Sorption of Cesium on Clay Colloids: Kinetic and Thermodynamic Studies

Aquatic Geochemistry

Volumn 18, Issue 4, 2012, Pages 281-296

  Rani, R Deepthi ^a   Sasidhar, P ^a  

^a INDIRA GANDHI CENTRE FOR ATOMIC RESEARCH   (India)

Author keywords

Cesium; Clay colloids; Exothermic; Kinetics; Sorption

Indexed keywords

CESIUM; COLLOID; CONCENTRATION (COMPOSITION); GROUNDWATER; KINETICS; PH; RADIONUCLIDE; SORPTION; THERMODYNAMICS; WATER CHEMISTRY; WATER QUALITY;

EID: 84862261840     PISSN: 13806165     EISSN: 15731421     Source Type: Journal    
DOI: 10.1007/s10498-012-9163-6     Document Type: Article

References (35)

1. Adeleye SA, Clay PG, Oladipo MOA (1994) Sorption of caesium and europium ions on clay minerals. J Mater Sci 29: 954-958.
2. Aksoyoglu S (1989) Sorption of U (VI) on granite. J Radioanal Nucl Chem 134(2): 393-403.
3. Aksu Z (2001) Equilibrium and kinetic modeling of cadmium (II) biosorption by C. vulgaris in a batch system: effect of temperature. Sep Pur Technol 21: 285-294.
4. Aksu Z, Tezer S (2005) Biosorption of reactive dyes on the green alga Chlorella vulgaris. Process Biochem 40: 1347-1361.
5. Al-Ghouti M, Khraisheh MAM, Ahmad MNM, Allen S (2005) Thermodynamic behaviour and the effect of temperature on the removal of dyes from aqueous solution using modified diatomite: a kinetic study. J Col Interface Sci 287: 6-13.
6. Argun ME, Dursun S (2008) A new approach to modification of natural adsorbent for heavy metal adsorption. Bioresour Technol 99: 2516-2527.
7. Bostick BC, Vairavamurthy MA, Karthikeyan KG, Chorover J (2002) Cesium adsorption on clay minerals: an EXAFS spectroscopic investigation. Environ Sci Technol 36: 2670-2676.
8. Buddemeier RW, Hunt JR (1988) Transport of colloidal contaminants in groundwater: radionuclide migration at the Nevada test site. Appl Geochem 3: 535-548.
9. Chegrouche S, Mellah A, Barkat M (2009) Removal of strontium from aqueous solutions by adsorption onto activated carbon: kinetic and thermodynamic studies. Desalination 235: 306-318.
10. Cornell RM (1993) Sorption of cesium on minerals: a review. J Radioanal Nucl Chem 171: 483-500.
11. Deepthi Rani R, Sasidhar P (2010) Role of clays in radioactive waste disposal. International conference on advances in materials, mechanics and management, pp 584-589.
12. Deepthi Rani R, Sasidhar P (2010) Stability assessment and characterization of colloids in coastal groundwater aquifer system at Kalpakkam. Environ Earth Sci (2011) 62: 233-243.
13. Deepthi Rani R, Sasidhar P (2011) Physico-chemical characterization of clays at Kalpakkam nuclear plant site towards assessment of radioactive waste disposal. Nucl Eng Des 241: 2353-2358.
14. Degueldre C, Baeyens B, Goerlich W, Riga J, Verbist J, Stadelmann P (1989) Colloids in water from a subsurface fracture in granitic rock, Grimsel Test Site, Switzerland. Geochim Cosmochim Acta 53: 603-610.
15. Gschwend PM, Reynolds MD (1987) Monodisperse ferrous phosphate colloids in an anoxic groundwater plume. J Contam Hydrol 1: 309-327.
16. Hening C, Reich T, Dahn R, Scheidegger AM (2002) Structure of uranium sorption complexes at montmorillonite edge sites. Rad Che Act 90: 653-657.
17. Ho YS (2004) Selection of optimum sorption isotherm. Carbon 42: 2115-2116.
18. Ho YS, McKay G (1998) Sorption of dye from aqueous solution by peat. Chem Eng J 70: 115-124.
19. Khan SA (2002) Sorption of the long lived radionuclides cesium -134, strontium-85 and cobalt -60 on bentonite. J Radioanal Nucl Chem 258: 3-6.
20. Khan SA, Riaz ur Reman, Alikhan M (1994) Adsorption of Cs(I), Sr(II) and Co(II) on Al2O3. J Radioanal Nucl Chem 190: 81-96.
21. Komarneni S (1979) Cesium sorption by clay minerals and shales at elevated temperatures. J Inorg Nucl Chem 41: 397-400.
22. Oguz E (2005) Adsorption characteristics and the kinetics of the Cr(VI) on the Thuja oriantalis. Colloids Surf A 252: 121-128.
23. Rahman ROA, Ibrahim HA, Hanafy M, Monem NMA (2010) Assessment of synthetic zeolite Na A-X as sorbing barrier for strontium in a radioactive disposal facility. Chem Eng J 157: 100-112.
24. Ryan JN, Elimelech M (1996) Colloid mobilization and transport in groundwater. Coll Surf A Physicochem Eng Aspects 107: 1-56.
25. Saiers JE, Hornberger GM (1996) The role of colloidal kaolinite in the transport of cesium through laboratory sand columns. Water Resour Res 32: 33-41.
26. Sasidhar P (1993) Safety assessment of low level radioactive waste disposal facility at Kalpakkam. PhD Thesis.
27. Sawhney BL (1972) Selective sorption and fixation of cations by clay minerals: a review. Clays Clay Miner 20: 93-100.
28. Shahwan T, Akar D, Eroglu AE (2005) Physicochemical characterization of the retardation of aqueous Cs+ ions by natural kaolinite and clinoptilolite minerals. J Col Interface Sci 285: 9-17.
29. Sheng G, Hu J, Wang X (2008) Sorption properties of Th(IV) on the raw diatomite-Effects of contacttime, pH, ionic strength and temperature. Appl Rad Isot 66: 1313-1320.
30. Singh VS, Saxena VK, Jain SC, Anjaneyulu GR, Prakash BA, Mondal NC (2003) Hydrogeological and geophysical Investigations at PFBR Site, Kalpakkam, Tamilnadu. Techical report no. NGRI-2003-GW-396.
31. Sivaiah MV, Kumar SS, Venkatesan KA, Sasidhar P, Krishna RM, Murthy GS (2004) Sorption of strontium on zirconia modified vermiculite. J Nucl Radiochem Sci 5: 33-36.
32. Staunton S, Roubaud M (1997) Adsorption of 137Cs on montmorillonite and illite: effect of charge compensating cation, ionic strength, concentration of Cs and fulvic acid. Clays Clay Miner 45: 251-260.
33. Temkin MI, Pyzhev V (1940) Kinetics of ammonia synthesis on promoted iron catalysts. Acta Physiochim URSS 12: 327-356.
34. Unlu N, Ersoz M (2006) Adsorption characteristics of heavy metal ions onto a low cost biopolymeric sorbent from aqueous solutions. J Hazard Mater 136: 272-280.
35. Weiss CA Jr, Kirkpatrick RJ, Altaner SP (1990) The structural environments of cations adsorbed onto clays: 133Cs variable-temperature MAS NMR spectroscopic study of hectorite. Geochim et Cosmochim Acta 54: 1655-1669.