Crystal structure, physical properties, and electrochemistry of copper substituted LiFePO 4 single crystals

Chemistry of Materials

Volumn 24, Issue 1, 2012, Pages 166-173

  Upreti, Shailesh ^a,f   Chernova, Natasha A ^a   Xiao, Jie ^a,g   Miller, Joel K ^a,h   Yakubovich, Olga V ^b   Cabana, Jordi ^c,i   Grey, Clare P ^c,j   Chevrier, Vincent L ^d,k   Ceder, Gerbrand ^d   Musfeldt, Janice L ^e   Whittingham, M Stanley ^a  

^a BINGHAMTON UNIVERSITY   (United States)

^b MOSCOW STATE UNIVERSITY   (Russian Federation)

^c STONY BROOK UNIVERSITY   (United States)

^d Massachusetts Institute of Technology Cambridge   (United States)

^e UNIVERSITY OF TENNESSEE   (United States)

^f Primet Precision   (United States)

^g PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^h State University of New York   (United States)

ⁱ LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^j UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^k NONE

more..

Author keywords

copper olivine; hydrothermal synthesis; redox behavior

Indexed keywords

BROWN COLOR; CUPRIC IONS; D-D TRANSITIONS; DE-LITHIATION; ELECTROCHEMICAL PROCESS; FIRST-PRINCIPLES CALCULATION; GALVANOSTATIC INTERMITTENT TITRATION; HYDROTHERMALLY; IRON IONS; LIFEPO; LITHIUM IONS; LITHIUM IRON PHOSPHATES; OLIVINE STRUCTURES; OPTICAL MEASUREMENT; POWDER SAMPLES; REDOX BEHAVIOR; REDOX POTENTIALS; SINGLE CRYSTAL X-RAY DIFFRACTION; SOLID STATE NMR;

COPPER; CRYSTAL STRUCTURE; ELECTROCHEMISTRY; HYDROTHERMAL SYNTHESIS; IRON; IRON COMPOUNDS; LANTHANUM COMPOUNDS; LITHIUM; LITHIUM ALLOYS; MAGNETIC MOMENTS; MAGNETIC SUSCEPTIBILITY; METAL IONS; NUCLEAR MAGNETIC RESONANCE; OLIVINE; OPTICAL DATA PROCESSING; REDOX REACTIONS; X RAY DIFFRACTION;

SINGLE CRYSTALS;

EID: 84862973342     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/cm2026619     Document Type: Conference Paper

References (46)

1. Padhi, A. K.; Nanjundaswamy, K. S.; Goodenough, J. B. J.Electrochem. Soc. 1997, 144, 1188
2. Yang, S.; Zavalij, P. Y.; Whittingham, M. S. Electrochem. Commun. 2001, 3, 505
3. Chen, J.; Vacchio, M. J.; Wang, S.; Chernova, N.; Zavalij, P. Y.; Whittingham, M. S. Solid State Ionics 2008, 178, 1676
4. Meethong, N.; Huang, H.-Y. S.; Carter, W. C.; Chiang, Y.-M. Electrochem. Solid-State Lett. 2007, 10, A134
5. Meethong, N.; Huang, H.-Y. S.; Speakman, S. A.; Carter, W. C.; Chiang, Y.-M. Adv. Funct. Mater. 2007, 17, 1115
6. Hong, J.; Wang, C. S.; Kasavajjula, U. J. Power Sources 2006, 162, 1289
7. Hong, J.; Wang, C. S.; Chen, X.; Upreti, S.; Whittingham, M. S. Electrochem. Solid-State Lett. 2009, 12, A33
8. Wang, D.; Ouyang, C.; Drézen, T.; Exnar, I.; Kay, A.; Kwon, N.-H.; Gouerec, P.; Miners, J. H.; Wang, M.; Grätzel, M. J. Electrochem. Soc. 2010, 157, A225
9. Chung, S.-Y.; Bloking, J. T.; Chiang, Y.-M. Nat. Mater. 2002, 1, 123
10. Herle, P. S.; Ellis, B.; Coombs, N.; Nazar, L. F. Nat. Mater. 2004, 3, 147
11. Ellis, B.; Herle, P. S.; Rho, Y.-H.; Nazar, L. F.; Dunlap, R.; Perry, L. K.; Ryan, D. H. Faraday Discuss. 2007, 134, 119
12. Chen, J.; Whittingham, M. S. Electrochem. Commun. 2006, 8, 855
13. Yang, S.; Song, Y.; Zavalij, P. Y.; Whittingham, M. S. Electrochem. Commun. 2002, 4, 239
14. Upreti, S.; Yakubovich, O. V.; Chernova, N. A.; Whittingham, M. S. Acta Crystallogr., Sect. E 2011, 67, i29
15. SMART, Bruker Molecular Analysis Research Tool, Version 5.0 618; Bruker AXS Inc.: Madision, WI, 2000.
16. SAINT-NT and SHELXTL-NT; Bruker AXS Inc.: Madision, WI, 2001.
17. Sheldrick, G. M. Acta Crystallogr., Sect. A 1990, 46, 467
18. Pankove, J. I. Optical processes in semiconductors; Courier Dover Publications: Mineola, NY, 1971.
19. Heyd, J.; Scuseria, G. E.; Ernzerhof, M. J. Chem. Phys. 2003, 118, 8207
20. Paier, J.; Marsman, M.; Hummer, K.; Kresse, G.; Gerber, I. C.; Angyan, J. G. J. Chem. Phys. 2006, 125, 249901
21. Heyd, J.; Scuseria, G. E.; Ernzerhof, M. J. Chem. Phys. 2006, 124, 219906
22. Aydinol, M. K.; Kohan, A. F.; Ceder, G.; Cho, K.; Joannopoulos, J. D. Phys. Rev. B 1997, 56, 1354
23. Liang, G.; Park, K.; Li, J.; Benson, R. E.; Vaknin, D.; Markert, J. T.; Croft, M. C. Phys. Rev. B 2008, 77, 064414
24. Chernova, N. A.; Nolis, G. M.; Omenya, F. O.; Zhou, H.; Li, Z.; Whittingham, M. S. J. Mater. Chem. 2011, 21, 9865
25. Mabbs, F. E.; Machin, D. J. Magnetism and Transition Metal Complexes; Chapman and Hall: London, U.K., 1973.
26. Zaghib, K.; Mauger, A.; Goodenough, J. B.; Gendron, F.; Julien, C. M. Chem. Mater. 2007, 19, 3740
27. Grey, C. P.; Dupré, N. Chem. Rev. 2004, 104, 4493
28. Santoro, R. P.; Newnham, R. E. Acta Crystallogr. 1967, 22, 344
29. Cabana, J.; Grey, C. P. In Energy Production and Storage: Inorganic Chemical Strategies for a Warming World; Crabtree, R. H., Ed.; John Wiley & Sons: West Sussex, U.K., 2010; p 375.
30. Tucker, M. C.; Doeff, M. M.; Richardson, T. J.; Fiñones, R.; Cairns, E. J.; Reimer, J. A. J. Am. Chem. Soc. 2002, 124, 3832
31. Recham, N.; Casas-Cabanas, M.; Cabana, J.; Grey, C. P.; Jumas, J. C.; Dupont, L.; Armand, M.; Tarascon, J. M. Chem. Mater. 2008, 20, 6798
32. Hamelet, S.; Gibot, P.; Casas-Cabanas, M.; Bonnin, D.; Grey, C. P.; Cabana, J.; Leriche, J.-B.; Rodriguez-Carvajal, J.; Courty, M.; Levasseur, S.; Carlach, P.; Van Thournout, M.; Tarascon, J. M.; Masquelier, C. J. Mater. Chem. 2009, 19, 3979
33. Cabana, J.; Shirakawa, J.; Chen, G.; Richardson, T. J.; Grey, C. P. Chem. Mater. 2010, 22, 1249
34. Davis, L. J. M.; Heinmaa, I.; Goward, G. R. Chem. Mater. 2010, 22, 769
35. Castets, A.; Carlier, D.; Trad, K.; Delmas, C.; Menetrier, M. J.Phys. Chem. C 2010, 114, 19141
36. Kim, J.; Middlemiss, D. S.; Zhu, B. Y. X.; Chernova, N. A.; Masquelier, C.; Grey, C. P. J. Am. Chem. Soc. 2010, 132, 16825
37. Shirakawa, J.; Cabana, J.; Wakihara, M.; Grey, C. P. J. Mater. Chem. 2011, 21, 10012
38. Zhou, F.; Kang, K.; Maxisch, T.; Ceder, G.; Morgan, D. Solid State Commun. 2004, 132, 181
39. Chevrier, V. L.; Ong, S. P.; Armiento, R.; Chan, M. K. Y.; Ceder, G. Phys. Rev. B 2010, 82, 075122
40. Zhou, F.; Cococcioni, M.; Kang, K.; Ceder, G. Electrochem. Commun. 2004, 6, 1144
41. Kobayashi, G.; Yamada, A.; Nishimura, S.; Kanno, R.; Kobayashi, Y.; Seki, S.; Ohno, Y.; Miyashiro, H. J. Power Sources 2009, 189, 397
42. Gwon, H.; Seo, D.-H.; Kim, S.-W.; Kim, J.; Kang, K. Adv. Funct. Mater. 2009, 19 (20) 3285
43. Seo, D.-H.; Gwon, H.; Kim, S.-W.; Kim, J.; Kang, K. Chem. Mater. 2010, 22, 518
44. Weppner, W.; Huggins, R. A. J. Electrochem. Soc. 1977, 124, 1569
45. Zhu, Y.; Wang, C. J. Phys. Chem. C 2010, 114, 2830
46. Morgan, D.; Van der Ven, A.; Ceder, G. Electrochem. Solid-State Lett. 2004, 7, A30