Study of the film formation and mechanical properties of the latexes obtained by miniemulsion co-polymerization of butyl acrylate, methyl acrylate and 3-methacryloxypropyltrimethoxysilane

Progress in Organic Coatings

Volumn 75, Issue 1-2, 2012, Pages 86-91

  Ramos Fernández, José Manuel ^a   Beleña, Irene ^a   Romero Sánchez, María Dolores ^a   Fuensanta, Monica ^a   Guillem, Celia ^a   López Buendía, Ángel María ^a  

^a AIDICO   (Spain)

Author keywords

Alkoxysilane; Films; Mechanical properties; Miniemulsion

Indexed keywords

ALKOXYSILANES; BUTYL ACRYLATES; FILM FORMATIONS; HYDROLYSIS AND CONDENSATION; LATEX FILMS; LATEX PARTICLES; METHYL ACRYLATES; MINI-EMULSION POLYMERIZATION; MINIEMULSIONS; POLYMER PARTICLES;

CONDENSATION REACTIONS; COPOLYMERIZATION; EMULSION POLYMERIZATION; FILMS; HYDROLYSIS; MECHANICAL PROPERTIES; NANOINDENTATION; STRESS-STRAIN CURVES;

LATEXES;

EID: 84861827740     PISSN: 03009440     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.porgcoat.2012.03.012     Document Type: Article

References (17)

1. J. Taylor, and M. Winnik Functional latex and thermoset latex films J. Coat. Technol. Res. 1 2004 163 190
2. F. Tronc, R. Liu, M.A. Winnik, S.T. Eckersley, G.D. Rose, J.M. Weishuhn, and D.M. Meunier Epoxy-functionalized, low glass-transition temperature latex. I. Synthesis, characterizations, and polymer interdiffusion J. Polym. Sci. A: Polym. Chem. 40 2002 2609 2625 (Pubitemid 34822432)
3. Z.H. Cao, G.R. Shan, G. Fevotte, N. Sheibat-Othman, and E. Bourgeat-Lami Miniemulsion copolymerization of styrene and γ- methacryloxypropyltrimethoxysilane: kinetics and mechanism Macromolecules 41 2008 5166 5173
4. V. Castelvetro, F. Ciardelli, C. De Vita, and A. Puppo Hybrid nanocomposite films from mono- and multi-functional POSS copolyacrylates in miniemulsion Macromol. Rapid Commun. 27 2006 619 625
5. S. Huang, D. Fan, Y. Lei, and H. Huang Alkoxysilane-functionalized acrylic copolymer latexes. I. Particle size, morphology, and film-forming properties J. Appl. Polym. Sci. 94 2004 954 960 (Pubitemid 39404384)
6. Y. Luo, H. Xu, and B. Zhu The influence of monomer types on the colloidal stability in the miniemulsion copolymerization involving alkoxysilane monomer Polymer 47 2006 4959 4966 (Pubitemid 43947115)
7. I. Marcu, E.S. Daniels, V.L. Dimonie, C. Hagiopol, J.E. Roberts, and M.S. El-Aasser Incorporation of alkoxysilanes into model latex systems: vinyl copolymerization of vinyltriethoxysilane and n-butyl acrylate Macromolecules 36 2002 328 332
8. H. Schmidt, H. Scholze, and A. Kaiser Principles of hydrolysis and condensation reaction of alkoxysilanes J. Non-Cryst. Solids 63 1984 1 11
9. F.D. Osterholtz, and E.R. Pohl Kinetics of the hydrolysis and condensation of organofunctional alkoxysilanes: a review J. Adhes. Sci. Technol. 6 1992 127 149
10. J.M. Asua Miniemulsion polymerization Prog. Polym. Sci. 27 2002 1283 1346 (Pubitemid 34648981)
11. J.L. Gardon Emulsion polymerization. II. Review of experimental data in the context of the revised Smith-Ewart theory J. Polym. Sci. A-1: Polym. Chem. 6 1968 643 664
12. M. Manea, A. Chemtob, M. Paulis, J.C. de la Cal, M.J. Barandiaran, and J.M. Asua Miniemulsification in high-pressure homogenizers AIChE J. 54 2008 289 297
13. S.-W. Zhang, S.-X. Zhou, Y.-M. Weng, and L.-M. Wu Synthesis of silanol-functionalized latex nanoparticles through miniemulsion copolymerization of styrene and γ-methacryloxypropyltrimethoxysilane Langmuir 22 2006 4674 4679 (Pubitemid 43829149)
14. J.A. Alduncin, J. Forcada, M.J. Barandiaran, and J.M. Asua On the main locus of radical formation in emulsion polymerization initiated by oil-soluble initiators J. Polym. Sci. A: Polym. Chem. 29 1991 1265 1270 (Pubitemid 21682942)
15. I. González, J.M. Asua, and J.R. Leiza The role of methyl methacrylate on branching and gel formation in the emulsion copolymerization of BA/MMA Polymer 48 2007 2542 2547 (Pubitemid 46578238)
16. J.L. Keddie Film formation of latex Mater. Sci. Eng. R 21 1997 101 170 (Pubitemid 127385003)
17. T.Y. Guo, C. Xi, G.J. Hao, M.D. Song, and B.H. Zhang Preparation and properties of room temperature self-crosslinking poly(MMA-co-BA-co-St-co-VTES) latex film Adv. Polym. Technol. 24 2005 288 295 (Pubitemid 43256859)