybrid nanocomposite membranes for pervaporation separation of water-isopropanol mixtures. Sep. Purif. Technol. 2006, 49:56-63.
24. Rehm B.H.A. Alginates: Biology and Applications 2009, 1-55. Springer Verlag Berlin.
25. Bhat S.D., Aminabhavi T.M. Novel sodium alginate composite membranes incorporated with SBA-15 molecular sieves for the pervaporation dehydration of aqueous mixtures of isopropanol and 1,4-dioxane at 30 C. Microporous Mesoporous Mater. 2006, 91:206-214.
26. Bhat S.D., Aminabhavi T.M. Novel sodium alginate-NaMMT hybrid composite membranes for pervaporation dehydration of isopropanol, 1,4-dioxane and tetrahydrofuran. Sep. Purif. Technol. 2006, 51:85-94.
27. Bhat S.D., Mallikarjuna N.N., Aminabhavi T.M. Microporous alumino-phosphate (AlPO4-5) molecular sieve-loaded novel sodium alginate composite membranes for pervaporation dehydration of aqueous-organic mixtures near their azeotropic compositions. J. Membr. Sci. 2006, 282:473-483.
28. Bhat S.D., Aminabhavi T.M. Pervaporation-aided dehydration and esterification of acetic acid with ethanol using 4a zeolite-filled cross-linked sodium alginate-mixed matrix membranes. J. Appl. Polym. Sci. 2009, 113:157-168.
29. Swayampakula K., Biduri S., Sundergopal S., Abburi K. Pervaporation separation of ethanol-water mixtures through sodium alginate membranes. Desalination 2008, 229:68-81.
30. Gang L., Eiichi K., Masahiko M. ZSM-5 zeolite membranes prepared from a clear template-free solution. Microporous Mesoporous Mater. 2003, 60:225-235.
31. Qiao X., Chung T.S., Rajagopalan R. Zeolite filled P84 co-polyimide membranes for dehydration of isopropanol through pervaporation process. Chem. Eng. Sci. 2006, 61:6816-6825.
32. Dogan H., Hilmioglu N.D. Chitosan coated zeolite filled regenerated cellulose membrane for dehydration of ethylene glycol/water mixtures by pervaporation. Desalination 2010, 258:120-127.
33. Kariduraganavar M.Y., Kittur A.A., Kulkarni S.S., Ramesh K. Development of novel pervaporation membranes for the separation of water-isopropanol mixtures using sodium alginate and NaY zeolite. J. Membr. Sci. 2004, 238:165-175.
34. Vane L.M., Namboodiri V.V., Meier R.G. Factors affecting alcohol-water pervaporation performance of hydrophobic zeolite-silicone rubber mixed matrix membranes. J. Membr. Sci. 2010, 364:102-110.
35. Nunes Susana Pereira, Peinemann Klaus-Viktor Membrane Technology in the Chemical Industry 2006, 2.
36. Szostak R. Molecular Sieves - Principles of Synthesis and Identification 1989, Van Nostrand Reinhold, New York. 1st edition.
37. Tai-Shung C., Lan Y.J., Yi L., Santi K. Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation. Prog. Polym. Sci. 2007, 32:483-507.
38. Shah D., Kissick K., Ghorpade A., Hannahb R., Bhattacharyya D. Pervaporation of alcohol-water and dimethylformamide-water mixtures using hydrophilic zeolite NaA membranes: mechanisms and experimental results. J. Membr. Sci. 2000, 179:185-205.
39. R. Mahajan, Formation, characterization and modeling of mixed matrix membrane materials, PhD thesis, Univeristy of Texas at Austin, 2000.
40. Li Y., Krantz W.B., Chung T.S. A novel primer to prevent nanoparticle agglomeration in mixed matrix membranes. AIChE J. 2007, 53:2470-2475.
41. Adoor S.G., Manjeshwar S.L., Bhat S.D., Aminabhavi T.M. Aluminum-rich zeolite beta incorporated sodium alginate mixed matrix membranes for pervaporation dehydration and esterification of ethanol and acetic acid. J. Membr. Sci. 2008, 318:233-246.
42. Bhat S.D., Aminabhavi T.M. Pervaporation separation using sodium alginate and its modified membranes-a review. Sep. Purif. Rev. 2007, 36:203-229.