Ansa-rare-earth-metal catalysts for rapid and stereoselective polymerization of renewable methylene methylbutyrolactones

Chemistry - A European Journal

Volumn 18, Issue 11, 2012, Pages 3345-3354

  Hu, Yangjian ^a   Miyake, Garret M ^a   Wang, Baoli ^b   Cui, Dongmei ^b   Chen, Eugene Y X ^a  

^a Department of Environmental and Radiological Health Sciences   (United States)

^b CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

Author keywords

homogeneous catalysis; polymerization; rare earth metals; renewable feedstock; stereoregular polymers

Indexed keywords

ACTIVE CATALYST; BUTYROLACTONES; CATALYST LOADINGS; CATALYTIC POLYMERIZATION; COORDINATION POLYMERIZATION; DIALKYL COMPLEXES; ETHYLENE-BRIDGED; FLUORENYL; HIGH-T; HOMOGENEOUS CATALYSIS; KINETIC STUDY; METHYL METHACRYLATES; MONOMER CONVERSIONS; N-HETEROCYCLIC CARBENE LIGANDS; PENTAMETHYLCYCLOPENTADIENYL; PROPAGATION MECHANISM; RARE-EARTH METALS; RATE ENHANCEMENT; RENEWABLE FEEDSTOCKS; ROOM TEMPERATURE; SHARP CONTRAST; STEREO-REGULAR POLYMER; STEREOREGULAR; STEREOSELECTIVE POLYMERIZATION; TURNOVER FREQUENCY; UNIMOLECULAR;

ACRYLIC MONOMERS; CATALYSTS; COMPLEXATION; DIMETHYLFORMAMIDE; ESTERS; ETHYLENE; LIGANDS; MONOMERS; ORGANIC SOLVENTS; POLYMERIZATION; REACTION KINETICS;

COPOLYMERIZATION;

EID: 84863230029     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201102677     Document Type: Article

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