Electrocatalytic oxidation of ethylene glycol (EG) on supported Pt and Au catalysts in alkaline media: Reaction pathway investigation in three-electrode cell and fuel cell reactors

Applied Catalysis B: Environmental

Volumn 125, Issue , 2012, Pages 85-94

  Xin, Le ^a   Zhang, Zhiyong ^a   Qi, Ji ^a   Chadderdon, David ^a   Li, Wenzhen ^a  

^a Michigan Technological University   (United States)

Author keywords

Alkaline electrolyte; Electrocatalytic oxidation; Ethylene glycol; Fuel cell; Reaction pathway

Indexed keywords

ALKALINE ELECTROLYTES; ALKALINE MEDIA; ANION EXCHANGE; ANODE CATALYSTS; APPLIED POTENTIALS; AU CATALYSTS; AU NANOPARTICLE; C-C BONDS; ELECTRO-CATALYTIC OXIDATION; FUEL CELL OPERATION; FUEL CELL REACTORS; GLYCOLIC ACIDS; HIGH SELECTIVITY; NARROW SIZE DISTRIBUTIONS; OVERPOTENTIAL; OXALIC ACID; OXIDATION REACTIONS; PEAK POWER DENSITIES; PT ANODES; REACTION PATHWAYS; SAMPLE COLLECTION; SOLUTION-PHASE REDUCTION METHOD; SUPPORTED PT; TEST CONDITION; THREE ELECTRODE CELLS;

ELECTROCATALYSIS; ETHYLENE GLYCOL; FORMIC ACID; FUEL CELLS; GOLD; METAL DRAWING; ORGANIC ACIDS; OXIDATION; PLATINUM; PLATINUM ALLOYS;

CATALYST SELECTIVITY;

EID: 84862278317     PISSN: 09263373     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apcatb.2012.05.024     Document Type: Article

References (39)

1. Parsons R., Vandernoot T. Journal of Electroanalytical Chemistry 1988, 257:9-45.
2. Wasmus S., Kuver A. Journal of Electroanalytical Chemistry 1999, 461:14-31.
3. Lamy C., Coutanceau C., leger J.M. Catalysis for Sustainable Energy Production 2009, Wiley-VCH Verlag GmbH & Co. KGaA, pp. 281-304.
4. Antolini E., Gonzalez E.R. Journal of Power Sources 2010, 195:3431-3450.
5. Serov A., Kwak C. Applied Catalysis B 2010, 97:1-12.
6. Yu E.H., Krewer U., Scott K. Energies 2010, 3:1499-1528.
7. Ji N., Zhang T., Zheng M.Y., Wang A.Q., Wang H., Wang X.D., Chen J.G.G. Angewandte Chemie International Edition 2008, 47:8510-8513.
8. Zheng M.-Y., Wang A.-Q., Ji N., Pang J.-F., Wang X.-D., Zhang T. ChemSusChem 2010, 3:63-66.
9. Beltowska-Brzezinska M., Luczak T., Holze R. Journal of Applied Electrochemistry 1997, 27:999-1011.
10. Kadirgan F., Bouhiercharbonnier E., Lamy C., Leger J.M., Beden B. Journal of Electroanalytical Chemistry 1990, 286:41-61.
11. Christensen P.A., Hamnett A. Journal of Electroanalytical Chemistry 1989, 260:347-359.
12. Hauffe W., Heitbaum J. Electrochimica Acta 1978, 23:299-304.
13. Hauffe W., Heitbaum J. Physical Chemistry Chemical Physics 1978, 82:487-491.
14. Matsuoka K., Iriyama Y., Abe T., Matsuoka M., Ogumi Z. Electrochimica Acta 2005, 51:1085-1090.
15. Matsuoka K., Inaba M., Iriyama Y., Abe T., Ogumi Z., Matsuoka M. Fuel Cells 2002, 2:35-39.
16. Zope B.N., Hibbitts D.D., Neurock M., Davis R.J. Science 2010, 330:74-78.
17. Kwon Y., Lai S.C.S., Rodriguez P., Koper M.T.M. Journal of the American Chemical Society 2011, 133:6914-6917.
18. Chang S.C., Ho Y.H., Weaver M.J. Journal of the American Chemical Society 1991, 113:9506-9513.
19. Demarconnay L., Brimaud S., Coutanceau C., Leger J.M. Journal of Electroanalytical Chemistry 2007, 601:169-180.
20. Wang H., Jusys Z., Behm R.J. Journal of Electroanalytical Chemistry 2006, 595:23-36.
21. Kwon Y., Koper M.T.M. Analytical Chemistry 2010, 82:5420-5424.
22. Kwon Y., Schouten K.J.P., Koper M.T.M. ChemCatChem 2011, 3:1176-1185.
23. Zhang Z., More K.L., Sun K., Wu Z., Li W. Chemistry of Materials 2011, 23:1570-1577.
24. Zhang Z., Xin L., Li W. Applied Catalysis B 2012, 119-120:40-48.
25. Xin L., Zhang Z., Wang Z., Li W. ChemCatChem 2012, cctc.201200017.
26. Zope B.N., Davis R.J. Topics in Catalysis 2009, 52:269-277.
27. Ketchie W.C., Murayama M., Davis R.J. Topics in Catalysis 2007, 44:307-317.
28. Carrettin S., McMorn P., Johnston P., Griffin K., Hutchings G.J. Chemical Communications 2000, 696-697.
29. Zhang Z., Li M., Wu Z., Li W. Nanotechnology 2011, 22:015602.
30. Li W.Z., Liang C.H., Zhou W.J., Qiu J.S., Zhou Z.H., Sun G.Q., Xin Q. Journal of Physical Chemistry 2003, 107B:6292-6299.
31. Simoes M., Baranton S., Coutanceau C. Applied Catalysis B 2010, 93:354-362.
32. Chen A.C., Lipkowski J. Journal of Physical Chemistry B 1999, 103:682-691.
33. Burke L.D., Moran J.M., Nugent P.F. Journal of Solid State Electrochemistry 2003, 7:529-538.
34. Bambagioni V., Bevilacqua M., Bianchini C., Filippi J., Marchionni A., Vizza F., Wang L.Q., Shen P.K. Fuel Cells 2010, 10:582-590.
35. Bayer D., Berenger S., Joos M., Cremers C., Tubke J. International Journal of Hydrogen Energy 2010, 35:12660-12667.
36. Lamy C., Belgsir E.M., Leger J.M. Journal of Applied Electrochemistry 2001, 31:799-809.
37. Miyazaki K., Matsumiya T., Abe T., Kurata H., Fukutsuka T., Kojima K., Ogumi Z. Electrochimica Acta 2011, 56:7610-7614.
38. Roquet L., Belgsir E.M., Leger J.M., Lamy C. Electrochimica Acta 1994, 39:2387-2394.
39. Kadirgan F., Beden B., Lamy C. Journal of Electroanalytical Chemistry 1983, 143:135-152.