Tuning the surface structure and optical properties of CdSe clusters using coordination chemistry

Journal of Physical Chemistry Letters

Volumn 2, Issue 24, 2011, Pages 3075-3080

  Cossairt, Brandi M ^a   Juhas, Pavol ^b   Billinge, Simon J L ^b,c   Owen, Jonathan S ^a  

^a Och Spine at New York Presbyterian Hospitals   (United States)

^b Columbia University ^*  (United States)

^c BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

Nanoparticles and Nanostructures

Indexed keywords

CDSE; COORDINATION CHEMISTRY; CORE CHANGES; DIPHENYLPHOSPHINE; ELECTRONIC ABSORPTION; ENERGY TRANSFER PROCESS; LIGAND EXCHANGES; LUMINESCENCE SPECTRUM; MOLECULAR WEIGHT ANALYSIS; NONSTOICHIOMETRIC; PAIR DISTRIBUTION FUNCTION ANALYSIS; PHOTOLUMINESCENCE EXCITATION SPECTRUM; SELENIDES; THIOLATES; TRANSFER MECHANISMS; X-RAY DIFFRACTION DATA;

CADMIUM; CADMIUM ALLOYS; ENERGY TRANSFER; EXCITED STATES; LIGANDS; LIGHT EMISSION; NAPHTHALENE; OPTICAL PROPERTIES; PHOSPHORESCENCE; X RAY DIFFRACTION;

CADMIUM COMPOUNDS;

EID: 84863311521     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz2013769     Document Type: Article

References (35)

1. Jiang, Z. J.; Kelley, D. F. Role of Magic-Sized Clusters in the Synthesis of CdSe Nanorods. ACS Nano 2010, 4 (3), 1561-1572.
2. Yu, K.; Hu, M. Z.; Wang, R.; Le Piolet, M.; Frotey, M.; Zaman, B.; Wu, X.; Leek, D. M.; Tao, Y.; Wilkinson, D.; et al. Thermodynamic Equilibrium-Driven Formation of Single-Sized Nanocrystals: Reaction Media Tuning CdSe Magic-Sized versus Regular Quantum Dots. J. Phys. Chem. C 2010, 114, 3329-3339.
3. Kudera, S.; Zanella, M.; Giannini, C.; Rizzo, A.; Li, Y.; Gigli, G.; Cingolani, R.; Ciccarella, G.; Spahl, W.; Parak, W. J.; et al. Sequential Growth of Magic-Size CdSe Nanocrystals. Adv. Mater. 2007, 19, 548-552.
4. Bowers, M. J. I.; McBride, J. R.; Rosenthal, S. J. White-Light Emission from Magic-Sized Cadmium Selenide Nanocrystals. J. Am. Chem. Soc. 2005, 127, 15378-15379.
5. Chen, H. S.; Kumar, R. V. Discontinuous Growth of Colloidal CdSe Nanocrystals in the Magic Structure. J. Phys. Chem. C 2009, 113, 31-36.
6. Dai, Q.; Li, D.; Chang, J.; Song, Y.; Kan, S.; Chen, H.; Zou, B.; Xu, W.; Xu, S.; Liu, B.; et al. Facile Synthesis of Magic-Sized CdSe and CdTe Nanocrystals with Tunable Existence Periods. Nanotechnology 2007, 18, 405603-7.
7. Dukes, A. D. I.; McBride, J. R.; Rosenthal, S. J. Synthesis of Magic-Sized CdSe and CdTe Nanocrystals with Diisooctylphosphinic Acid. Chem. Mater. 2010, 2010 (22), 6402-6408.
8. Ouyang, J.; Zaman, B.; Yan, F. J.; Johnston, D.; Li, G.; Wu, X.; Leek, D.; Ratcliffe, C. I.; Ripmeester, J. A.; Yu, K. Multiple Families of Magic-Sized CdSe Nanocrystals with Strong Bandgap Photoluminescence via Noninjection One-Pot Syntheses. J. Phys. Chem. C 2008, 112, 13805-13811.
9. Cossairt, B. M.; Owen, J. S. CdSe Clusters: At the Interface Between Small Molecules and Quantum Dots. Chem. Mater. 2011, 23, 3114-3119.
10. Kasuya, A.; Sivamohan, R.; Barnakov, Y. A.; Dmitruk, I. M.; Nirasawa, T.; Romanyuk, V. R.; Kumar, V.; Mamykin, S. V.; Tohji, K.; Jeyadevan, B.; et al. Ultra-Stable Nanoparticles of CdSe Revealed from Mass Spectrometry. Nat. Mater. 2004, 3, 99-102.
11. McBride, J. R.; Dukes, A. D. I.; Schreuder, M. A.; Rosenthal, S. J. On Ultrasmall Nanocrystals. Chem. Phys. Lett. 2010, 498, 1-9.
12. Liu, Y.-H.; Wang, F.; Wang, Y.; Gibbons, P. C.; Buhro, W. E. Lamellar Assembly of Cadmium Selenide Nanoclusters into Quantum Belts. J. Am. Chem. Soc. 2011, 133 (42), 17005-17013.
13. Bowers, M. J. I.; McBride, J. R.; Garrett, M. D.; Sammons, J. A.; Dukes, A. D. I.; Schreuder, M. A.; Watt, T. L.; Lupini, A. R.; Pennycook, S. J.; Rosenthal, S. J. Structure and Ultrafast Dynamics of White-Light-Emitting CdSe Nanocrystals. J. Am. Chem. Soc. 2009, 131, 5730-5731.
14. Chestnoy, N.; Harris, T. D.; Hull, R.; Brus, L. E. Luminescence and Photophysics of CdS Semiconductor Clusters. J. Phys. Chem. 1986, 90, 3393-3399.
15. van Dijken, A.; Meulenkamp, E. A.; Vanmaekelbergh, D.; Meijerink, A. The Kinetics of the Radiative and Nonradiative Processes in Nanocrystalline ZnO Particles upon Photoexcitation. J. Phys. Chem. B 2000, 104, 1715-1723.
16. Dukes, A. D. I.; Schreuder, M. A.; Sammons, J. A.; McBride, J. R.; Smith, N. J.; Rosenthal, S. J. Pinned Emission from Ultrasmall Cadmium Selenide Nanocrystals. J. Chem. Phys. 2008, 129, 121102-4.
17. Schreuder, M. A.; Xiao, K.; Ivanov, I. N.; Weiss, S. M.; Rosenthal, S. J. White Light-Emitting Diodes Based on Ultrasmall CdSe Nanocrystal Electroluminescence. Nano Lett. 2010, 10 (2), 573-576.
18. Guild, J. The Colorimetric Properties of the Spectrum. Philos. Trans. R. Soc. London, A 1931, 230, 149-187.
19. Nirmal, M.; Murray, C. B.; Bawendi, M. G. Fluorescence-Line Narrowing in CdSe Quantum Dots: Surface Localization of the Photogenerated Exciton. Phys. Rev. B 1994, 50 (4), 2293-2300.
20. Bawendi, M. G.; Steigerwald, M. L.; Brus, L. E. The Quantum Mechanics of Larger Semiconductor Clusters. Annu. Rev. Phys. Chem. 1990, 41, 447-496.
21. Hochstrasser, R. M. The Luminescence of Complex Molecules in Relation to the Internal Conversion of Excitation Energy. Can. J. Chem. 1961, 39, 1776-1782.
22. Rogach, A. L. Fluorescence Energy Transfer in Hybrid Structures of Semiconductor Nanocrystals. Nano Today 2011, 6 (4), 355-365.
23. Jiang, G.; Susha, A. S.; Lutich, A. A.; Stefani, F. D.; Feldman, J.; Rogach, A. L. Cascaded FRET in Conjugated Polymer/Quantum Dot/Dye-Labeled DNA Complexes for DNA Hybridization Detection. ACS Nano 2009, 3 (12), 4127-4131.
24. Kowerko, D.; Schuster, J.; Amecke, N.; Abdel-Mottaleb, M.; Dobrawa, R.; Wurthner, F.; von Borczyskowski, C. FRET and Ligand-Related Non-FRET Processes in Single Quantum Dot-Perylene Bisimide Assemblies. Phys. Chem. Chem. Phys. 2010, 12, 4112-4123.
25. Lakowicz, J. R. Principles of Fluorescence Spectroscopy, 3rd ed.; Springer: New York, 2006; p 980.
26. Speiser, S. Photophysics and Mechanisms of Intramolecular Electronic Energy Transfer in Bichromophoric Molecular Systems. Chem. Rev. 1996, 96, 1953-1976.
27. Dexter, D. L. A Theory of Sensitized Luminescence in Solids. J. Chem. Phys. 1953, 21, 836-850.
28. Underwood, D. F.; Kippeny, T.; Rosenthal, S. J. Ultrafast Carrier Dynamics in CdSe Nanocrystals Determined by Femtosecond Fluorescence Upconversion Spectroscopy. J. Phys. Chem. B 2001, 105, 436-443.
29. Jackson, G.; Porter, G. Acidity Constants in the Triplet State. Proc. R. Soc. London A 1961, 260 (1300), 13-30.
30. Frederick, M. T.; Weiss, E. A. Relaxation of Exciton Confinement in CdSe Quantum Dots by Modification with a Conjugated Dithiocarbamate Ligand. ACS Nano 2010, 4 (6), 3195-3200.
31. Masadeh, A. S.; Bozin, E. S.; Farrow, C. L.; Paglia, G.; Juhas, P.; Billinge, S. J. L. Quantitative Size and Strain Determination of CdSe Nanoparticles using Atomic Pair Distribution Function Analysis. Phys. Rev. B 2007, 76, 115413-1-11.
32. Chen, O.; Yang, Y.; Wu, H.; Niu, C.; Yang, J.; Cao, Y. C. Surface-Functionalization-Dependent Optical Properties of II-VI Semiconductor Nanocrystals. J. Am. Chem. Soc. 2011, 133 (43), 17504-17512.
33. Jasieniak, J.; Smith, L.; van Embden, J.; Mulvaney, P. Re-examination of the Size-Dependent Absorption Properties of CdSe Quantum Dots. J. Phys. Chem. C 2009, 113, 19468-19474.
34. Leatherdale, C. A.; Woo, W. K.; Mikulec, F. V.; Bawendi, M. G. On the Absorption Cross Section of CdSe Nanocrystal Quantum Dots. J. Phys. Chem. B 2002, 106, 7619-7622.
35. Yu, W. W.; Qu, L.; Guo, W.; Peng, X. Experimental Determination of the Extinction Coefficient of CdTe, CdSe, and CdS Nanocrystals. Chem. Mater. 2003, 15, 2854-2860.