Organic oxalate as leachant and precipitant for the recovery of valuable metals from spent lithium-ion batteries

Waste Management

Volumn 32, Issue 8, 2012, Pages 1575-1582

  Sun, Liang ^a   Qiu, Keqiang ^a  

^a CENTRAL SOUTH UNIVERSITY   (China)

Author keywords

Leaching; Lithium ion battery; Oxalate; Precipitation; Valuable metals

Indexed keywords

ENVIRONMENTALLY COMPATIBLE; HYDROMETALLURGICAL PROCESS; LEACHANTS; LITHIUM-ION BATTERY; OXALATE; REACTION EFFICIENCY; SECONDARY RESOURCES; SOLID/LIQUID RATIOS; SPENT LITHIUM-ION BATTERIES; STRATEGIC RESOURCE; VACUUM PYROLYSIS;

COBALT; COBALT COMPOUNDS; ELECTROCHEMICAL CELLS; LEACHING; LITHIUM; LITHIUM BATTERIES; PRECIPITATION (CHEMICAL);

METAL RECOVERY;

COBALT; LITHIUM; LITHIUM ION; OXALIC ACID; OXYGEN;

COBALT; LEACHATE; LEACHING; LITHIUM; METALLURGY; OXALATE; PRECIPITATION (CHEMISTRY); PYROLYSIS;

AIR POLLUTION; ARTICLE; BINDING AFFINITY; CHEMICAL BINDING; CHEMICAL COMPOSITION; CONCENTRATION (PARAMETERS); CRYSTALLIZATION; DECOMPOSITION; DISSOLUTION; LEACHING; METAL RECOVERY; METALLURGY; POLLUTION TRANSPORT; PRECIPITATION; PRIORITY JOURNAL; PROCESS TECHNOLOGY; PYROLYSIS; REACTION TIME; SEPARATION TECHNIQUE; TEMPERATURE SENSITIVITY;

CHEMICAL PRECIPITATION; COBALT; ELECTRODES; ELECTRONIC WASTE; HYDROGEN PEROXIDE; LITHIUM; OXALATES; RECYCLING; TEMPERATURE; VACUUM;

EID: 84863207137     PISSN: 0956053X     EISSN: 18792456     Source Type: Journal    
DOI: 10.1016/j.wasman.2012.03.027     Document Type: Article

References (40)

1. 4) nanoparticles from submicrometer rods of cobalt oxalate. J. Colloid Interface Sci. 2008, 321:434-441.
2. Castillo S., Ansart F., Laberty-Robert C., Portal J. Advances in the recovering of spent lithium battery compounds. J. Power Sources 2002, 112:247-254.
3. Chen L., Tang X.C., Zhang Y., Li L.X., Zeng Z.W. Process for the recovery of cobalt oxalate from spent lithium-ion batteries. Hydrometallurgy 2011, 108:80-86.
4. Contestabile M., Panero S., Scrosati B. A laboratory-scale lithium-ion battery recycling process. J. Power Sources 2001, 92:65-69.
5. Dorella G., Mansur M.B. A study of the separation of cobalt from spent Li-ion battery residues. J. Power Sources 2007, 170:210-215.
6. Espinosa D.C.R., Bernardes A.M., Tenorio J.A.S. An overview on the current processes for the recycling of batteries. J. Power Sources 2004, 135:311-319.
7. Ferreira D.A., Prados L.M.Z., Majuste D., Mansur M.B. Hydrometallurgical separation of aluminium, cobalt, copper and lithium from spent Li-ion batteries. J. Power Sources 2009, 187:238-246.
8. 2 from spent lithium-ion batteries. J. Anal. Appl. Pyrol. 2007, 78:65-69.
9. Freitas M.B.J.G., Garcia E.M. Electrochemical recycling of cobalt from cathodes of spent lithium-ion batteries. J. Power Sources 2007, 171:953-959.
10. Freitas M.B.J.G., Celante V.G., Pietre M.K. Electrochemical recovery of cobalt and copper from spent Li-ion batteries as multilayer deposits. J. Power Sources 2010, 195:3309-3315.
11. Garcia E.M., Santos J.S., Pereira E.C., Freitas M.B.J.G. Electrodeposition of cobalt from spent Li-ion battery cathodes by the electrochemistry quartz crystal microbalance technique. J. Power Sources 2008, 185:549-553.
12. Kang J., Senanayake G., Sohn J., Shin S.M. Recovery of cobalt sulfate from spent lithium ion batteries by reductive leaching and solvent extraction with Cyanex 272. Hydrometallurgy 2010, 100:168-171.
13. Kang J., Sohn J., Chang H., Senanayake G., Shin S.M. Preparation of cobalt oxide from concentrated cathode material of spent lithium ion batteries by hydrometallurgical method. Adv. Powder Technol. 2010, 21:175-179.
14. Kirsch T., Maurer G. Distribution of oxalic acid between water and organic solutions of Tri-n-octylamine. Ind. Eng. Chem. Res. 1996, 35:1722-1735.
15. 2 from spent lithium-ion batteries. J. Power Sources 2002, 109:17-21.
16. Lee C.K., Rhee K.I. Reductive leaching of cathodic active materials from lithium ion battery wastes. Hydrometallurgy 2003, 68:5-10.
17. Li J.H., Shi P.X., Wang Z.F., Chen Y., Chang C.C. A combined recovery process of metals in spent lithium-ion batteries. Chemosphere 2009, 77:1132-1136.
18. Li L., Ge J., Chen R., Wu F., Chen S., Zhang X. Environmental friendly leaching reagent for cobalt and lithium recovery from spent lithium-ion batteries. Waste Manag. 2010, 30:2615-2621.
19. Li L., Ge J., Wu F., Chen R.J., Chen S., Wu B.R. Recovery of cobalt and lithium from spent lithium ion batteries using organic citric acid as leachant. J. Hazard. Mater. 2010, 176:288-293.
20. 2 films from spent lithium-ion batteries by a combined recycling process. Hydrometallurgy 2011, 108:220-225.
21. 2 from incisors bound of Li-ion batteries. Trans. Nonfer. Met. Soc. China 2006, 16:956-959.
22. Lupi C., Pasquali M., Dell'Era A. Nickel and cobalt recycling from lithium-ion batteries by electrochemical processes. Waste Manag. 2005, 25:215-220.
23. Majumdar S., Sharma I.G., Bidaye A.C., Suri A.K. A study on isothermal kinetics of thermal decomposition of cobalt oxalate to cobalt. Thermochim. Acta. 2008, 473:45-49.
24. Mantuano D.P., Dorella G., Elias R.C.A., Mansur M.B. Analysis of a hydrometallurgical route to recover base metals from spent rechargeable batteries by liquid-liquid extraction with Cyanex 272. J. Power Sources 2006, 159:1510-1518.
25. Mishra D., Kim D.J., Ralph D.E., Ahn J.G., Rhee Y.H. Bioleaching of metals from spent lithium ion secondary batteries using Acidithiobacillus ferrooxidans. Waste Manag. 2008, 28:333-338.
26. 2 by electrochemical-hydrothermal method. J. Power Sources 2002, 112:639-642.
27. Nan J.M., Han D.M., Zuo X.X. Recovery of metal values from spent lithium-ion batteries with chemical deposition and solvent extraction. J. Power Sources 2005, 152:278-284.
28. Paulino J.F., Busnardo N.G., Afonso J.C. Recovery of valuable elements from spent Li-batteries. J. Hazard. Mater. 2008, 150:843-849.
29. Provazi K., Campos B.A., Espinosa D.C.R., Tenorio J.A.S. Metal separation from mixed types of batteries using selective precipitation and liquid-liquid extraction techniques. Waste Manag. 2011, 31:59-64.
30. Shin S.M., Kim N.H., Sohn J.S., Yang D.H., Kim Y.H. Development of a metal recovery process from Li-ion battery wastes. Hydrometallurgy 2005, 79:172-181.
31. Sun L., Qiu K. Vacuum pyrolysis and hydrometallurgical process for the recovery of valuable metals from spent lithium-ion batteries. J. Hazard. Mater. 2011, 194:378-384.
32. Swain B., Jeong J., Lee J.C., Lee G.H. Separation of cobalt and lithium from mixed sulphate solution using Na-Cyanex 272. Hydrometallurgy 2006, 84:130-138.
33. Swain B., Jeong J., Lee J.C., Lee G.H., Sohn J.S. Hydrometallurgical process for recovery of cobalt from waste cathodic active material generated during manufacturing of lithium ion batteries. J. Power Sources 2007, 167:536-544.
34. Swain B., Jeong J., Lee J.C., Lee G.H. Development of process flow sheet for recovery of high pure cobalt from sulfate leach liquor of LIB industry waste: a mathematical model correlation to predict optimum operational conditions. Sep. Purif. Technol. 2008, 63:360-369.
35. Tian Q.H., Li Z.H., Guo X.Y. Selective extraction of oxalic acid from cobalt mother-liquor with complexing agent P350. J. Cent. South Univ. (Science and Technology) 2009, 40:884-890.
36. Vassura I., Morselli L., Bernardi E., Passarini F. Chemical characterisation of spent rechargeable batteries. Waste Manag. 2009, 29:2332-2335.
37. Wang R.C., Lin Y.C., Wu S.H. A novel recovery process of metal values from the cathode active materials of the lithium-ion secondary batteries. Hydrometallurgy 2009, 99:194-201.
38. Xin B.P., Zhang D., Zhang X., Xia Y.T., Wu F., Chen S., Li L. Bioleaching mechanism of Co and Li from spent lithium-ion battery by the mixed culture of acidophilic sulfur-oxidizing and iron-oxidizing bacteria. Bioresour. Technol. 2009, 100:6163-6169.
39. Xu J.Q., Thomas H.R., Francis R.W., Lum K.R., Wang J.W., Liang B. A review of processes and technologies for the recycling of lithium-ion secondary batteries. J. Power Sources 2008, 177:512-527.
40. Zhang P., Yokoyama T., Itabashi O., Suzuki T.M., Inoue K. Hydrometallurgical process for recovery of metal values from spent lithium-ion secondary batteries. Hydrometallurgy 1998, 47:259-271.