메뉴 건너뛰기




Volumn 51, Issue 3, 2012, Pages 1158-1165

Reaction kinetics and mechanism of iron(II)-induced catalytic oxidation of sulfur(IV) during wet desulfurization

Author keywords

[No Author keywords available]

Indexed keywords

CONCENTRATION RANGES; IRON CONCENTRATIONS; KINETICS AND MECHANISM; NEGATIVE INFLUENCE; OXIDATION REACTIONS; RADICAL MECHANISM; REACTION ORDERS; SIMPLIFIED MODELS; WET DESULFURIZATION;

EID: 84863070701     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie2014372     Document Type: Article
Times cited : (50)

References (47)
  • 1
    • 0009703578 scopus 로고
    • Kinetics of the Manganese(III)-Sulfur(IV) Reaction in Aqueous Perchloric Acid Solutions
    • Siskos, P. A.; Peterson, N. C.; Huie, R. E. Kinetics of the Manganese(III)-Sulfur(IV) Reaction in Aqueous Perchloric Acid Solutions Inorg. Chem. 1984, 23, 1134
    • (1984) Inorg. Chem. , vol.23 , pp. 1134
    • Siskos, P.A.1    Peterson, N.C.2    Huie, R.E.3
  • 2
    • 0000801823 scopus 로고
    • Kinetics and Mechanism of the Iiron(III)-Catalyzed Autoxidation of Sulfur(IV) Oxides in Aqueous Solution. 2. Decomposition of Transient Iron(III)-Sulfur(IV) Complexes
    • Kraft, J.; van Eldik, R. Kinetics and Mechanism of the Iiron(III)-Catalyzed Autoxidation of Sulfur(IV) Oxides in Aqueous Solution. 2. Decomposition of Transient Iron(III)-Sulfur(IV) Complexes Inorg. Chem. 1989, 28, 2306
    • (1989) Inorg. Chem. , vol.28 , pp. 2306
    • Kraft, J.1    Van Eldik, R.2
  • 3
    • 0000583633 scopus 로고
    • Transition Metal-Catalyzed Oxidation of Sulfur(IV) Oxides. Atmospheric-Relevant Processes and Mechanisms
    • Brandt, C.; van Eldik, R. Transition Metal-Catalyzed Oxidation of Sulfur(IV) Oxides. Atmospheric-Relevant Processes and Mechanisms Chem. Rev. 1995, 95, 119
    • (1995) Chem. Rev. , vol.95 , pp. 119
    • Brandt, C.1    Van Eldik, R.2
  • 4
    • 0033734777 scopus 로고    scopus 로고
    • 2 in Acidic Media: Part I. Kinetics and Mechanism
    • 2 in Acidic Media: Part I. Kinetics and Mechanism Hydrometallurgy 2000, 55, 229
    • (2000) Hydrometallurgy , vol.55 , pp. 229
    • Zhang, W.1    Singh, P.2    Muir, D.3
  • 5
    • 33751386047 scopus 로고
    • Kinetics and Mechanism for Manganese-Catalyzed Oxidation of Sulfur(IV) by Oxygen in Aqueous Solution
    • Berglund, J.; Fronaeus, S.; Elding, L. I. Kinetics and Mechanism for Manganese-Catalyzed Oxidation of Sulfur(IV) by Oxygen in Aqueous Solution Inorg. Chem. 1993, 32, 4527
    • (1993) Inorg. Chem. , vol.32 , pp. 4527
    • Berglund, J.1    Fronaeus, S.2    Elding, L.I.3
  • 6
    • 0000921166 scopus 로고
    • Kinetics and Mechanism of the Iron(III)-Catalyzed Autoxidation of Sulfur(IV) Oxides in Aqueous Solution. Evidence for the Redox Cycling of Iron in the Presence of Oxygen and Modeling of the Overall Reaction Mechanism
    • Brandt, C.; Fábián, I.; van Eldik, R. Kinetics and Mechanism of the Iron(III)-Catalyzed Autoxidation of Sulfur(IV) Oxides in Aqueous Solution. Evidence for the Redox Cycling of Iron in the Presence of Oxygen and Modeling of the Overall Reaction Mechanism Inorg. Chem. 1994, 33, 687
    • (1994) Inorg. Chem. , vol.33 , pp. 687
    • Brandt, C.1    Fábián, I.2    Van Eldik, R.3
  • 8
    • 0028160878 scopus 로고
    • Iron-Catalysed Oxidation of Bisulphite Aqueous Solution: Evidence for a Free Radical Chain Mechanism
    • Ziajka, J.; Beer, F.; Warneck, P. Iron-Catalysed Oxidation of Bisulphite Aqueous Solution: Evidence for a Free Radical Chain Mechanism Atmos. Environ. 1994, 28, 2549
    • (1994) Atmos. Environ. , vol.28 , pp. 2549
    • Ziajka, J.1    Beer, F.2    Warneck, P.3
  • 9
    • 33847244258 scopus 로고    scopus 로고
    • Kinetics and Mechanism of the Iron(III)-Catalyzed Autoxidation of Sulfur(IV) Oxides in Aqueous Solution. The Influence of pH, Medium and Aging
    • Brandt, C.; van Eldik, R. Kinetics and Mechanism of the Iron(III)-Catalyzed Autoxidation of Sulfur(IV) Oxides in Aqueous Solution. The Influence of pH, Medium and Aging Transition Met. Chem. (Dordrecht, Neth.) 1998, 23, 667
    • (1998) Transition Met. Chem. (Dordrecht, Neth.) , vol.23 , pp. 667
    • Brandt, C.1    Van Eldik, R.2
  • 10
    • 33845554435 scopus 로고
    • Oxidation of Aqueous Sulfur Dioxide. 2. High-Pressure Studies and Proposed Reaction Mechanisms
    • Huss, A.; Lim, P. K.; Eckert, C. A. Oxidation of Aqueous Sulfur Dioxide. 2. High-Pressure Studies and Proposed Reaction Mechanisms J. Phys. Chem. 1982, 86, 4229
    • (1982) J. Phys. Chem. , vol.86 , pp. 4229
    • Huss, A.1    Lim, P.K.2    Eckert, C.A.3
  • 11
    • 0001066355 scopus 로고    scopus 로고
    • 2. 2. The Manganese(II)-Catalyzed Reaction
    • 2. 2. The Manganese(II)-Catalyzed Reaction Inorg. Chem. 1996, 35, 4613
    • (1996) Inorg. Chem. , vol.35 , pp. 4613
    • Connick, R.E.1    Zhang, Y.X.2
  • 12
    • 33746397151 scopus 로고    scopus 로고
    • Influence of Atmospheric Carboxylic Acids on Catalytic Oxidation of Sulfur(IV)
    • Podkrajsek, B.; Grgić, I.; Tursic, J.; Bercic', G. Influence of Atmospheric Carboxylic Acids on Catalytic Oxidation of Sulfur(IV) J. Atmos. Chem. 2006, 54, 103
    • (2006) J. Atmos. Chem. , vol.54 , pp. 103
    • Podkrajsek, B.1    Grgić, I.2    Tursic, J.3    Bercic, G.4
  • 13
    • 19944372437 scopus 로고    scopus 로고
    • Effects of Monochromatic UV-Visible Light and Sunlight on Fe(III)-Catalyzed Oxidation of Dissolved Sulfur Dioxide
    • Zuo, Y. G.; Zhan, J.; Wu, T. X. Effects of Monochromatic UV-Visible Light and Sunlight on Fe(III)-Catalyzed Oxidation of Dissolved Sulfur Dioxide J. Atmos. Chem. 2005, 50, 195
    • (2005) J. Atmos. Chem. , vol.50 , pp. 195
    • Zuo, Y.G.1    Zhan, J.2    Wu, T.X.3
  • 14
    • 67650119466 scopus 로고    scopus 로고
    • Kinetics of Ammonia and Ammonium Ion Inhibition of the Atmospheric Oxidation of Aqueous Sulfur Dioxide by Oxygen
    • Mudgal, P. K.; Sharm, A. K.; Mishra, C. D.; Bansal, S. P.; Gupta, K. S. Kinetics of Ammonia and Ammonium Ion Inhibition of the Atmospheric Oxidation of Aqueous Sulfur Dioxide by Oxygen J. Atmos. Chem. 2009, 61, 31
    • (2009) J. Atmos. Chem. , vol.61 , pp. 31
    • Mudgal, P.K.1    Sharm, A.K.2    Mishra, C.D.3    Bansal, S.P.4    Gupta, K.S.5
  • 15
    • 49349139984 scopus 로고
    • Homogeneous Kinetics of Potassium Sulfite Oxidation
    • Mishra, G. C.; Srivastava, R. D. Homogeneous Kinetics of Potassium Sulfite Oxidation Chem. Eng. Sci. 1976, 31, 969
    • (1976) Chem. Eng. Sci. , vol.31 , pp. 969
    • Mishra, G.C.1    Srivastava, R.D.2
  • 16
    • 0011295543 scopus 로고
    • Some Aspects of the Homogeneous Kinetics of Sulfite Oxidation
    • Chen, T. I.; Barron, C. H. Some Aspects of the Homogeneous Kinetics of Sulfite Oxidation Ind. Eng. Chem. Fundam. 1972, 11, 466
    • (1972) Ind. Eng. Chem. Fundam. , vol.11 , pp. 466
    • Chen, T.I.1    Barron, C.H.2
  • 19
    • 40949122757 scopus 로고    scopus 로고
    • 2 Removal by Cast Iron Scraps in a Magnetically Fixed Bed
    • 2 Removal by Cast Iron Scraps in a Magnetically Fixed Bed J. Hazard. Mater. 2008, 153, 508
    • (2008) J. Hazard. Mater. , vol.153 , pp. 508
    • Jiang, J.H.1    Li, Y.H.2    Cai, W.M.3
  • 20
    • 45449119133 scopus 로고    scopus 로고
    • Catalytic Oxidation of S(IV) in the Flue Gas Desulfurization Process Using Magnetically Fluidized Bed
    • Zhang, Q.; Gui, K. T.; Yao, G. H. Catalytic Oxidation of S(IV) in the Flue Gas Desulfurization Process Using Magnetically Fluidized Bed J. Eng. Thermophys. 2008, 29, 987
    • (2008) J. Eng. Thermophys. , vol.29 , pp. 987
    • Zhang, Q.1    Gui, K.T.2    Yao, G.H.3
  • 23
    • 84863043884 scopus 로고    scopus 로고
    • General Administration of Quality Supervision; Inspection and Quarantine of the People's Republic of China; Standardization Administration of the People's Republic of China. Water Treatment Chemicals-Poly Ferric Sulfate (GB 14591-2006)
    • Standards Press of China: Beijing
    • General Administration of Quality Supervision; Inspection and Quarantine of the People's Republic of China; Standardization Administration of the People's Republic of China. Water Treatment Chemicals-Poly Ferric Sulfate (GB 14591-2006). National Standard of the People's Republic of China; Standards Press of China: Beijing, 2006.
    • (2006) National Standard of the People's Republic of China
  • 25
    • 0021481342 scopus 로고
    • The Oxidation of Fe(II) Sulfate with Sulfur and Oxygen Mixtures
    • Sato, T.; Goto, T.; Okabe, T.; Lawson, F. The Oxidation of Fe(II) Sulfate with Sulfur and Oxygen Mixtures Bull. Chem. Soc. Jpn. 1984, 57, 2082
    • (1984) Bull. Chem. Soc. Jpn. , vol.57 , pp. 2082
    • Sato, T.1    Goto, T.2    Okabe, T.3    Lawson, F.4
  • 27
    • 0025872967 scopus 로고
    • Aqueous S(IV) Oxidation-I. Catalytic Effects of Some Metal Ion
    • Grgić, I.; Hudnik, V.; Bizjak, M.; Levec, J. Aqueous S(IV) Oxidation-I. Catalytic Effects of Some Metal Ion Atmos. Environ. 1991, 25A, 1591
    • (1991) Atmos. Environ. , vol.25 , pp. 1591
    • Grgić, I.1    Hudnik, V.2    Bizjak, M.3    Levec, J.4
  • 30
    • 0016572034 scopus 로고
    • Kinetics of Oxidation of Ammonium Sulfite by Rapid-Mixing Method
    • Mishra, G. C.; Srivastava, R. D. Kinetics of Oxidation of Ammonium Sulfite by Rapid-Mixing Method Chem. Eng. Sci. 1975, 30, 1387
    • (1975) Chem. Eng. Sci. , vol.30 , pp. 1387
    • Mishra, G.C.1    Srivastava, R.D.2
  • 31
    • 0019697726 scopus 로고
    • Chemical Engineering Use of Catalyzed Sulfite Oxidation Kinetics for the Determination of Mass Transfer Characteristics of Gas-Liquid Contactors
    • Linek, V.; Vacek, V. Chemical Engineering Use of Catalyzed Sulfite Oxidation Kinetics for the Determination of Mass Transfer Characteristics of Gas-Liquid Contactors Chem. Eng. Sci. 1981, 36, 1747
    • (1981) Chem. Eng. Sci. , vol.36 , pp. 1747
    • Linek, V.1    Vacek, V.2
  • 32
    • 0021282752 scopus 로고
    • Manganese(II) Catalyzed Sulfur Dioxide Oxidation in Aqueous Solution at Environmental Concentrations
    • Ibusuki, T.; Barnes, H. M. Manganese(II) Catalyzed Sulfur Dioxide Oxidation in Aqueous Solution at Environmental Concentrations Atmos. Environ. 1984, 18, 145
    • (1984) Atmos. Environ. , vol.18 , pp. 145
    • Ibusuki, T.1    Barnes, H.M.2
  • 34
    • 0001151022 scopus 로고
    • Reaction Kinetics of Sodium Sulfite Oxidation by the Rapid-Mixing Method
    • Barron, C. H.; O'Hern, H. A. Reaction Kinetics of Sodium Sulfite Oxidation by the Rapid-Mixing Method Chem. Eng. Sci. 1966, 21, 397
    • (1966) Chem. Eng. Sci. , vol.21 , pp. 397
    • Barron, C.H.1    O'Hern, H.A.2
  • 35
    • 0026597247 scopus 로고
    • Kinetics and Mechanism of the Sulfite-Induced Autoxidation of Fe(II) in Acidic Aqueous Solution
    • Bal Reddy, K.; van Eldik, R. Kinetics and Mechanism of the Sulfite-Induced Autoxidation of Fe(II) in Acidic Aqueous Solution Atmos. Environ. 1992, 26A, 661
    • (1992) Atmos. Environ. , vol.26 , pp. 661
    • Bal Reddy, K.1    Van Eldik, R.2
  • 36
    • 3543007732 scopus 로고    scopus 로고
    • Calcium Bisulfite Oxidation in the Flue Gas Desulfurization Process Catalyzed by Iron and Manganese Ions
    • Karatza, D.; Prisciandaro, M.; Lancia, A.; Musmarra, D. Calcium Bisulfite Oxidation in the Flue Gas Desulfurization Process Catalyzed by Iron and Manganese Ions Ind. Eng. Chem. Res. 2004, 43, 4876
    • (2004) Ind. Eng. Chem. Res. , vol.43 , pp. 4876
    • Karatza, D.1    Prisciandaro, M.2    Lancia, A.3    Musmarra, D.4
  • 39
    • 0023500446 scopus 로고
    • Sulfur Dioxide Oxidation by Oxygen Catalyzed by Mixtures of Manganese(II) and Iron(III) in Aqueous Solutions at Environmental Reaction Conditions
    • Ibusuki, T.; Takeuchi, K. Sulfur Dioxide Oxidation by Oxygen Catalyzed by Mixtures of Manganese(II) and Iron(III) in Aqueous Solutions at Environmental Reaction Conditions Atmos. Environ. 1987, 21, 1555
    • (1987) Atmos. Environ. , vol.21 , pp. 1555
    • Ibusuki, T.1    Takeuchi, K.2
  • 40
    • 45849105082 scopus 로고
    • Recovery of Sulfur Dioxide as Dilute Sulfuric Acid -Catalytic Oxidation in Water Solution
    • Copson, R. L.; Payne, J. W. Recovery of Sulfur Dioxide as Dilute Sulfuric Acid -Catalytic Oxidation in Water Solution Ind. Eng. Chem. 1933, 25, 909
    • (1933) Ind. Eng. Chem. , vol.25 , pp. 909
    • Copson, R.L.1    Payne, J.W.2
  • 42
    • 0027518975 scopus 로고
    • Electrolyte Effects on Aqueous Atmospheric Oxidation of Sulphur Dioxide by Hydrogen Peroxide
    • Lagrange, J.; Pallares, C.; Wenger, G.; Lagrange, P. Electrolyte Effects on Aqueous Atmospheric Oxidation of Sulphur Dioxide by Hydrogen Peroxide Atmos. Environ. 1993, 27A, 129
    • (1993) Atmos. Environ. , vol.27 , pp. 129
    • Lagrange, J.1    Pallares, C.2    Wenger, G.3    Lagrange, P.4
  • 43
    • 33845553871 scopus 로고
    • Oxidation of Aqueous Sulfur Dioxide. 1. Homogeneous Manganese(II) and Iron(II) Catalysis at Low pH
    • Huss, A.; Lim, P. K.; Eckert, C. A. Oxidation of Aqueous Sulfur Dioxide. 1. Homogeneous Manganese(II) and Iron(II) Catalysis at Low pH J. Phys. Chem. 1982, 86, 4224
    • (1982) J. Phys. Chem. , vol.86 , pp. 4224
    • Huss, A.1    Lim, P.K.2    Eckert, C.A.3
  • 44
    • 49949136554 scopus 로고
    • The Iron Catalyzed Oxidation of Sulfur: Reconciliation of the Literature Rates
    • Martin, L. R.; Hill, M. W. The Iron Catalyzed Oxidation of Sulfur: Reconciliation of the Literature Rates Atmos. Environ. 1987, 21, 1487
    • (1987) Atmos. Environ. , vol.21 , pp. 1487
    • Martin, L.R.1    Hill, M.W.2
  • 45
    • 0001734755 scopus 로고
    • Effect of Ionic Strength and Ionic Interactions on the Oxidation of Fe(II)
    • Millero, F. J.; Izaguirre, M. Effect of Ionic Strength and Ionic Interactions on the Oxidation of Fe(II) J. Solution Chem. 1989, 18, 585
    • (1989) J. Solution Chem. , vol.18 , pp. 585
    • Millero, F.J.1    Izaguirre, M.2
  • 46
    • 71749114684 scopus 로고    scopus 로고
    • Studies on Salt Effect to the Saponification Reaction Rate Constant of Ethyl Acetate. Acta Univ
    • Gu, G. Y.; Han, S. J. Studies on Salt Effect to the Saponification Reaction Rate Constant of Ethyl Acetate. Acta Univ Acta Univ. Med. Secondae Shanghai 1997, 17, 67
    • (1997) Acta Univ. Med. Secondae Shanghai , vol.17 , pp. 67
    • Gu, G.Y.1    Han, S.J.2
  • 47
    • 0024792211 scopus 로고
    • The Possible Role of Iron(III)-Sulfur(IV) Complexes in the Catalyzed Autoxidation of Sulfur(IV)-Oxides. A Mechanistic Investigation
    • Kraft, J.; van Eldik, R. The Possible Role of Iron(III)-Sulfur(IV) Complexes in the Catalyzed Autoxidation of Sulfur(IV)-Oxides. A Mechanistic Investigation Atmos. Environ. 1989, 23, 2709
    • (1989) Atmos. Environ. , vol.23 , pp. 2709
    • Kraft, J.1    Van Eldik, R.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.