Aqueous pharmaceutical compounds removal by potassium monopersulfate. Uncatalyzed and catalyzed semicontinuous experiments

Chemical Engineering Journal

Volumn 192, Issue , 2012, Pages 326-333

  Rivas, F J ^a   Gimeno, O ^a   Borallho, T ^a  

^a UNIVERSITY OF EXTREMADURA   (Spain)

Author keywords

Cobalt catalysis; Monopersulfate; Oxone; Pharmaceuticals; Water treatment

Indexed keywords

CATALYZED REACTIONS; CO COMPLEXES; DOXYCYCLINE; HALF LIVES; MODEL COMPOUND; MONOPERSULFATE; OXIDATION PROCESS; OXONE; PHARMACEUTICAL COMPOUNDS; POTASSIUM MONOPERSULFATE; REACTION MECHANISM; SECOND ORDER KINETIC EXPRESSION; SECOND-ORDER RATE CONSTANTS; SEMI-CONTINUOUS;

CATALYSIS; CHEMICALS REMOVAL (WATER TREATMENT); COBALT; DRUG PRODUCTS; POTASSIUM; POTASSIUM COMPOUNDS; RATE CONSTANTS; WATER TREATMENT;

PH EFFECTS;

EID: 84862327031     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2012.03.055     Document Type: Article

References (41)

1. Wells M.J.M., Bell K.Y., Traexler K.A., Pellegrin M.L., Morse A. Emerging pollutants. Water Environ. Res. 2010, 82:2095-2170.
2. Pal A., Gin K.Y.H., Lin A.Y.C., Reinhard M. Impacts of emerging organic contaminants on freshwater resources: review of recent occurrences, sources, fate and effects. Sci. Total. Environ. 2010, 408:6062-6069.
3. Burkhardt-Holm P. Endocrine disruptors and water quality: a state-of-the-art review. Int. J. Wat. Res. Develop. 2010, 26:477-493.
4. Snyder S.A., Benotti M.J. Endocrine disruptors and pharmaceuticals: implications for water sustainability. Wat. Sci. Technol. 2010, 61:145-154.
5. Gerrity D., Snyder S. Review of ozone for water reuse applications: toxicity, regulations, and trace organic contaminant oxidation. Ozone Sci. Eng. 2011, 33:253-266.
6. Rodríguez A., Rosal R., Gomez M.J., García-Calvo E., Fernandez-Alba A.R. Ozone-based reclamation of an STP effluent. Wat. Sci. Technol. 2011, 63:2123-2130.
7. Rivas F.J., Gimeno O., Borralho T., Sagasti J. UV-C and UV-C/peroxide elimination of selected pharmaceuticals in secondary effluents. Desalination 2011, 279:115-120.
8. Tong A.Y.C., Braund R., Tan E.W., Tremblay L.A., Stringer T., Trought K., Peake B.M. UV-induced photodegradation of oseltamivir (Tamiflu) in water. Environ. Chem. 2011, 8:182-189.
9. Beltrán F.J., Aguinaco A., García-Araya J.F., Oropesa A. Ozone and photocatalytic processes to remove the antibiotic sulfamethoxazole from water. Wat. Res. 2008, 42:3799-3808.
10. Pérez-Estrada L.A., Malato S., Gernjak W., Agüera A., Thurman E.M., Ferrer I., Fernández-Alba A.R. Photo-Fenton degradation of diclofenac: identification of main intermediates and degradation pathway. Environ. Sci. Technol. 2005, 39:8300-8306.
11. 2+/Oxone regent: kinetic analysis. J. Hazard. Mat. 2011, 190:1083-1087.
12. Zhang W., Tay H.L., Lim S.S., Wang Y., Zhong Z., Xu R. Supported cobalt oxide on MgO: highly efficient catalysts for degradation of organic dyes in dilute solutions. App. Catal. B: Environ. 2010, 95:93-99.
13. Rivas F.J., Gimeno O., Borralho T., Carbajo M. UV-C photolysis of endocrine disruptors. the influence of inorganic peroxides. J. Hazard. Mat. 2010, 174:393-397.
14. Rivas F.J., García de la Calle R., García-Araya J.F., Gimeno O. Promoted wet air oxidation of polynuclear aromatic hydrocarbons. J. Hazard. Mat. 2008, 153:792-798.
15. Anipsitakis G.P., Dionysiou D.D. Transition metal/UV-based advanced oxidation technologies for water decontamination. App. Catal. B: Environ. 2004, 54:155-163.
16. Pagano M., Volpe A., Mascolo G., Lopez A., Locaputo V., Ciannarella R. Peroxymonosulfate-Co(II) oxidation system for the removal of the non-ionic surfactant Brij 35 from aqueous solution. Chemosphere 2012, 86:329-334.
17. Yuan R., Ramjaun S.N., Wang Z., Liu J. Effects of chloride ion on degradation of acid orange 7 by sulfate radical-based advanced oxidation process: implications for formation of chlorinated aromatic compounds. J. Hazard. Mat. 2011, 196:173-179.
18. Antoniou M.G., de la Cruz A.A., Dionysiou D.D. Degradation of microcystin-LR using sulfate radicals generated through photolysis, thermolysis and e- transfer mechanisms. App. Catal. B: Environ. 2010, 96:290-298.
19. J. Sun, M. Song, J. Feng, Y. Pi, Highly efficient degradation of ofloxacin by UV/Oxone/Co2+ oxidation process, Environ. Sci. Pollut. Res, http://dx.doi.org/10.1007/s11356011.0654.6.
20. Nfodzo P., Choi H. Sulfate radicals destroy pharmaceuticals and personal care products. Environ. Eng. Sci. 2011, 28:605-609.
21. Firouzabadi H., Iranpoor N., Kazemi S. Direct halogenation of organic compounds with halides using Oxone in water - a green protocol. Canadian J. Chem. 2009, 87:1675-1681.
22. Yu J., Cui J., Zhang C. A simple and effective method for α-hydroxylation of β-dicarbonyl compounds using Oxone as an oxidant without a catalyst. Eur. J. Org. Chem. 2010, 36:7020-7026.
23. Priewisch B., Rück-Braun K. Efficient preparation of nitrosoarenes for the synthesis of azobenzenes. J. Org. Chem. 2005, 70:2350-2352.
24. Desai L.V., Malik H.A., Sanford M.S. Oxone as an inexpensive, safe, and environmentally benign oxidant for C-H bond oxygenation. Org. Lett. 2006, 8:1141-1144.
25. Yan J., Travis B.R., Borhan B. Direct oxidative cleavage of alpha- and beta- dicarbonyls and alpha-hydroxyketones to diesters with KHSO5. J. Org. Chem. 2004, 69:9299-9302.
26. Fields J.D., Kropp P.J. Surface-mediated reactions. 9. Selective oxidation of primary and secondary amines to hydroxylamines. J. Org. Chem. 2000, 65:5937-5941.
27. Ball D.L., Edwards J.O. The kinetics and mechanism of the decomposition of Caro's acid I. J. Am. Chem. Soc. 1956, 78:1125-1129.
28. Ball D.L., Edwards J.O. The catalysis of the decomposition of Caro's acid. J. Phys. Chem. 1958, 62:343-345.
29. Anipsitakis G.P., Dionysiou D.D. Degradation of organic contaminants in water with sulphate radicals generated by the conjunction of peroxymonosulfate with cobalt. Environ. Sci. Technol. 2003, 37:4790-4797.
30. Rivas F.J., Gimeno O., Carbajo M., Borralho T. Catalytic decomposition of potassium monopersulfate influence of variables. Proceedings of World Academy of Science, Engineering and Technology 2009, 57:218-222.
31. Rivas F.J., Beltrán F.J., Carvalho F., Alvarez P.M. Oxone-promoted wet air oxidation of landfill leachates. Ind. Eng. Chem. Res. 2005, 44:749-758.
32. 4- radical in aqueous solution. J. Photochem. & Photobiol. A: Chemistry 1988, 44:243-258.
33. 5- radicals self reaction in aqueous solution. J. Phys. Chem. 1993, 1993(97):10712-10714.
34. 5- radicals self reaction in aqueous solution. J. Phys. Chem. 1996, 100:3557-3560.
35. Zhang Z., Edwards J.O., Rieger P.H. The decomposition of peroxomonosulfate induced by manganese (II) in acid solution. Inorg. Chim. Acta. 1994, 221:25-30.
36. Rivas F.J., Gimeno O., Carbajo M., Borralho T. Catalytic decomposition of potassium monopersulfate. The kinetics, Proceedings of World Academy of Science, Engineering and Technology 2009, 57:223-227.
37. Li X., Xiong Z., Ruan X., Xia D., Zeng Q., Xu A. Kinetics and mechanism of organic pollutants degradation with cobalt-bicarbonate-hydrogen peroxide system: Investigation of the role of substrates. Appl. Catal. A: General 2012, 411-412:24-30.
38. P. Hendry, A. Ludi, Advances in Inorganic Chemistry, Vol. 35. A.G. Sykes (Ed.). Academic Press, London, (1990) 117-192.
39. Rivas F.J., Beltran F.J., Frades J., Buxeda P. Oxidation of p-hydroxybenzoic acid by Fenton's reagent. Wat. Res. 2001, 35:387-396.
40. http://www.inchem.org/documents/ukpids/ukpids/ukpid51.htm.
41. http://www.inchem.org/documents/iarc/vol52/11-cobaltandcobaltcomp.html.