Electrochemical performance of a Pb/Pb-MnO 2 composite anode in sulfuric acid solution containing Mn 2+

Hydrometallurgy

Volumn 115-116, Issue , 2012, Pages 64-70

  Lai, Y Q ^a   Li, Y ^a   Jiang, L X ^a   Lv, X J ^a   Li, J ^a   Liu, Y X ^a  

^a CENTRAL SOUTH UNIVERSITY   (China)

Author keywords

Corrosion resistance; Mn 2+ ion; Oxygen evolution reaction; Pb Pb MnO 2 composite anode; Zinc electrowinning

Indexed keywords

ACID ELECTROLYTES; ADSORPTION RESISTANCES; ANODIC LAYERS; COMPOSITE ANODES; CORROSION BEHAVIOUR; ELECTROCHEMICAL METHODS; ELECTROCHEMICAL PERFORMANCE; HIGH CONCENTRATION; KINETIC MECHANISM; OXYGEN EVOLUTION; OXYGEN EVOLUTION ACTIVITY; OXYGEN EVOLUTION REACTION; REACTION RESISTANCE; SULFURIC ACID SOLUTION; XRD; ZINC ELECTROWINNING;

ADSORPTION; ANODES; CORROSION RESISTANCE; ELECTROLYTES; LEAD OXIDE; MANGANESE OXIDE; OXYGEN; REACTION INTERMEDIATES; SULFURIC ACID;

MANGANESE;

EID: 84862804453     PISSN: 0304386X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.hydromet.2011.12.013     Document Type: Article

References (45)

1. 2 anodes in acid media J. Electroanal. Chem. 534 2002 1
2. J. Aromaa, and J.M. Evans Electrowinning of metals Encycl. Electrochem. 5 2007 159 265
3. 2 permanent anode Electrochem. Acta 51 2006 6104 6110 (Pubitemid 44223444)
4. 2+ ions on the kinetics of lead anodes for zinc electrowinning J. Appl. Electrochem. 29 1999 813 820
5. C.N. Cao On the impedance plane displays for irreversible electrode reactions based on the stability conditions of the steady-state - I. One state variable besides electrode potential Electrochim. Acta 35 1990 831 836
6. K.J. Cathro Electrowinning of zinc at high current density Chem. Aust. 58 1991 490
7. 2 composite electrode J. Yunnan Univ. 29 2007 272 277 (In Chinese)
8. 2 surfaces J. Mater. Chem. 1 1991 725 734
9. A. Czerwinski, M. Zelazowska, and M. Grden Electrochemical behaviour of lead in sulfuric acid solutions J. Power Sources 85 2000 49 55 (Pubitemid 30564930)
10. 4(1 - x) electrodes from acid solution Electrochim. Acta 46 2000 1369 1375
11. L.M. Da Silva, L.A. de Faria, and J.F.C. Boodts Green processes for environmental application. Electrochemical ozone production Pure Appl. Chem. 73 2001 1871
12. L.M. Da Silva, L.A. de Faria, and J.F.C. Boodts Electrochemical ozone production: influence of the supporting electrolyte on kinetics and current efficiency Electrochim. Acta 48 2003 699
13. D. Devilliers, M.T. Dinh Thi, E. Mahe, V. Daruiac, and N. Lequeux Electroanalytical investigations on electrodeposited lead dioxide J. Electroanal. Chem. 573 2004 227 239
14. T. Dobrev, I. Valchanova, Y. Stefanov, and S. Magaeva Investigations of new anodic materials for electrowinning Trans. Inst. Met. Finish. 87 2009 136 140
15. A. Felder, and R.D. Prengaman Lead alloys for permanent anodes in the nonfereous metals industry JOM 58 2006 28 31 (Pubitemid 44605209)
16. D.V. Franco, L.M. Da Silva, and W.F. Jardim Influence of the electrolyte composition on the kinetics of the oxygen evolution reaction and ozone production processes J. Braz. Chem. Soc. 17 2006 746 757 (Pubitemid 44167175)
17. 2 J. Electroanal. Chem. 366 1994 147
18. 4 anodes in copper electrowinning J. Appl. Electrochem. 32 2002 505 512 (Pubitemid 34950883)
19. 4, Pb-Ca-Sn, and Pb-Sb anodes for copper electrowinning: Part I Hydrometallurgy 72 2004 205 213
20. 4, Pb-Ca-Sn, and Pb-Sb anodes for copper electerwinning: Part II Hydrometallurgy 72 2004 215 224
21. 2-based DSA type electrodes: kinetics analysis of Tafel lines and EIS Int. J. Hydrogen Energy 29 2004 791 797
22. I. Ivanov Increased current efficiency of zinc electrowinning in the presence of metal impurities by addition of organic inhibitors Hydrometallurgy 72 2004 73 78
23. I. Ivanov, and Y. Stefanov Electroextraction of zinc from sulfate electrolytes containing antimony ions and hydroxyethylated-butyne-2-diol-1, 4: part 3. The influence of manganese ions and a divided cell Hydrometallurgy 64 2002 181 186 (Pubitemid 34704422)
24. G.H. Kelsall, E. Guerra, G. Li, and M. Bestetti Effects of manganese (II) and chloride ions in zinc electrowinning reactors Proceedings - -Electrochemical Society, 2000-14 (Electrochemistry in Mineral and Metal Processing V) 2000 350 361
25. Krupkowa, D., Jurczyk, H., Krezel, K., Nosel, J., Gluszczyszyn, A. and Mendyka, M., 1977. Zinc electrowinning. Pl Patent No. 89821.
26. Y.Q. Lai, L.X. Jiang, J. Li, S.P. Zhong, X.J. Lv, H.J. Peng, and Y.X. Liu A novel porous Pb-Ag anode for energy-saving in zinc electro-winning. Part I Laboratory preparation and properties Hydrometallurgy 102 2010 73 80
27. 2 composite anode for zinc electrowinning Chin. J. Nonferrous Met. 20 2010 2357 2365 (In Chinese)
28. 2 composite anode for electrowinning of nonferrous metals Hydrometallurgy 109 2011 252 257
29. D.J. MacKinnon, and J.M. Brannen Effect of manganese, magnesium, sodium and potassium sulfates on zinc electrowinning from synthetic acid sulfate electrolytes Hydrometallurgy 27 1991 99 111 (Pubitemid 21727500)
30. G.N. Martelli, R. Ornelas, and G. Faita Deactivation mechanism of oxygen evolving anodes at high current density Electrochim. Acta 39 1994 1551
31. 5/Ti anodes Electrochim. Acta 46 2000 401
32. 2: a composite anode for oxygen evolution from sulphuric acid solution J. Electroanal. Chem. 465 1999 160 167
33. R.H. Newnham Corrosion rates of lead-based anodes for zinc electrowinning at high current densities J. Appl. Electrochem. 22 1992 116 124
34. St Rashkov, Y. Stefanov, and Z. Noncheva Investigation of the processes of obtaining plastic treatment and electrochemical behaviour of lead alloys in their capacity as anodes during the electroextraction of zinc II. Electrochemical formation of phases layers on binary Pb-Ag and Pb-Ca, and ternary Pb-Ag-Ca alloys in a sulphuric-acid electrolyte for zinc electro-extraction Hydrometallurgy 40 1996 319 334 (Pubitemid 126349503)
35. C. Rerolle, and R. Wiart Kinetics of oxygen evolution on Pb and Pb-Ag anodes during zinc electrowinning Electrochim. Acta 41 1996 1063 1069 (Pubitemid 126328207)
36. 2 electrodes J. Electrochem. Soc. 139 1992 1347
37. A.E. Saba, and A.E. Elsherief Continuous electrowinning of zinc Hydrometallurgy 54 2000 91 106 (Pubitemid 30541724)
38. T. Schierle, and K. Hein Anode depolarization in the metal winning electrolysis Erzmetall World Metall. 46 1993 164 169
39. 2 composite electrodes J. Appl. Electrochem. 39 2009 1835 1848
40. 2 coated titanium anodes J. Appl. Electrochem. 39 2009 107 116
41. 2 alloy coated lead composite anodes for zinc electrowinning Trans. Inst. Met. Finish. 83 2005 291 295 (Pubitemid 43129060)
42. B. Verbaan, and B. Mullinder The simultaneous electrowinning of manganese dioxide and zinc from purified neutral zinc sulfate at high current efficiencies Hydrometallurgy 7 1981 339 352 (Pubitemid 12458414)
43. Y. Yamamoto, K. Fumino, T. Ueda, and M. Nambu A potentiodynamic study of the lead electrode in sulphuric acid solution Electrochim. Acta 37 1992 199 203
44. P. Yu, and T.J. O'Keefe Evaluation of lead anode reactions in acid sulfate electrolytes II. Manganese reactions J. Electrochem. Soc. 149 2002 A558 A569
45. W. Zhang, and C.Y. Cheng Manganese metallurgy review. Part III: Manganese control in zinc and copper electrolytes Hydrometallurgy 89 2007 178 188 (Pubitemid 47625740)