Kinetic and thermodynamic studies on the removal of Zn2+ and Ni2+ from their aqueous solution using poly(phenylthiourea)imine

Chemical Engineering Journal

Volumn 197, Issue , 2012, Pages 368-378

  Murugesan, A ^a   Vidhyadevi, T ^a   Kalaivani, S S ^a   Premkumar, M P ^a   Ravikumar, L ^b   Sivanesan, S ^a  

^a ANNA UNIVERSITY   (India)

^b CBM College   (India)

Author keywords

Desorption; Isotherm; Kinetic; Poly(phenylthiourea)imine (PPTUI); Selectivity

Indexed keywords

ADSORBENT DOSE; ADSORPTION CAPACITIES; ADSORPTION EFFICIENCY; ADSORPTION PARAMETERS; BATCH ADSORPTION; COMPETITIVE ADSORPTION; CONTACT TIME; FOUR CYCLES; FREUNDLICH; LANGMUIR ISOTHERM MODELS; METAL ION CONCENTRATION; PHENYLTHIOUREA; PSEUDO-SECOND-ORDER KINETIC MODELS; TEXTURAL CHARACTERISTIC; THERMODYNAMIC PARAMETER; THERMODYNAMIC STUDIES;

ADSORBENTS; ADSORPTION; ADSORPTION ISOTHERMS; CATALYST SELECTIVITY; CHEMICAL ANALYSIS; DESORPTION; DYES; ISOTHERMS; KINETICS; METAL IONS; NITROGEN COMPOUNDS; POLYCONDENSATION; SOLUTIONS; THIOUREAS;

ZINC;

EID: 84863204225     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2012.05.027     Document Type: Article

References (55)

1. Moraci N., Calabro Paolo S. Heavy metals removal and hydraulic performance in zero-valent iron/pumice permeable reactive barriers. J. Environ. Manage. 2010, 91:2336-2341.
2. Sthiannopkao S., Sreesai S. Utilization of pulp and paper industrial wastes to remove heavy metals from metal finishing wastewater. J. Environ. Manage. 2009, 90:3283-3289.
3. Basu T., Ghosh U.C. Influence of groundwater occurring ions on the kinetics of As(III) adsorption reaction with synthetic nanostructured Fe(III)-Cr(III) mixed oxide. Desalination 2011, 266:25-32.
4. Zhang Y., Shan X., Gao X. Development of a molecularly imprinted membrane for selective separation of flavonoids. Sep. Purif. Technol. 2011, 76:337-344.
5. Kuo S., Bembenek R. Sorption and desorption of chromate by wood shavings impregnated with iron or aluminum oxide. Bioresour. Technol. 2008, 99:5617-5625.
6. Singh L.P., Bhatnagar J.M., Tanaka S., Tsue H., Mori M. Selective anion recognition: charged diaza crown ethers based electrochemical sensors for chromate ions. Anal. Chim. Acta 2005, 546:199-205.
7. Stewart D.I., Burke I.T., Hughes-Berry D.V., Whittleston R.A. Microbially mediated chromate reduction in soil contaminated by highly alkaline leachate from chromium containing waste. Ecol. Eng. 2010, 36:211-221.
8. Bayrakci{dotless} M., Ertul S., Yilmaz M. Synthesis of di-substituted calix[4]arene-based receptors for extraction of chromate and arsenate anions. Tetrahedron 2009, 65:7963-7968.
9. Ahmad M.A., Rahman N.K. Equilibrium, kinetics and thermodynamic of Remazol Brilliant Orange 3R dye adsorption on coffee husk-based activated carbon. Chem. Eng. J. 2011, 170:154-161.
10. Konovalova V.V., Dmytrenko G.M., Nigmatullin R.R., Bryk M.T., Gvozdyak P.I. Chromium(VI) reduction in a membrane bioreactor with immobilized Pseudomonas cells. Enzyme Microb. Technol. 2003, 33:899-907.
11. Li W., Yue Q., Tu P., Ma Z., Gao B., Li J., Xu X. Adsorption characteristics of dyes in columns of activated carbon prepared from paper mill sewage sludge. Chem. Eng. J. 2011, 178:197-203.
12. 2+ ions onto chestnut shell. Desalination 2009, 249:855-860.
13. Vazquez-Morillas A., Vaca-Mier M., Alvarez P.J. Biological activation of hydrous ferric oxide for reduction of hexavalent chromium in the presence of different anions. Eur. J. Soil Biol. 2006, 42:99-106.
14. Igwe J.C., Abia A.A., Ibeh C.A. Adsorption kinetics and intraparticulate diffusivities of Hg, As and Pb ions on unmodified and thiolated coconut fiber. Int. J. Environ. Sci. Technol. 2008, 5:83-92.
15. 2+ ions from water using polyacrylamide grafted rice (Oryza sativa) husk and (Tectona grandis) saw dust. J. Hazard. Mater. 2009, 163:1338-1344.
16. Azizian S., Haerifar M., Bashiri H. Adsorption of methyl violet onto granular activated carbon: equilibrium, kinetics and modeling. Chem. Eng. J. 2009, 146:36-41.
17. Nuhoglu Y., Oguz E. Removal of copper(II) from aqueous solutions by biosorption on the cone biomass of Thuja orientalis. Process Biochem. 2003, 38:1627-1631.
18. Mukhopadhyay M., Noronha S.B., Suraishkumar G.K. Kinetic modeling for the biosorption of copper by pretreated Aspergillus niger biomass. Bioresour. Technol. 2007, 98:1781-1787.
19. SenthilKumar P., Ramalingam S., Sathyaselvabala V., Dinesh Kirupha S., Sivanesan S. Removal of copper(II) ions from aqueous solution by adsorption using cashew nut shell. Desalination 2011, 266:63-71.
20. Aksu Z., Isoglu I.A. Removal of copper(II) ions from aqueous solution by biosorption onto agricultural waste sugar beet pulp. Process Biochem. 2005, 40:3031-3044.
21. Murugesan A., Ravikumar L., SathyaSelvaBala V., SenthilKumar P., Vidhyadevi T., Dinesh Kirupha S., Kalaivani S.S., Krithiga S., Sivanesan S. Removal of Pb(II), Cu(II) and Cd(II) ions from aqueous solution using polyazomethineamides: equilibrium and kinetic approach. Desalination 2011, 271:199-208.
22. Long C., Li Y., Yu W., Li A. Adsorption characteristics of water vapor on the hypercrosslinked polymeric adsorbent. Chem. Eng. J. 2012, 180:106-112.
23. Wua F., Tsengb R., Juangc R. Characteristics of Elovich equation used for the analysis of adsorption kinetics in dye-chitosan systems. Chem. Eng. J. 2009, 150:366-373.
24. Jing X.S., Liu F.Q., Yang X., Ling P., Li L.J., Long C., Li A.M. Adsorption performances and mechanisms of the newly synthesized N, N-di(carboxymethyl) dithiocarbamate chelating resin toward divalent heavy metal ions from aqueous media. J. Hazard. Mater. 2009, 167:589-596.
25. Abdullaha M.A., Chiangb L., Nadeema M. Comparative evaluation of adsorption kinetics and isotherms of a natural product removal by Amberlite polymeric adsorbents. Chem. Eng. J. 2009, 146:370-376.
26. Misra R.K., Jain S.K., Khatri P.K. Iminodiacetic acid functionalized cation exchange resin for adsorptive removal of Cr(VI), Cd(II), Ni(II) and Pb(II) from their aqueous solutions. J. Hazard. Mater. 2011, 185:1508-1512.
27. Saha D., Zacharia R., Lafi L., Cossement D., Chahine R. Synthesis, characterization and hydrogen adsorption on metal-organic frameworks Al, Cr, Fe and Ga-BTB. Chem. Eng. J. 2011, 171:517-525.
28. Vazquez G., Calvo M., Freire M.S., Gonzalez-Alvarez J., Antorrena G. Chestnut shell as heavy metal adsorbent: optimization study of lead, copper and zinc cations removal. J. Hazard. Mater. 2009, 172:1402-1414.
29. Shukla S.R., Pai R.S. Adsorption of Cu(II), Ni(II) and Zn(II) on modified jute fibres. Bioresour. Technol. 2005, 96:1430-1438.
30. Rahmana M.S., Islamb M.R. Effects of pH on isotherms modeling for Cu(II) ions adsorption using maple wood sawdust. Chem. Eng. J. 2009, 149:273-280.
31. Sawalha M.F., Peralta-Videa J.R., Duarte-Gardea M., Gardea-Torresdey J.L. Removal of copper, lead, and zinc from contaminated water by saltbush biomass: analysis of the optimum binding, stripping, and binding mechanism. Bioresour. Technol. 2008, 99:4438-4444.
32. Alyuz B., Veli S. Kinetics and equilibrium studies for the removal of nickel and zinc from aqueous solutions by ion exchange resins. J. Hazard. Mater. 2009, 167:482-488.
33. Kausar A., Zulfiqar S., Ahmad Z., Sarwar M.I. Facile synthesis and properties of a new generation of soluble and thermally stable polyimides. Polym. Degrad. Stab. 2010, 95:2603-2610.
34. Chen J., Liu Y., Ju J., Chiang C., Chern Y. Synthesis, characterization and hydrolysis of aromatic polyazomethines containing non-coplanar biphenyl structures. Polymer 2011, 52:954-964.
35. Yildirim M., Kaya I. Synthesis and characterization of a novel kind soluble, conjugated, and fluorescent chelate polymer containing fluorene ring in the backbone: optical, electrical, and electrochemical properties. Synth. Met. 2011, 161:13-22.
36. Niu H., Luo P., Zhang M., Zhang L., Hao L., Luo J., Bai X., Wang W. Multifunctional, photochromic, acidichromic, electrochromic molecular switch: novel aromatic poly(azomehine)s containing triphenylamine Group. Eur. Polym. J. 2009, 45:3058-3071.
37. Ravikumar L., Kalaivani S.S., Murugesan A., Vidhyadevi T., Karthik G., Dinesh Kirupha S., Sivanesan S. Synthesis, characterization, and heavy metal ion adsorption studies of polyamides, polythioamides having pendent chlorobenzylidine rings. J. Appl. Polym. Sci. 2011, 122:1634-1642.
38. Ravikumar L., Pradeep I., Thangaiyan T., Mohan R., Balachandran J. Synthesis, characterization, and conducting properties of poly(thioureaazomethines). Int. J. Polym. Mater. 2012, 61:288-299.
39. Vasanthi B., Ravikumar L. Synthesis and characterization of new poly(azomethine ester)s having phenylthiourea units. Eur. Polym. J. 2007, 43:4325-4331.
40. Lagergren S. About the theory of so-called adsorption of soluble substances. Kungliga Sven. Vetensk Handl. 1898, 24:1-39.
41. Ho Y.S., McKay G. Pseudo-second order model for sorption processes. Process Biochem. 1999, 34:451-465.
42. Ho Y.S., McKay G. Application of kinetic models to the sorption of copper(II) onto peat. Adsorpt. Sci. Technol. 2002, 20:797-815.
43. Weber W.J., Morris J.C. Kinetics of adsorption on carbon from solution. J. Sanit. Eng. Div. Am. Soc. Civ. Eng. 1963, 89:31-60.
44. Langmuir I. The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc. 1918, 40:1361-1403.
45. Freundlich H.M.F. Over the adsorption in solution. J. Phys. Chem. 1906, 57:385-470.
46. Redlich O., Peterson D.L. A useful adsorption isotherm. J. Phys. Chem. 1959, 63:1024.
47. Sips R. Combined form of Langmuir and Freundlich equations. J. Chem. Phys. 1948, 16:490-495.
48. Nie R., Chang X., He Q., Hu Z., Li Z. Preparation of p-tert[(dimethylamino)methyl]-calix[4]arene functionalized aminopropolysiloxane resin for selective solid-phase extraction and preconcentration of metal ions. J. Hazard. Mater. 2009, 169:203-209.
49. Ajmal M., Rao R.A.K., Ahmad R., Ahmad J. Adsorption studies on citrus reticulate (fruit peel of orange) removal and recovery of Ni(II) from electroplating wastewater. J. Hazard. Mater. 1999, 69:263-268.
50. Zouboulis A.I., Kydros K.A. Use of red mud for toxic metal removal the case of nickel. J. Chem. Technol. Biotechnol. 1993, 58:95-101.
51. Vengris T., Binkiene R., Sveikauskaite A. Nickel, copper, and zinc removal from wastewater by a modified clay sorbent. Appl. Clay Sci. 2001, 18:183-190.
52. El-Hag Ali A., Shawky H.A., El-Sayed M.H., Ibrahim H. Radiation synthesis of functionalized polypropylene fibers and their application in the treatment of some water resources in western desert of Egypt. Sep. Purif. Technol. 2008, 63:69-76.
53. Shukla S.R., Pai Roshan S., Shendharkar A.D. Adsorption of Ni(II), Zn(II) and Fe(II) on modified coir fibers. Sep. Purif. Technol. 2006, 47:141-147.
54. Chuber N., Carvalho J.R., Correia M.J.N. Cork biomass as biosorbent for Cu(II), Zn(II) and Ni(II). Colloids Surf. A: Physicochem. Eng. Aspects 2003, 230:57-65.
55. Shukla S.R., Pai R.S. Adsorption of Cu(II), Ni(II) and Zn(II) on dye loaded groundnut shells and sawdust. Sep. Purif. Technol. 2005, 43:1-8.