Spectroscopic studies on U(VI)-salicylate complex formation with multiple equilibria

Radiochimica Acta

Volumn 100, Issue 6, 2012, Pages 371-379

  Cha, W ^a   Cho, H R ^a   Jung, E C ^a   Park, K K ^a   Kim, W H ^a   Song, K ^a  

^a Korea Atomic Energy Research Institute   (South Korea)

Author keywords

Charge transfer complex; Hydrolysis; Luminescence quenching; Salicylic acid; Time resolved laser induced fluorescence; Uranium(VI)

Indexed keywords

EID: 84862017239     PISSN: 00338230     EISSN: None     Source Type: Journal    
DOI: 10.1524/ract.2012.1930     Document Type: Article

References (41)

1. Dozol, M., Hagemann, R.: Radionuclide migration in groundwaters: review of the behavior of actinides. Pure Appl. Chem. 65, 1081 (1993).
2. Fanghänel, T., Neck, V.: Aquatic chemistry and solubility phenomena of actinide oxides/hydroxides. Pure Appl. Chem. 74, 1895 (2002).
3. Kim, J.-I.: Significance of actinide chemistry for the long-term safety of waste disposal. Nucl. Eng. Technol. 38, 459 (2006).
4. Koll, H., Geipel, G., Reich, T., Bernhard, G., Fanghänel, T., Grenthe, I.: Uranyl (VI) complexes with alpha-substituted carboxylic acids in aqueous solution. Radiochim. Acta 91, 11 (2003).
5. Moyagi, N., Toraishi, T., Geipel, G., Hotokezaka, H., Nagasaki, S., Tanaka, S.: Fluorescence characteristics of complex formation of europium (III)-salicylate. Radiochim. Acta 92, 589 (2004).
6. Toraishi, T., Aoyagi, N., Nagasaki, S., Tanaka, S.: Stoichiometry, stability constants and coordination geometry of Eu (III) 5-sulfosalicylate complex in aqueous system - a TRLFS study. Dalton Trans. 33, 3495 (2004).
7. Toraishi, T., Nagasaki, S., Tanaka, S.: A theoretical study on molecular structure of Eu (III)-salicylate complexes in aqueous system. J. Mol. Struct. Theochem. 757, 87 (2005).
8. Yousif, Y. Z., Al-Imarah, F. J. M.: Spectroscopic study of the effect of substitution on the thermodynamic stability of the 1:1 complexes of the dioxouranium (II) ion with mono-substituted salicylic acids in aqueous media. Transit. Metal. Chem. 14, 123 (1989).
9. Silva, J. C. G E. d., Machado, A. A. S. C., Oliveira, C. J. S.: Study of the interaction of a soil fulvic acid with UO22+ by self-modelling mixture analysis of synchronous molecular fluorescence spectra. Analyst 121, 1373 (1996).
10. Schmeide, K., Sachs, S., Bubner, M., Reich, T., Heise, K. H., Bernhard, G: Interaction of uranium (VI) with various modified and unmodified natural and synthetic humic substances studied by EXAFS and FTIR spectroscopy. Inorg. Chim. Acta 351, 133 (2003).
11. Stumm, W., Furrer, G: The dissolution of oxides and aluminium silicates: examples of surface-coordinatin-controlled kinetics. In: Aquatic Surface Chemistry. (Stumm, W., ed.) J. Wiley & Sons, New York (1987), pp. 197-219.
12. Jankovic, I. A., Saponjic, Z. V., Comor, M. I., Nedeljkovic, J. M.: Surface modification of colloidal TiO2 nanoparticles with bidentate benzene derivatives. J. Phys. Chem. 113, 12645 (2009).
13. Mitchell-Koch, J. T., Reid, K. R., Meyerhoff, M. E.: Salicylate detection by complexation with Iron (III) and optical absorbance spectroscopy. J. Chem. Educ. 85, 1658 (2008).
14. Greenaway, F. T., Norris, L. J.: Mononuclear and binuclear copper (II) complexes of 3, 5-diisopropylsalicylic acid. Inorg. Chim. Acta 145, 279 (1988).
15. Kim, B.-I., Miyake, C, Imoto, S.: Spectroscopic studies on the uranyl complexes with 1, 2-disubstituted benzenes. J. Inorg. Nucl. Chem. 36, 2015 (1974).
16. Banks, C. V., Singh, R. S.: Composition and stability of some metal-5-sulfosalicylate complexes. J. Inorg. Nucl. Chem. 15, 125 (1960).
17. Foley, R. T., Anderson, R. C: Spectrophotometric studies of complex formation with sulfosalicylic acid. II. With uranyl ion. J. Am. Chem. Soc. 71, 909 (1949).
18. Rao, J. M., Seshaiah, U. V.: Stability constants of uranyl chelates with nuclear-substituted salicylic acids. B. Chem. Soc. Jpn. 39, 2668 (1966).
19. Gangopadhyay, S., Banerjee, R. N., Banerjea, D.: Complexation of uranium (VI) by salicylate and substitute salicylates: a kinetic study. Transit. Metal. Chem. 10, 325 (1985).
20. Jahagirdar, D. V., Khanolkar, D. D.: Studies of UO2 (II) complexes of substituted salicylic acids. J. Inorg. Nucl. Chem. 35, 921 (1973).
21. Rajan, K. S., Martell, A. E.: Equilibrium studies of uranyl complexes - I. Interaction of uranyl ion with some hydroxycarboxylic and aminocarboxylic acids. J. Inorg. Nucl. Chem. 26, 789 (1964).
22. Vartak, D. G., Menon, K. R.: Stability constants of some substituted salicylic acids and their complexes. J. Inorg. Nucl. Chem. 33, 1003 (1971).
23. Geipel, G: Some aspects of actinide speciation by laser-induced spectroscopy. Coord. Chem. Rev. 250, 844 (2006).
24. Guillaumont, R., Fanghänel, T., Fuger, J., Grenthe, I., Neck, V., Palmer, D. A., Rand, M. H.: Update on the chemical thermodynamics of uranium, neptinum, plutonium, americium and technetium. In: (OECD, NEA-TDB): Chemical Thermodynamics. (Mompean, F. J., Domenech-Orti, C, Ben-Said, K., Illemassène, M., eds.) Vol. 5, Elsevier, North-Holland, Amsterdam (2003), p. 157.
25. Jung, E. C., Cho, H.-R., Park, K. K., Yeon, J.-W., Song, K.: Nanoparticle sizing by a laser-induced breakdown detection using an optical probe beam deflection. Appl. Phys. B 97, 867 (2009).
26. Cho, H.-R., Jung, E. C., Park, K. K., Song, K., Yun, J.-I.: Effect of reduction on the stability of Pu (VI) hydrolysis species. Radiochim. Acta 98, 555 (2010).
27. Lajunen, L. H. J., Portanova, R., Piispanen, J., Tolazzi, M.: Stability constants for alpha-hydroxycarboxylic acid complexes with protons and metal ions and the accompanying enthalpy changes - Part I: Aromatic ortho- hydroxycarboxylic acids. Pure Appl. Chem. 69, 329 (1997).
28. Harris, D. C: Application of spectrophotometry. In: Quantitative Chemcal Analysis. (Harris, D. C., ed.) 6th Edn., W. H. Freeman and Company, New York (2006), pp. 440-442.
29. Deranleau, D. A.: Theory of the measurement of weak molecular complexes. II. Consequences of multiple equilibria. J. Am. Chem. Soc. 91, 4050 (1969).
30. Moulin, C., Laszak, I., Moulin, V., Tondre, C: Time-resolved laser-induced fluorescence as a unique tool for low-level uranium speciation. Appl. Spectrosc. 52, 528 (1998).
31. Eliet, V., Bidoglio, G., Omenetto, N, Parma, L., Grenthe, I.: Characterisation of hydroxide complexes of uranium (VI) by timeresolved fluorescence spectroscopy. J. Chem. Soc. Faraday Trans. 91, 2275 (1995).
32. Meinrath, G.: Uranium (VI) speciation by spectroscopy. J. Radioanal. Nucl. Chem. 224, 119 (1997).
33. Rabinovitch, E., Belford, R. L.: Spectroscopy and Photochemistry of Uranyl Compounds. Pergamon, Oxford (1964).
34. Bruneau, E., Lavabre, D., Levy, G., Micheau, J. C: Quantitative analysis of continuous-variation plots with a comparison of several methods. J. Chem. Educ. 69, 833 (1992).
35. Eliet, V., Grenthe, I., Bidoglio, G: Time-resolved laser-Induced fluorescence of uranium (VI) hydroxo-complexes at different temperatures. Appl. Spectrosc. 54, 99 (2000).
36. Cho, H.-R., Jung, E. C., Jee, K. Y: Probe beam detection of laserinduced breakdown for measuring solubility of actinide compounds. Jpn. J. Appl. Phys. 47, 3530 (2008).
37. v. d. Weert, M.: Fluorescence quenching to study protein-ligand binding: common errors. J. Fluoresc. 20, 625 (2010).
38. Lavrik, N. L., Mulloev, N. U.: A fluorescence quenching study of the complexation of salicylic acid mono-and dianions with the copper (II) ion in aqueous solutions. High Energy Chem. 44, 139 (2010).
39. Lakowicz, J. R.: Quenching of fluorescence. In: Principles of Fluorescence Spectroscopy. (Lakowicz, J. R., ed.) Springer, New York, NY (2006), p. 282.
40. Pompe, S., Brachmann, A., Bubner, M., Geipel, G., Heise, K. H., Bernhard, G., Nitsche, H: Determination and comparison of uranyl complexation constants with natural and model humic acids. Radiochim. Acta 82, 89 (1998).
41. Vulpius, D., Geipel, G., Baraniak, L., Rossberg, A., Bernhard, G: Complex formation of uranium (VI) with 4-hydroxy-3-methoxybenzoic acid and related compounds. J. Radioanal. Nucl. Chem. 270, 661 (2006).