Probing segmental dynamics of polymer glasses during tensile deformation with dielectric spectroscopy

Macromolecules

Volumn 45, Issue 11, 2012, Pages 4839-4847

  Kalfus, Jan ^a   Detwiler, Andrew ^a   Lesser, Alan J ^a  

^a UNIVERSITY OF MASSACHUSETTS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE DEFORMATION; AMORPHOUS POLYMERS; BROADBAND DIELECTRIC RELAXATION SPECTROSCOPY; CHAIN SEGMENTS; DIELECTRIC PERMITTIVITIES; ISOTHERMAL AGING; MECHANICAL EXCITATIONS; MOLECULAR MOBILITY; OUT OF PHASE; POLYMER GLASS; RELAXATION SPECTRUM; REORIENTATION DYNAMICS; SEGMENTAL DYNAMICS; STRAIN-DEPENDENT; TENSILE DEFORMATION; TRANSITION ACTIVITY;

CHLORINE COMPOUNDS; DYNAMICS; ELECTRIC EXCITATION; ELECTRIC FIELDS; PERMITTIVITY; POLYVINYL CHLORIDES;

DEFORMATION;

EID: 84862158425     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma202708j     Document Type: Article

References (22)

1. Chen, K.; Saltzman, E. J.; Schweizer, K. S. Annu. Condens. Matter Phys. 2010, 1, 277
2. Riggleman, R. A.; Lee, H.-N.; Ediger, M. D.; de Pablo, J. J. Soft Matter 2010, 6, 287
3. Capaldi, F. M.; Boyce, M. C.; Rutledge, G. C. Polymer 2004, 45, 1391
4. Capaldi, F. M.; Boyce, M. C.; Rutledge, G. C. Phys. Rev. Lett. 2002, 89, 175505
5. Adolf, D. B.; Chambers, J. M.; Caruthers, J. M. Polymer 2004, 45, 4599
6. Warren, M.; Rottler, J. J. Chem. Phys. 2010, 133, 164513
7. Lee, H.-N.; Ediger, M. D. Macromolecules 2010, 43, 5863
8. Lee, H.-N.; Paeng, K.; Swallen, S. F.; Ediger, M. D.; Stamm, R. A.; Medvedev, G. A.; Caruthers, J. M. J. Polym. Sci., Part B: Polym. Phys. 2009, 47, 1713
9. Strobl, G. The Physics of Polymers: Concepts for Understanding Their Structure and Behavior; Springer: Berlin, Germany, 2007.
10. Matsumiya, Y.; Watanabe, H.; Inoue, T.; Osaki, K. Macromolecules 1998, 31, 7975
11. Bartenev, G. M. Relaxation Phenomena in Polymers; Wiley: London, UK, 1974.
12. Smith, G. D.; Bedrov, D. J. Polym. Sci., Part B: Polym. Phys. 2007, 45, 627
13. Donth, E. The Glass Transition: Relaxation Dynamics in Liquids and Disordered Materials; Springer: Berlin, Germany, 2001.
14. Adam, G.; Gibbs, J. H. J. Chem. Phys. 1965, 43, 139
15. Miller, A. A. Macromolecules 1978, 11, 859
16. Matsuoka, S. Relaxation Phenomena in Polymers; Hanser: Munich, Germany, 1992.
17. Hodge, I. M. Macromolecules 1983, 16, 898
18. Runt, P. J.; Fitzgerald, J. J. Dielectric Spectroscopy of Polymeric Materials: Fundamentals and Applications; American Chemical Society: Washington, DC, 1997.
19. McCrum, N. G.; Read, B. E.; Williams, G. Anelastic and Dielectric Effects in Polymeric Solids; Wiley: London, UK, 1967.
20. Brown, D.; Clarke, J. H. R. Macromolecules 1991, 24, 2075
21. Eyring, H. J. Chem. Phys. 1936, 4, 283
22. Tobolsky, A. V.; Andrews, R. D. J. Chem. Phys. 1945, 13, 3