Initiation of radical chain reactions of thiol compounds and alkenes without any added initiator: Thiol-catalyzed cis/trans isomerization of methyl oleate

Chemistry - A European Journal

Volumn 18, Issue 26, 2012, Pages 8201-8207

  Biermann, Ursula ^a   Butte, Werner ^a   Koch, Rainer ^a   Fokou, Patrice A ^b   Türünç, Oǧuz ^c   Meier, Michael A R ^c   Metzger, Jürgen O ^a  

^a UNIVERSITY OF OLDENBURG   (Germany)

^b UNIVERSITY OF APPLIED SCIENCES EMDEN LEER   (Germany)

^c KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

isomerization; methyl oleate; molecule assisted homolysis (MAH); radicals; renewable resources

Indexed keywords

CIS/TRANS ISOMERIZATION; COMPLEX REACTIONS; COMPUTATIONAL STUDIES; DODECANETHIOLS; EDA COMPLEX; ELECTRON DONORS; HOMOLYSIS; KINETIC ISOTOPE EFFECTS; KINETIC STUDY; METHYL OLEATE; RADICAL CHAIN REACTIONS; RADICALS; REACTION ORDERS; RENEWABLE RESOURCE; SHELF LIFE; THERMAL GENERATION; THIOL COMPOUNDS; THIYL RADICALS;

ACTIVATION ENERGY; ADDITION REACTIONS; CATALYSIS; HYDROGEN BONDS; ISOMERIZATION; ISOTOPES; MOLECULES; OLEFINS; SULFUR;

ISOMERS;

ALKENE; OLEIC ACID; OLEIC ACID METHYL ESTER; THIOL DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL MODEL; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; THERMODYNAMICS;

ALKENES; CATALYSIS; MODELS, CHEMICAL; MOLECULAR STRUCTURE; OLEIC ACIDS; STEREOISOMERISM; SULFHYDRYL COMPOUNDS; THERMODYNAMICS;

EID: 84862515317     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201103252     Document Type: Article

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