Thioketone-mediated polymerization with dithiobenzoates: Proof for the existence of stable radical intermediates in RAFT polymerization

Macromolecular Rapid Communications

Volumn 33, Issue 11, 2012, Pages 984-990

  Junkers, Thomas ^a,b   Delaittre, Guillaume ^a   Chapman, Robert ^c,d   Günzler, Fabian ^a   Chernikova, Elena ^e   Barner Kowollik, Christopher ^a  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^b HASSELT UNIVERSITY   (Belgium)

^c UNIVERSITY OF NEW SOUTH WALES   (Australia)

^d UNIVERSITY OF SYDNEY   (Australia)

^e MOSCOW STATE UNIVERSITY   (Russian Federation)

Author keywords

controlled living radical polymerization; dithiobenzoate; radical stability; reversible addition fragmentation transfer; thioketone

Indexed keywords

CONTROL AGENT; CONTROLLED/LIVING RADICAL POLYMERIZATION; DISPERSITY; DITHIOBENZOATE; DITHIOBENZOATES; DITHIOESTERS; DORMANT RADICALS; INTERMEDIATE RADICAL TERMINATIONS; MOLAR MASS DISTRIBUTION; MONOMER CONVERSIONS; N-BUTYL ACRYLATE; RAFT POLYMERIZATION; RATE OF POLYMERIZATION; REVERSIBLE ADDITION-FRAGMENTATION TRANSFERS; STABLE RADICALS; THIOKETONE;

ATOM TRANSFER RADICAL POLYMERIZATION; MOLAR MASS; POLYMETHYL METHACRYLATES;

LIVING POLYMERIZATION;

ACRYLIC ACID BUTYL ESTER; ACRYLIC ACID DERIVATIVE; N-BUTYL ACRYLATE; POLYMER;

ARTICLE; CHEMISTRY; SYNTHESIS;

ACRYLATES; POLYMERS;

EID: 84861846026     PISSN: 10221336     EISSN: 15213927     Source Type: Journal    
DOI: 10.1002/marc.201200128     Document Type: Article

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