Magnetic relaxation behavior of a spatially closed dysprosium(III) phthalocyaninato double-decker complex

Science China Chemistry

Volumn 55, Issue 6, 2012, Pages 918-925

  Katoh, Keiichi ^a   Umetsu, Kaori ^a   Breedlove Brian, K ^a   Yamashita, Masahiro ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

double decker complex; dysprosium; magnetic relaxation process; pseudo dinuclear complex; single molecule magnets

Indexed keywords

AC FIELD; AC-SUSCEPTIBILITY MEASUREMENTS; ANTIFERROMAGNETIC INTERACTION; COMPLEX 1; DC MAGNETIC FIELD; DIMER STRUCTURE; DINUCLEAR COMPLEX; DOUBLE-DECKER COMPLEX; MONOCLINIC SPACE GROUPS; POWDER SAMPLES; PREEXPONENTIAL FACTOR; QUANTUM TUNNELING; RELAXATION MECHANISM; SINGLE-MOLECULE MAGNET;

ANTIFERROMAGNETISM; ARRHENIUS PLOTS; ETHANOL; MAGNETIC RELAXATION; MAGNETIC SUSCEPTIBILITY; MAGNETS; MOLECULES;

DYSPROSIUM;

EID: 84862524138     PISSN: 16747291     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11426-012-4615-9     Document Type: Conference Paper

References (44)

1. C. Joachim J.K. Gimzewski A. Aviram 2000 Electronics using hybrid-molecular and mono-molecular devices Nature 408 541 548 10.1038/35046000 1:CAS:528:DC%2BD3cXovFWrsr4%3D
2. M.F. Cracium S. Rogge A.F. Morpurgo 2005 Correlation between molecular orbitals and doping dependence of the electrical conductivity in electron-doped metal-phthalocyanine compounds J Am Chem Soc 127 12210 12211 10.1021/ja054468j (Pubitemid 41279230)
3. N. Papageorgiou E. Salomon T. Angot J.M. Layet L. Giovanelli G.L. Lay 2004 Physics of ultra-thin phthalocyanine films on semiconductors Prog Surf Sci 77 139 258 10.1016/j.progsurf.2005.01.001 1:CAS:528:DC%2BD2MXhs1ygs7c%3D
4. N. Ishikawa M. Sugita T. Ishikawa S. Koshihara T. Kaizu 2003 Lanthanide double-decker complexes functioning as magnets at the single-molecular level J Am Chem Soc 25 8694 8695 10.1021/ja029629n (Pubitemid 36886185)
5. L. Bogani W. Wernsdorfer 2008 Molecular spintronics using single-molecule magnets Nat Mater 7 179 186 10.1038/nmat2133 1:CAS:528:DC%2BD1cXisVSrsrk%3D (Pubitemid 351311291)
6. M. Urdampilleta S. Klyatskaya J.P. Cleuziou M. Ruben W. Wernsdorfer 2011 Supramolecular spin valves Nat Mater 10 502 506 10.1038/nmat3050 1:CAS:528:DC%2BC3MXnslSmtbY%3D
7. K. Katoh Y. Yoshida M. Yamashita H. Miyasaka B.K. Breedlove T. Kajiwara S. Takaishi N. Ishikawa H. Isshiki Y.F. Zhang T. Komeda M. Yamagishi J. Takeya 2009 Direct observation of lanthanide(III)-phthalocyanine molecules on Au(111) by using scanning tunneling microscopy and scanning tunneling spectroscopy and thin-film field-effect transistor properties of Tb(III)-and Dy(III)- phthalocyanine molecules J Am Chem Soc 131 9967 9976 10.1021/ja902349t 1:CAS:528:DC%2BD1MXnvFWrs7c%3D
8. T. Komeda H. Isshiki L. Liu Y.F. Zhang N. Lorente K. Katoh B.K. Breedlove M. Yamashita 2011 Observation and electric current control of a local spin in a single-molecule magnet Nat Commun 2 217 223 10.1038/ncomms1210
9. C. Romeike M.R. Wegewijs W. Hofstetter H. Schoeller 2006 Kondo-transport spectroscopy of single molecule magnets Phys Rev Lett 97 206601/1 4 10.1103/PhysRevLett.97.206601 1:CAS:528:DC%2BD28Xht1ajur7O (Pubitemid 44759873)
10. Kasuga K, Ando M, Morimoto H, Isa M. Preparation of new phthalocyanine complexes of yttrium(III) and some lanthanoid(III) ions. Chem Lett, 1986, 1095-1098
11. Takahashi K, Itoh M, Tomita Y, Nojima K, Kasuga K, Isa K. Preparation, characterization, and electrochemical properties of tris (2,3,9,10,16,17,23,24- octabutoxyphthalocyaninato)diytterbium(III) and -didysprosium(III). Chem Lett, 1993, 1915-1918
12. 8 system in a dinuclear terbium complex with phthalocyanines Angew Chem Int Ed 44 731 733 10.1002/anie.200461546 1:CAS:528:DC%2BD2MXhtVSksb4%3D (Pubitemid 40203982)
13. N. Ishikawa T. Iion Y. Kaizu 2002 Interaction between f-electronic systems in dinuclear lanthanide complexes with phthalocyanines J Am Chem Soc 124 11440 11447 10.1021/ja027119n 1:CAS:528:DC%2BD38Xms1CnsLo%3D
14. K. Katoh T. Kajiwara M. Nakano Y. Nakazawa W. Wernsdorfer N. Ishikawa B.K. Breedlove M. Yamashita 2011 Magnetic relaxation of single-molecule magnets in an external magnetic field: An ising dimer of a terbium(III)-phthalocyaninate triple-decker complex Chem Eur J 17 117 122 10.1002/chem.201002026 1:CAS:528:DC%2BC3MXit1OmtQ%3D%3D
15. K. Katoh H. Isshiki T. Komeda M. Yamashita 2011 Multiple-decker phthalocyaninato Tb(III) single-molecule magnets and Y(III) complexes for next generation devices Coord Chem Rev 255 2124 2146 10.1016/j.ccr.2011.02.024 1:CAS:528:DC%2BC3MXpt1CisLY%3D
16. W. Wernsdorfer N. Aliaga-Alcalde D.N. Hendrickson G. Christou 2002 Exchange-biased quantum tunnelling in a supramolecular dimer of single-molecule magnets Nature 416 406 409 10.1038/416406a (Pubitemid 34272870)
17. K. Katoh K. Yamamoto T. Kajiwara J. Takeya B.K. Breedlove M. Yamashita 2011 Magnetic properties of lanthanoid(III) phthalocyaninato triple-decker complexes in an external magnetic field and electronic transport properties for molecular spintronics J Phys: Conf Ser 303 012035/1 10 10.1088/1742-6596/303/1/ 012035 1:CAS:528:DC%2BC3MXhtFWrs7jE
18. L. Margheriti D. Chiappe M. Mannini P.E. Car P. Sainctavit M.A. Arrio F.B. de Mangeot J.C. Cezar F.M. Piras A. Magnani E. Otero A. Caneschi R. Sessoli 2010 X-ray detected magnetic hysteresis of thermally evaporated terbium double-decker oriented films Adv Mater 22 5488 5493 10.1002/adma.201003275 1:CAS:528:DC%2BC3cXhsFGlt77E
19. 3OH Inorg Chem 24 3162 3167 10.1021/ic00214a016
20. Sheldrick GM. SHELXTL program for Crystal Structure Determination. Siemens Analytical X-ray Instruments Inc., Madison, WI, 1994
21. Beurskens PT, Admiraal G, Beurskens G, Bosman WP, de Gelder R, Israel R, Smits JMM. DIRDIF94, 1994
22. J. Padilla W.E. Hatfield 1989 Magnetic and electrical properties of sandwich-like lanthanide phthalocyanines Synth Met 29 F45 F50 10.1016/0379-6779(89)90877-1
23. D. Markovitsi T.H. Tran-Thi R. Even J. Simon 1987 Near infrared absorption spectra of lanthanide bis-phthalocyanines Chem Phys Lett 137 107 112 10.1016/0009-2614(87)80313-5 1:CAS:528:DyaL2sXks1Kqtrs%3D
24. A. Iwase C. Harnoode Y.J. Kameda 1993 Synthesis and electrochemistry of double-decker lanthanoid (III) phthalocyanine complexes Alloys Compd 192 280 283 10.1016/0925-8388(93)90249-M 1:CAS:528:DyaK3sXlvFChu74%3D
25. K.M. Kadish G. Moninot Y. Hu D. Dubois A. Ibnlfassi M. Barbe R. Guilard 1993 Double-decker actinide porphyrins and phthalocyanines. Synthesis and spectroscopic characterization of neutral, oxidized, and reduced homo- and heteroleptic complexes J Am Chem Soc 115 8153 8166 10.1021/ja00071a028 1:CAS:528:DyaK3sXlsFWjtbk%3D
26. J. Jiang R.C.W. Liu T.C.W. Mak T.W.D. Chan D.K.P. Ng 1997 Synthesis, spectroscopic and electrochemical properties of substituted bis(phthalocyaninato)lanthanide(III) complexes Polyhedron 16 515 520 10.1016/0277-5387(96)00248-3 1:CAS:528:DyaK2sXht1amtL8%3D (Pubitemid 127348473)
27. F. Habib P.H. Lin J. Long I. Korobkov W. Wernsdorfer M. Murugesu 2011 The use of magnetic dilution to elucidate the slow magnetic relaxation effects of a Dy2 single-molecule magnet J Am Chem Soc 133 8830 8833 10.1021/ja2017009 1:CAS:528:DC%2BC3MXmt1Krt7w%3D
28. 12] cores with different magnetic anisotropies Chem Sci 2 1268 1272 10.1039/c1sc00166c
29. J. Long F. Habib P.H. Lin I. Korobkov G. Enright L. Ungur W. Wernsdorfer L.F. Chibotaru M. Murugesu 2011 Single-molecule magnet behavior for an antiferromagnetically superexchange-coupled dinuclear dysprosium(III) complex J Am Chem Soc 133 5319 5328 10.1021/ja109706y 1:CAS:528:DC%2BC3MXjsFKnsrg%3D
30. III) Chem Eur J 8 525 531 10.1002/1521-3765(20020118)8:2<525::AID-CHEM525>3.0.CO;2-L 1:CAS:528:DC%2BD38XhtVyisrk%3D (Pubitemid 34121005)
31. P.H. Lin T.J. Burchell R. Clérac M. Murugesu 2008 Dinuclear dysprosium( III) single-molecule magnets with a large anisotropic barrier Angew Chem Int Ed Engl 120 8980 8983 10.1002/ange.200802966
32. H. Wang K. Qian K. Wang Y. Bian J. Jiang S. Gao 2011 Sandwich-type tetrakis(phthalocyaninato) dysprosium-cadmium quadruple-decker SMM Chem Commun 47 9624 9626 10.1039/c1cc12509e 1:CAS:528:DC%2BC3MXhtVWgs73K
33. P.H. Lin T.J. Burchell L. Ungur L.F. Chibotaru W. Wernsdorfer M. Murugesu 2009 A polynuclear lanthanide single-molecule magnet with a record anisotropic barrier Angew Chem Int Ed 48 9489 9492 10.1002/anie.200903199 1:CAS:528:DC%2BD1MXhsFars7bJ
34. 3--radical-bridged lanthanide complexes Nat Chem 3 538 542 10.1038/nchem.1063 1:CAS:528:DC%2BC3MXmsVGmt7o%3D
35. N. Ishikawa Y. Mizuno S. Takamatsu T. Ishikawa S. Koshihara 2008 Effects of chemically induced contraction of a coordination polyhedron on the dynamical magnetism of bis(phthalocyaninato)disprosium, a single-4f-ionic single-molecule magnet with a Kramers ground state Inorg Chem 47 10217 10219 10.1021/ic8014892 1:CAS:528:DC%2BD1cXht1CgsbrP
36. N. Ishikawa M. Sugita W. Wernsdorfer 2005 Quantum tunneling of magnetization in lanthanide single-molecule magnets: bis (phthalocyaninato) terbium and bis(phthalocyaninato)dysprosium anions Angew Chem Int Ed 44 2931 2935 10.1002/anie.200462638 1:CAS:528:DC%2BD2MXksVKlsbo%3D (Pubitemid 40689677)
37. K.S. Cole R.H. Cole 1941 Dispersion and absorption in dielectrics J Chem Phys 9 341 351 10.1063/1.1750906 1:CAS:528:DyaH3MXit1Sktw%3D%3D
38. C. Lampropoulos S. Hill G. Christou 2009 A caveat for single-molecule magnetism: Nonlinear Arrhenius plots ChemPhysChem 10 2397 2400 10.1002/cphc.200900420 1:CAS:528:DC%2BD1MXht1ajur3P
39. N. Domingo F. Luis M. Nakano J. Muntó Jordi Gómez J. Chaboy N. Ventosa J. Campo J. Veciana D. Ruiz-Molina 2009 Particle-size dependence of magnetization relaxation in Mn12 crystals Phys Rev B 79 214404/1 9 10.1103/PhysRevB.79.214404 1:CAS:528:DC%2BD1MXotFOhtbg%3D
40. S.D. Jiang B.W. Wang H.L. Sun Z.M. Wang S. Gao 2011 An organometallic single-ion magnet J Am Chem Soc 133 4730 4733 10.1021/ja200198v 1:CAS:528:DC%2BC3MXjtFers7c%3D
41. N. Ishikawa Y. Mizuno S. Takamatsu T. Ishikawa S. Koshihara 2008 Effects of chemically induced contraction of a coordination polyhedron on the dynamical magnetism of bis(phthalocyaninato)disprosium, a single-4f-ionic single-molecule magnet with a Kramers ground state Inorg Chem 47 10217 10219 10.1021/ic8014892 1:CAS:528:DC%2BD1cXht1CgsbrP
42. D. Gatteschi R. Sessoli 2003 Quantum tunneling of magnetization and related phenomena in molecular materials Angew Chem Int Ed 42 268 297 10.1002/anie.200390099 1:CAS:528:DC%2BD3sXhtVWqsLw%3D (Pubitemid 36181508)
43. H.A. Kramers 1930 General theory of the paramagnetic rotation in crystals Proc K Ned Akad Wet 33 959 972 1:CAS:528:DyaA3MXis1aisQ%3D%3D
44. W. Wernsdorfer S. Bhaduri C. Boskovic G. Christou D.N. Hendrickson 2002 Spin-parity dependent tunneling of magnetization in single-molecule magnets Phys Rev B 65 180403/1 4 10.1103/PhysRevB.65.180403 1:CAS:528:DC%2BD38XktVSqs7w%3D