Synthesis of stable and soluble one-handed helical homopoly(substituted acetylene)s without the coexistence of any other chiral moieties via two-step polymer reactions in membrane state: Molecular design of the starting monomer

Molecules

Volumn 17, Issue 1, 2012, Pages 433-451

  Abe, Yunosuke ^a   Aoki, Toshiki ^a   Jia, Hongge ^b   Hadano, Shingo ^c   Namikoshi, Takeshi ^d   Kakihana, Yuriko ^a   Liu, Lijia ^a   Zang, Yu ^a   Teraguchi, Masahiro ^a   Kaneko, Takashi ^a  

^a NIIGATA UNIVERSITY   (Japan)

^b QIQIHAR UNIVERSITY   (China)

^c TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^d KITAMI INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Asymmetric polymerization; Chirality; Membrane; One handed helicity; Phenylacetylene; Polymer reaction; Solubility

Indexed keywords

ACETYLENE; DRUG DERIVATIVE; POLY(PHENYLACETYLENE);

ARTICLE; ARTIFICIAL MEMBRANE; CHEMISTRY; CIRCULAR DICHROISM; CONFORMATION; HYDROGEN BOND; INFRARED SPECTROPHOTOMETRY; ISOLATION AND PURIFICATION; POLYMERIZATION; STEREOISOMERISM; SYNTHESIS; ULTRAVIOLET SPECTROPHOTOMETRY;

ACETYLENE; CIRCULAR DICHROISM; HYDROGEN BONDING; MEMBRANES, ARTIFICIAL; MOLECULAR CONFORMATION; POLYMERIZATION; SPECTROPHOTOMETRY, INFRARED; SPECTROPHOTOMETRY, ULTRAVIOLET; STEREOISOMERISM;

EID: 84862967381     PISSN: None     EISSN: 14203049     Source Type: Journal    
DOI: 10.3390/molecules17010433     Document Type: Article

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34. The sign of the CD signals for poly(re-1) was opposite to those for poly(1) and poly(de-1). The reason is not clear at present but since they are not mirror images each other, it did not show inversion of the helical sense.